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公开(公告)号：US07056446B2
公开(公告)日：2006-06-06
申请号：US10662886
申请日：2003-09-16
申请人： Takashi Nagase , Tohru Kubota , Shinro Mashiko
发明人： Takashi Nagase , Tohru Kubota , Shinro Mashiko
IPC分类号： B44C1/22
CPC分类号： H01L21/0332 , G01N27/07 , H01L21/32139 , H01L21/76838 , Y10S977/722
摘要： A method of easily manufacturing a nano-gap electrode by using a focused ion beam lithography includes a layer depositing step of depositing an electrode layer and a metal mask layer in this order on an insulating substrate, a mask pattern forming step of etching the metal mask layer by using the focused ion beam and thereby forming a mask pattern, a dry etching step of transferring a pattern to the electrode layer by dry etching, and a wet etching step of removing the metal mask layer by using a solution that selectively dissolves the metal mask layer compared to the electrode layer.
摘要翻译： 通过使用聚焦离子束光刻法容易地制造纳米间隙电极的方法包括在绝缘基板上依次沉积电极层和金属掩模层的层沉积步骤，蚀刻金属掩模的掩模图案形成步骤 通过使用聚焦离子束形成掩模图案的干蚀刻步骤，通过干蚀刻将图案转印到电极层的干蚀刻步骤以及通过使用选择性溶解金属的溶液去除金属掩模层的湿蚀刻步骤 掩模层与电极层相比。
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公开(公告)号：US07918982B2
公开(公告)日：2011-04-05
申请号：US11961445
申请日：2007-12-20
申请人： Hiroyuki Hasegawa , Tohru Kubota , Shinro Mashiko
发明人： Hiroyuki Hasegawa , Tohru Kubota , Shinro Mashiko
CPC分类号： B82Y10/00 , C25D9/02 , H01L51/0048 , H01L51/0078 , H01L51/0504 , Y10S977/72 , Y10S977/762 , Y10S977/899 , Y10T29/49117 , Y10T29/49155 , Y10T29/49156
摘要： The object of the disclosure is to provide a nano-scale molecular assembly such as a conductive nano-wire. Specifically, there is provided an electrochemical apparatus for forming a molecular assembly, including two electrodes and an electrochemical cell holding an electrolytic solution and the two electrodes, wherein the gap between the two electrodes is from 1 nm to 100 μm, by allowing the electrochemical cell to hold an electrolytic solution containing molecules that is to constitute the molecular assembly, and applying a voltage across the two electrodes in the state wherein the electrolyte and the two electrodes are in contact.
摘要翻译： 本公开的目的是提供纳米级分子组件，例如导电纳米线。 具体地说，提供一种用于形成分子组件的电化学装置，包括两个电极和一个保持电解液的电化学电池和两个电极，其中两个电极之间的间隙为1nm至100μm，通过允许电化学电池 以保持含有构成分子组装体的分子的电解液，并且在电解质和两个电极接触的状态下，在两个电极之间施加电压。
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公开(公告)号：US20050138804A1
公开(公告)日：2005-06-30
申请号：US10506668
申请日：2003-03-07
申请人： Hiroyuki Hasegawa , Tohru Kubota , Shinro Mashiko
发明人： Hiroyuki Hasegawa , Tohru Kubota , Shinro Mashiko
CPC分类号： B82Y10/00 , C25D9/02 , H01L51/0048 , H01L51/0078 , H01L51/0504 , Y10S977/72 , Y10S977/762 , Y10S977/899 , Y10T29/49117 , Y10T29/49155 , Y10T29/49156
摘要： The object of the present invention is to provide a nano-scale molecular assembly such as a conductive nano-wire. Specifically, there is provided an electrolytic apparatus for forming a molecular assembly, including two electrodes and an electrolytic cell holding an electrolyte and the two electrodes, wherein the gap between the two electrodes is from 1 nm to 100 μm, by allowing the electrolytic cell to hold an electrolyte containing molecules that is to constitute the molecular assembly, and applying a voltage across the two electrodes in the state wherein the electrolyte and the two electrodes are in contact.
摘要翻译： 本发明的目的是提供诸如导电纳米线的纳米级分子组件。 具体地说，提供了一种用于形成分子组件的电解装置，包括两个电极和一个保持电解质的电解槽和两个电极，其中两个电极之间的间隙为1nm至100μm，通过使电解槽 保持含有构成分子组件的分子的电解质，并且在电解质和两个电极接触的状态下在两个电极之间施加电压。
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公开(公告)号：US20110162968A1
公开(公告)日：2011-07-07
申请号：US13034122
申请日：2011-02-24
申请人： Hiroyuki Hasegawa , Tohru Kubota , Shinro Mashiko
发明人： Hiroyuki Hasegawa , Tohru Kubota , Shinro Mashiko
CPC分类号： B82Y10/00 , C25D9/02 , H01L51/0048 , H01L51/0078 , H01L51/0504 , Y10S977/72 , Y10S977/762 , Y10S977/899 , Y10T29/49117 , Y10T29/49155 , Y10T29/49156
摘要： The object of the disclosure is to provide a nano-scale molecular assembly such as a conductive nano-wire. Specifically, there is provided an electrochemical apparatus for forming a molecular assembly, including two electrodes and an electrochemical cell holding an electrolytic solution and the two electrodes, wherein the gap between the two electrodes is from 1 nm to 100 μm, by allowing the electrochemical cell to hold an electrolytic solution containing molecules that is to constitute the molecular assembly, and applying a voltage across the two electrodes in the state wherein the electrolyte and the two electrodes are in contact.
摘要翻译： 本公开的目的是提供纳米级分子组件，例如导电纳米线。 具体地说，提供一种用于形成分子组件的电化学装置，包括两个电极和一个保持电解液的电化学电池和两个电极，其中两个电极之间的间隙为1nm至100μm，通过允许电化学电池 以保持含有构成分子组装体的分子的电解液，并且在电解质和两个电极接触的状态下，在两个电极之间施加电压。
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公开(公告)号：US07351313B2
公开(公告)日：2008-04-01
申请号：US10506668
申请日：2003-03-07
申请人： Hiroyuki Hasegawa , Tohru Kubota , Shinro Mashiko
发明人： Hiroyuki Hasegawa , Tohru Kubota , Shinro Mashiko
IPC分类号： C25B9/04
CPC分类号： B82Y10/00 , C25D9/02 , H01L51/0048 , H01L51/0078 , H01L51/0504 , Y10S977/72 , Y10S977/762 , Y10S977/899 , Y10T29/49117 , Y10T29/49155 , Y10T29/49156
摘要： The object of the present invention is to provide a nano-scale molecular assembly such as a conductive nano-wire. Specifically, there is provided an electrolytic apparatus for forming a molecular assembly, including two electrodes and an electrolytic cell holding an electrolyte and the two electrodes, wherein the gap between the two electrodes is from 1 nm to 100 μm, by allowing the electrolytic cell to hold an electrolyte containing molecules that is to constitute the molecular assembly, and applying a voltage across the two electrodes in the state wherein the electrolyte and the two electrodes are in contact.
摘要翻译： 本发明的目的是提供诸如导电纳米线的纳米级分子组件。 具体地说，提供了一种用于形成分子组件的电解装置，包括两个电极和一个保持电解质的电解槽和两个电极，其中两个电极之间的间隙为1nm至100μm，通过使电解槽 保持含有构成分子组件的分子的电解质，并且在电解质和两个电极接触的状态下在两个电极之间施加电压。
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公开(公告)号：US20080076869A1
公开(公告)日：2008-03-27
申请号：US11898411
申请日：2007-09-12
申请人： Seiichi Furumi , Akira Otomo , Shinro Mashiko
发明人： Seiichi Furumi , Akira Otomo , Shinro Mashiko
IPC分类号： C08G73/02
CPC分类号： C08G83/003 , B82Y30/00 , C07C233/40 , C08F291/00 , C08G73/02 , C08G73/0206 , C08G73/0672
摘要： An object of the present invention is to provide a method of effectively producing a nano-particle and a nano-wire, and others. Specifically, the present invention provides a method of producing a molecular device including: the use of a molecular structure having a higher atomic density in the periphery than in the interior and bonding residues in the periphery; and a step of crosslinking the bonding residues, and the method of producing a molecular device according to claim 1, characterized in that the molecular structure is constituted by a skeleton portion having a skeleton structure, and a terminal portion which is arranged in the outer shell of the skeleton portion, has a higher atomic density than that of the skeleton portion and has bonding residues; and that in the step of crosslinking the bonding residues, the bonding residues in the terminal portion of the molecular structure are crosslinked to form the molecular structure into a shell structure, and others.
摘要翻译： 本发明的目的是提供一种有效地制造纳米颗粒和纳米线等的方法。 具体地说，本发明提供了一种分子装置的制造方法，其特征在于，在周边比在内部使用具有较高的原子密度的分子结构，并且在周边中键合残基; 权利要求1所述的分子装置的制造方法，其特征在于，所述分子结构由具有骨架结构的骨架部和所述外壳中配置的末端部构成 的骨架部分具有比骨架部分更高的原子密度并具有结合残基; 并且在交联键合残基的步骤中，分子结构的末端部分中的键合残基被交联以形成壳结构等分子结构。
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公开(公告)号：US07038217B2
公开(公告)日：2006-05-02
申请号：US11104443
申请日：2005-04-13
IPC分类号： B01D59/44
CPC分类号： H01J49/162 , H01J49/0422 , H01J49/0445
摘要： Here is disclosed a method for generation of a molecular beam from a sample solution, comprising steps of operating a spray-in device to introduce the sample solution in atomized state into a spray chamber, impinging a suitable gas on the sample solution in atomized state or heating the sample solution in atomized state to generate solute molecules deprived of solvent molecules, and then ejecting these solute molecules through an orifice into a low air pressure chamber. The apparatus as well as the method according to the present invention enable to generate a molecular beam for a variety of molecules, particularly for the neutral molecules which can be decomposed by heating at a high temperature or those which can not be sublimated or vaporized even by heating at a high temperature, as long as the sample solutions are prepared. Due to the method as well as the apparatus according to the invention, it is possible to conduct the mass spectroscopy studies and also other spectroscopic analyses about the molecules and the molecular clusters containing in the molecular beam generated in this manner, for example, by irradiating laser beams. It is possible to also possible to deposit the molecules on a substrate.
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公开(公告)号：US07285604B2
公开(公告)日：2007-10-23
申请号：US10509380
申请日：2003-03-26
申请人： Seiichi Furumi , Akira Otomo , Shinro Mashiko
发明人： Seiichi Furumi , Akira Otomo , Shinro Mashiko
CPC分类号： C08G83/003 , B82Y30/00 , C07C233/40 , C08F291/00 , C08G73/02 , C08G73/0206 , C08G73/0672
摘要： An object of the present invention is to provide a method of effectively producing a nano-particle and a nano-wire, and others.Specifically, the present invention provides a method of producing a molecular device including: the use of a molecular structure having a higher atomic density in the periphery than in the interior and bonding residues in the periphery; and a step of crosslinking the bonding residues, and the method of producing a molecular device according to claim 1, characterized in that the molecular structure is constituted by a skeleton portion having a skeleton structure, and a terminal portion which is arranged in the outer shell of the skeleton portion, has a higher atomic density than that of the skeleton portion and has bonding residues; and that in the step of crosslinking the bonding residues, the bonding residues in the terminal portion of the molecular structure are crosslinked to form the molecular structure into a shell structure, and others.
摘要翻译： 本发明的目的是提供一种有效地制造纳米颗粒和纳米线等的方法。 具体地说，本发明提供了一种分子装置的制造方法，其特征在于，在周边比在内部使用具有较高的原子密度的分子结构，并且在周边中键合残基; 权利要求1所述的分子装置的制造方法，其特征在于，所述分子结构由具有骨架结构的骨架部和所述外壳中配置的末端部构成 的骨架部分具有比骨架部分更高的原子密度并具有结合残基; 并且在交联键合残基的步骤中，分子结构的末端部分中的键合残基被交联以形成壳结构等分子结构。
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9.发明申请Process for producing nano-device using potential singular points on substrate 失效在衬底上使用潜在的奇异点生产纳米器件的方法公开(公告)号：US20050023140A1
公开(公告)日：2005-02-03
申请号：US10886056
申请日：2004-07-08
CPC分类号： C25D1/18 , Y10S977/888 , Y10S977/896
摘要： The present invention provides a process for producing a bottom-up type nano-device in which a reaction is initiated from potential singular points on a substrate, and wherein compound molecules are arranged with regularity and a chain reaction is accelerated utilizing the sequence pattern of the potential singular points, specifically, the process comprises a step of producing potential singular points that involves placing potential singular points on a substrate and a contact step of contacting a compound having a functional group which interacts with the fore-mentioned potential singular points.
摘要翻译： 本发明提供了一种自底向上型纳米器件的制造方法，其中从衬底上的潜在奇点开始反应，并且其中化合物分子被规则地排列，并且使用序列模式来加速连锁反应 特别地，该方法包括产生潜在的奇异点的步骤，该步骤涉及将潜在的奇异点放置在基底上，以及使具有与上述潜在奇异点相互作用的官能团的化合物接触的接触步骤。
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公开(公告)号：US07205428B2
公开(公告)日：2007-04-17
申请号：US10346078
申请日：2003-01-17
IPC分类号： C07C323/00
CPC分类号： C08G83/003 , C08G75/0204 , C08L81/02
摘要： The present invention is directed to novel thioether dendritic molecules which respond immediately by emission of light when stimulated with light or electric energy.
摘要翻译： 本发明涉及当用光或电能刺激时立即响应光发射的新型硫醚树枝状分子。
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