公开(公告)号：US4946661A

公开(公告)日：1990-08-07

申请号：US271540

申请日：1988-11-15

申请人： Takahiro Tachi ,  Akira Kato ,  Hiroshi Kawagoshi ,  Hisao Yamashita ,  Tomoichi Kamo ,  Shinpei Matsuda ,  Yasuyoshi Kato ,  Fumito Nakajima

发明人： Takahiro Tachi ,  Akira Kato ,  Hiroshi Kawagoshi ,  Hisao Yamashita ,  Tomoichi Kamo ,  Shinpei Matsuda ,  Yasuyoshi Kato ,  Fumito Nakajima

IPC分类号： B01D53/94 ,  B01D53/86 ,  B01J21/06 ,  B01J23/28 ,  B01J35/10

CPC分类号： B01J21/063 ,  B01D53/8628 ,  B01J35/108

摘要： A process for removing nitrogen oxides from exhaust gases containing volatile metal compounds with good efficiency by contacting the gases with a catalyst comprising TiO.sub.2, difficulty reduced by the compounds, in the presence of ammonia, and such a catalyst are provided, which process is characterized in that the average pore diameter of the TiO.sub.2 is 10,000 .ANG. or less and the proportion of the volume of pores having pore diameters of 400-5,000 .ANG. to the total pore volume is 50% or more; a denitration-active component is supported on the TiO.sub.2 ; a catalyst carrier precursor comprising an aqueous slurry sol of TiO.sub.2 or Ti hydroxide prepared by hydrolyzing a Ti salt is precalcined at 150.degree.-700.degree. C., followed by adding a denitration-active component and then normally calcining the mixture; and a polymer compound having a thermal decomposition temperature of 110.degree. to 300.degree. C. is added in 1-20% by weight to the catalyst carrier precursor, followed by precalcining the mixture at the thermal decomposition temperature or higher.

公开(公告)号：US4865827A

公开(公告)日：1989-09-12

申请号：US194827

申请日：1988-05-17

申请人： Takahiro Tachi ,  Hiroshi Kawagoshi ,  Akira Kato ,  Hisao Yamashita ,  Tomoichi Kamo ,  Shinpei Matsuda ,  Yasuyoshi Kato ,  Fumito Nakajima

发明人： Takahiro Tachi ,  Hiroshi Kawagoshi ,  Akira Kato ,  Hisao Yamashita ,  Tomoichi Kamo ,  Shinpei Matsuda ,  Yasuyoshi Kato ,  Fumito Nakajima

IPC分类号： B01D53/94 ,  B01D53/86 ,  B01J27/053

CPC分类号： B01J27/053 ,  B01D53/8628

摘要： A process for removing nitrogen oxides from exhaust gases containing at least nitrogen oxides and volatile metal compounds by the use of a catalyst having prevented activity reduction due to the volatile metal compounds and having a superior durability is provided, which process comprises contacting the exhaust gases with a catalyst containing TiO.sub.2, a compound active to nitrogen oxides-removing reaction such as oxides of V, Cr, Mo, W, Fe, Co, Ni, Cu, Ce, etc. and/or sulfates thereof and a metal sulfate containing water of crystallization such as those of Al, Mg or Mn, in the presence of ammonia at 150.degree. to 600.degree. C.

公开(公告)号：US4207209A

公开(公告)日：1980-06-10

申请号：US954449

申请日：1978-10-25

申请人： Shinpei Matsuda ,  Youichi Sakuta ,  Tomoichi Kamo ,  Shigeo Uno ,  Masato Takeuchi ,  Jinichi Imahashi ,  Hideo Okada ,  Akira Kato ,  Fumito Nakajima

发明人： Shinpei Matsuda ,  Youichi Sakuta ,  Tomoichi Kamo ,  Shigeo Uno ,  Masato Takeuchi ,  Jinichi Imahashi ,  Hideo Okada ,  Akira Kato ,  Fumito Nakajima

IPC分类号： B01D53/86 ,  B01J20/06 ,  B01J21/06 ,  B01J23/28 ,  C04B35/46 ,  C04B35/628 ,  B01J23/88

CPC分类号： C04B35/6303 ,  B01D53/8628 ,  B01J20/06 ,  B01J21/063 ,  B01J23/28 ,  C04B35/46 ,  C04B35/495 ,  C04B35/6263 ,  C04B35/62818 ,  C04B38/0006 ,  C04B2111/0081 ,  C04B2235/3229 ,  C04B2235/3232 ,  C04B2235/3239 ,  C04B2235/3241 ,  C04B2235/3256 ,  C04B2235/3258 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3293 ,  C04B2235/40 ,  C04B2235/408 ,  C04B2235/6021

摘要： The present invention relates to a method for sintering oxidized titanium powder and an active metallic component containing oxidized molybdenum as a binder for oxidized titanium granules. The active metallic component comprises one or more than one selected from a group consisting of V.sub.2 O.sub.3, Fe.sub.2 O.sub.3, WO.sub.3, Co.sub.2 O.sub.3, NiO, Cr.sub.2 O.sub.3, CeO.sub.2, SnO.sub.2, CuO, MoO.sub.3, Pt, Pd, Rh, Ru, Ir and Re.The method comprising the steps of:depositing vaporized oxidized molybdenum on the oxidized titanium powder in an atmosphere of molybdenum vapor at temperatures of 460.degree. to 650.degree. C.,forming a powdery mixture comprising the oxidized titanium powder with the deposited oxidized molybdenum and said active metallic component,adding water sufficient to make a viscous material of the powdery mixture,kneading the viscous material,shaping an article by using the viscous material, andcalcining the article to produce a product.

摘要翻译： 本发明涉及氧化钛粉末和含有氧化钼作为氧化钛颗粒的粘合剂的活性金属成分的烧结方法。 活性金属组分包括选自V 2 O 3，Fe 2 O 3，WO 3，Co 2 O 3，NiO，Cr 2 O 3，CeO 2，SnO 2，CuO，MoO 3，Pt，Pd，Rh，Ru，Ir和Re中的一种或多种。 该方法包括以下步骤：在460℃至650℃的温度下，在钼蒸气气氛下，将氧化的氧化钼沉积在氧化的钛粉末上，形成包含氧化的钛粉末与沉积的氧化钼和所述活性物质的粉末混合物 金属组分，加入足以制备粉状混合物的粘性材料的水，捏合粘性物质，通过使用粘性物质成型物品，并煅烧制品以制备产品。

公开(公告)号：US4206036A

公开(公告)日：1980-06-03

申请号：US938365

申请日：1978-08-31

申请人： Masato Takeuchi ,  Shinpei Matsuda ,  Hideo Okada ,  Hiroshi Kawagoshi ,  Fumito Nakajima

发明人： Masato Takeuchi ,  Shinpei Matsuda ,  Hideo Okada ,  Hiroshi Kawagoshi ,  Fumito Nakajima

IPC分类号： B01J21/06 ,  B01J23/85 ,  C10G45/08 ,  C10G69/04 ,  C10G23/02

CPC分类号： B01J23/85 ,  C10G45/08 ,  C10G69/04 ,  B01J21/063

摘要： Hydrocarbon oil containing sulfur compounds, for example, lighter petroleum fraction having a boiling point of not higher than 250.degree. C. is hydrodesulfurized to less than 1 ppm with a hydrogenating gas containing 1 to 40% by volume of oxides of carbon (CO.sub.2 and CO) in the presence of a catalyst comprising 3 to 40% by weight of at least one of molybdenum and tungsten, and 2 to 15% by weight of at least one of nickel and cobalt, the balance being titanium oxide. Product gas from steam reforming can be used as the hydrogenating gas.

摘要翻译： 含有硫化合物的烃油，例如沸点不高于250℃的较轻的石油馏分，用含有1至40体积％的碳氧化物（CO 2和CO）的氢化气体加氢脱硫至小于1ppm ）在含有3〜40重量％的钼和钨中的至少一种和2〜15重量％的镍和钴中的至少一种的催化剂的存在下进行，其余为氧化钛。 可以使用来自蒸汽重整的产物气体作为氢化气体。

公开(公告)号：US4351811A

公开(公告)日：1982-09-28

申请号：US926111

申请日：1978-07-19

申请人： Shinpei Matsuda ,  Akira Kato ,  Shigeo Uno ,  Youichi Sakuta ,  Fumito Nakajima

发明人： Shinpei Matsuda ,  Akira Kato ,  Shigeo Uno ,  Youichi Sakuta ,  Fumito Nakajima

IPC分类号： B01D53/86 ,  B01D53/36

CPC分类号： B01D53/8628

摘要： The concentrations of NO and NO.sub.2 in nitrogen oxides contained in an exhaust gas are adjusted to substantially equal mol concentrations, whereupon the exhaust gas is held in contact with a metallic oxide catalyst together with ammonia. Owing to the adjustment of the NO and NO.sub.2 concentrations in the nitrogen oxides, the reaction rate is enhanced, and the nitrogen oxides are reduced even at a low temperature. The adjustment of the concentrations of NO and NO.sub.2 in the nitrogen oxides is done by the oxidation of NO with ozone, the catalytic oxidation of NO with air or oxygen, the addition of nitric acid, the addition of NO or NO.sub.2, etc.

摘要翻译： 将排气中含有的氮氧化物中的NO和NO 2的浓度调整为基本相等的摩尔浓度，由此废气与氨一起保持与金属氧化物催化剂接触。 由于氮氧化物中NO和NO 2浓度的调节，反应速度提高，氮氧化物即使在低温也降低。 氮氧化物中NO和NO2浓度的调节是通过用臭氧氧化NO，NO与空气或氧气的反应氧化，硝酸的添加，NO或NO2的添加等进行的。

公开(公告)号：US4141959A

公开(公告)日：1979-02-27

申请号：US853491

申请日：1977-11-21

申请人： Akira Kato ,  Shinpei Matsuda ,  Shigeo Uno ,  Youichi Sakuta ,  Fumito Nakajima ,  Hiroshi Kagabu

发明人： Akira Kato ,  Shinpei Matsuda ,  Shigeo Uno ,  Youichi Sakuta ,  Fumito Nakajima ,  Hiroshi Kagabu

IPC分类号： B01D53/94 ,  B01D53/86 ,  B01J21/06 ,  B01J23/12 ,  B01J23/14 ,  B01J23/16 ,  B01J23/22 ,  B01J23/24 ,  B01J23/34 ,  B01J23/90 ,  B01J27/053 ,  B01J27/055 ,  B01J38/02 ,  C01B21/02 ,  C01C1/242 ,  B01D53/34 ,  B01J23/92

CPC分类号： B01D53/8637 ,  C01B21/02 ,  C01C1/242 ,  Y10S502/517

摘要： Ammonia is added to combustion flue gas containing nitrogen and sulfur oxides and the gas is brought into contact with a catalyst which contains titanium or tin oxide, or a mixture of the two, as a main component at a temperature between 150 .about. 330.degree. C.Nitrogen oxides are reduced to nitrogen and water, and sulfur oxides are deposited as ammonium sulfates, on the surface of the catalyst which causes a decrease in the ability of the catalyst.A part of the catalyst is removed continuously or intermittently from a catalyst bed and fed to a regeneration tower where it is treated with a hot gas having a temperature of 350 .about. 600.degree. C. The ammonium sulfates deposited on the catalyst are decomposed into SO.sub.3 and NH.sub.3. The SO.sub.3 is adsorbed by an SO.sub.3 absorbent and the NH.sub.3 is returned to the combustion flue gas to be treated.

摘要翻译： 在含有氮和硫氧化物的燃烧烟道气中加入氨，使气体与含有钛或氧化锡的催化剂或两者的混合物作为主要成分与150〜330℃的温度接触。

公开(公告)号：US4060498A

公开(公告)日：1977-11-29

申请号：US520950

申请日：1974-11-04

申请人： Hiroshi Kawagoshi ,  Masato Takeuchi ,  Fumito Nakajima

发明人： Hiroshi Kawagoshi ,  Masato Takeuchi ,  Fumito Nakajima

IPC分类号： B01J23/89 ,  B01J35/02 ,  C01B3/40

CPC分类号： B01J35/02 ,  B01J23/894 ,  C01B3/40 ,  C01B2203/1052 ,  Y02P20/52

摘要： A process for steam reforming of hydrocarbons utilizing a catalyst comprising at least 3% by weight, preferably 10, to 30% by weight of nickel per weight of the catalyst, at least 2 mg-atoms of silver per 100 g of the catalyst; if necessary at least one of rare earth elements such as lanthanum, cerium, yttrium, praseodimium, neodimium, or a mixture of rare earth elements in an atomic ratio of the rare earth elements to silver of 10 or less, preferably 0.2 to 2.0; and a heat-resistant oxide carrier such as alumina, silica, magnesia, titania, zirconia, beryllia or thoria.

摘要翻译： 一种使用催化剂蒸发重整烃的方法，该催化剂包含每重量催化剂至少3重量％，优选10至30重量％的镍，每100g催化剂至少2毫克原子银; 如果需要，稀土元素与稀土元素与银的稀土元素中的至少一种稀土元素如镧，铈，钇，镨，新二锑或稀土元素的混合物为10以下，优选为0.2〜2.0; 和氧化铝，二氧化硅，氧化镁，二氧化钛，氧化锆，氧化铍或氧化钍等耐热氧化物载体。

公开(公告)号：US4436794A

公开(公告)日：1984-03-13

申请号：US362056

申请日：1982-03-26

申请人： Masato Takeuchi ,  Hideo Okada ,  Hirosi Tobita ,  Sigeru Okabe ,  Shinpei Matsuda ,  Munehiko Tonami ,  Kohki Tamura ,  Fumito Nakajima

发明人： Masato Takeuchi ,  Hideo Okada ,  Hirosi Tobita ,  Sigeru Okabe ,  Shinpei Matsuda ,  Munehiko Tonami ,  Kohki Tamura ,  Fumito Nakajima

IPC分类号： H01M4/86 ,  H01M4/90 ,  H01M8/14

CPC分类号： H01M8/142 ,  H01M4/8621 ,  H01M4/9016 ,  H01M2004/8684 ,  H01M2004/8689 ,  H01M2008/147 ,  H01M2300/0051 ,  Y02E60/526

摘要： In a molten carbonate fuel cell, an anode or cathode is made of a sintered material containing a nickel oxide and/or cobalt oxide and a rare earth element oxide. This anode or cathode has a high activity and is stable at high temperatures.

摘要翻译： 在熔融碳酸盐燃料电池中，阳极或阴极由含有氧化镍和/或氧化钴和稀土元素氧化物的烧结材料制成。 该阳极或阴极具有高活性并且在高温下是稳定的。

公开(公告)号：US5059576A

公开(公告)日：1991-10-22

申请号：US565211

申请日：1990-08-08

申请人： Yasuyoshi Kato ,  Fumito Nakajima ,  Ikuhisa Hamada ,  Masahiro Nitta ,  Kunihiko Konishi ,  Toshiaki Matsuda ,  Naomi Yoshida ,  Nobuyoshi Ishida ,  Hitoshi Yamasaki

发明人： Yasuyoshi Kato ,  Fumito Nakajima ,  Ikuhisa Hamada ,  Masahiro Nitta ,  Kunihiko Konishi ,  Toshiaki Matsuda ,  Naomi Yoshida ,  Nobuyoshi Ishida ,  Hitoshi Yamasaki

IPC分类号： B01D53/86 ,  B01J23/22 ,  B01J23/24 ,  B01J35/06

CPC分类号： B01J35/06 ,  B01D53/8628 ,  B01J23/22 ,  B01J23/24

摘要： A catalyst or a catalyst structure for removing nitrogen oxides contained in exhaust gases, having a small pressure loss and hard to cause ash deposition, and a process for producing the same are provided, which catalyst comprises a mixture of a catalyst composition of titanium oxide and at least one member of oxides of vanadium, molybdenum and tungsten, and inorganic fibers, the clearances of the inorganic fibers are filled with said catalyst composition; the ration by weight of said catalyst composition to said inorganic fibers is 3 or more; and the apparent density of said catalyst is 0.8 g/cm.sup.3 or more; and which process comprises providing a composition containing titanium oxide and at least one member of oxides of vanadium, molybdenum and tungsten, calcining said composition at 500.degree.-650.degree. C., crushing the calcined material so that powder of 20.mu. or less can occupy 90% by weight or more of the crushed material, adding water to the crushed material to form a slurry, impregnating an inorganic fiber sheet with the above slurry, placing the resulting sheet between porous molds, drying and molding it, and clacining the resulting molded material at 300.degree.-650.degree. C.

公开(公告)号：US5409681A

公开(公告)日：1995-04-25

申请号：US980182

申请日：1992-11-23

申请人： Yasuyoshi Kato ,  Kunihiko Konishi ,  Fumito Nakajima ,  Ikuhisa Hamada ,  Isato Morita

发明人： Yasuyoshi Kato ,  Kunihiko Konishi ,  Fumito Nakajima ,  Ikuhisa Hamada ,  Isato Morita

IPC分类号： B01D53/94 ,  B01J23/40 ,  B01J23/652 ,  B01J37/02 ,  B01J8/00 ,  B01J21/04

CPC分类号： B01J37/0201 ,  B01D53/9418 ,  B01J23/40 ,  B01J23/652 ,  B01D2251/2062 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776

摘要： A catalyst for purifying an exhaust gas includes a first component having activity for reducing nitrogen oxides with ammonia and a second component having at least one of activity for forming nitrogen oxide from ammonia and activity for forming carbon dioxide from carbon monoxide. The first component is a composition containing an oxide of at least one member selected from titanium, vanadium, tungsten and molybdenum and the second component is a composition containing a salt of a noble metal selected from platinum, palladium and rhodium or any one of these noble metals supported on a porous material selected from zeolites, alumina and silica. The invention further provides a method for purifying an exhaust gas containing NOx, CO and leak NH.sub.3 using the catalyst.

摘要翻译： 用于净化废气的催化剂包括具有用氨还原氮氧化物的活性的第一成分和具有从氨形成氮氧化物的活性中的至少一种和从一氧化碳形成二氧化碳的活性中的至少一种的第二成分。 第一组分是含有选自钛，钒，钨和钼中的至少一种的氧化物的组合物，第二组分是含有选自铂，钯和铑的贵金属的盐或这些贵金属中的任何一种的组合物 负载在选自沸石，氧化铝和二氧化硅的多孔材料上的金属。 本发明还提供一种使用催化剂净化含有NOx，CO和泄漏NH 3的废气的方法。