公开(公告)号：US06479578B2

公开(公告)日：2002-11-12

申请号：US09797693

申请日：2001-03-05

申请人： Takayuki Araki ,  Masahiro Kumegawa ,  Tsuyoshi Miyamori ,  Masami Kato ,  Masaji Komori ,  Taketo Kato ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Masahiro Kumegawa ,  Tsuyoshi Miyamori ,  Masami Kato ,  Masaji Komori ,  Taketo Kato ,  Tetsuo Shimizu

IPC分类号： C08F800

CPC分类号： C08L27/12 ,  C08K3/01 ,  C08K3/013 ,  C08L27/18 ,  C08L2205/02 ,  H05K1/034 ,  H05K1/0373 ,  C08L2666/04

摘要： A resin composition which gives a molded article having both of excellent mechanical properties and abrasion resistance with maintaining excellent thermal resistance, chemical resistance, surface characteristics (non-sticking property, low friction property), electric insulating property, etc. of a fluorine-containing polymer; a molded article obtained from the resin composition; and a method for producing the molded article are provided. The resin composition comprises: (A-1) a fluorine-containing ethylenic polymer prepared by copolymerizing at least one of fluorine-containing monomers having any one of hydroxyl, carboxyl, a carboxylate salt group, a carboxylate ester group or epoxy in an amount of 0.05 to 30% by mole on the basis of the total amount of monomers, and (B-1) an inorganic filler or a non-meltable organic filler, wherein said resin composition comprises 1 to 99.5% by weight of the component (A-1) and 0.5 to 99% by weight of the component (B-1).

摘要翻译： 赋予具有优异的机械性能和耐磨性两者的保持优异的含氟的耐热性，耐化学性，表面特性（不粘附性，低摩擦性），电绝缘性等的成型体的树脂组合物 聚合物; 由树脂组合物得到的成型体; 并提供了制造模制品的方法。 树脂组合物包含：（A-1）通过使具有羟基，羧基，羧酸盐基，羧酸酯基或环氧基中的任一个的含氟单体的至少一种共聚合而制备的含氟乙烯性聚合物的量为 基于单体总量为0.05〜30摩尔％，和（B-1）无机填料或不可熔融有机填料，其中所述树脂组合物包含1-99.5重量％的组分（A- 1）和0.5〜99重量％的成分（B-1）。

公开(公告)号：US06225399B1

公开(公告)日：2001-05-01

申请号：US09065032

申请日：1998-04-27

申请人： Takayuki Araki ,  Masahiro Kumegawa ,  Tsuyoshi Miyamori ,  Masami Kato ,  Masaji Komori ,  Taketo Kato ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Masahiro Kumegawa ,  Tsuyoshi Miyamori ,  Masami Kato ,  Masaji Komori ,  Taketo Kato ,  Tetsuo Shimizu

IPC分类号： C08F800

CPC分类号： C08L27/12 ,  C08K3/01 ,  C08K3/013 ,  C08L27/18 ,  C08L2205/02 ,  H05K1/034 ,  H05K1/0373 ,  C08L2666/04

摘要： A resin composition which gives a molded article having both of excellent mechanical properties and abrasion resistance with maintaining excellent thermal resistance, chemical resistance, surface characteristics (non-sticking property, low friction property), electric insulating property, etc. of a fluorine-containing polymer; a molded article obtained from the resin composition; and a method for producing the molded article are provided. The resin composition comprises: (A-1) a fluorine-containing ethylenic polymer prepared by copolymerizing at least one of fluorine-containing monomers having any one of hydroxyl, carboxyl, a carboxylate salt group, a carboxylate ester group or epoxy in an amount of 0.05 to 30% by mole on the basis of the total amount of monomers, and (B-1) an inorganic filler or a non-meltable organic filler, wherein said resin composition comprises 1 to 99.5% by weight of the component (A-1) and 0.5 to 99% by weight of the component (B-1).

摘要翻译： 赋予具有优异的机械性能和耐磨性两者的保持优异的含氟的耐热性，耐化学性，表面特性（不粘附性，低摩擦性），电绝缘性等的成型体的树脂组合物 聚合物; 由树脂组合物得到的成型体; 并提供了制造模制品的方法。 树脂组合物包含：（A-1）通过使具有羟基，羧基，羧酸盐基，羧酸酯基或环氧基中的任一个的含氟单体的至少一种共聚合而制备的含氟乙烯性聚合物的量为 基于单体总量为0.05〜30摩尔％，和（B-1）无机填料或不可熔融有机填料，其中所述树脂组合物包含1-99.5重量％的组分（A- 1）和0.5〜99重量％的成分（B-1）。

公开(公告)号：US06726994B1

公开(公告)日：2004-04-27

申请号：US09856066

申请日：2001-05-17

申请人： Takayuki Araki ,  Tsuyoshi Miyamori ,  Masaji Komori ,  Yoshito Tanaka ,  Masahiro Kumegawa

发明人： Takayuki Araki ,  Tsuyoshi Miyamori ,  Masaji Komori ,  Yoshito Tanaka ,  Masahiro Kumegawa

IPC分类号： B32B1508

CPC分类号： B32B27/08 ,  B32B27/06 ,  B32B27/20 ,  B32B2307/306 ,  B32B2323/04 ,  B32B2379/08 ,  C09D161/06 ,  C09D179/08 ,  C10M169/00 ,  C10M2201/041 ,  C10M2201/066 ,  C10M2213/062 ,  C10M2217/0403 ,  C10M2217/0443 ,  C10N2230/06 ,  C10N2240/02 ,  C10N2250/141 ,  C23C28/00 ,  F16C33/201 ,  H01G7/021 ,  Y02T10/7022 ,  Y10T428/31504 ,  Y10T428/31533 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31678 ,  Y10T428/31721 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31942

摘要： The structural member of the present invention comprises (A) a layer which comprises a fluorine-containing polymer and does not contain an adhesive material other than the fluorine-containing polymer substantially and (B) a substrate, in which the layer (A) is adhered directly to the substrate (B) without interposing a binder therebetween and a longitudinal shear strength between the layer (A) comprising a fluorine-containing polymer and the substrate (B) is not less than 0.98 N/mm2 at 150° C. The structural member comprising a fluorine-containing polymer and a substrate adhered to each other, particularly the structural member having improved adhesive strength at high temperature and the sliding material produced by using the structural member are provided.

摘要翻译： 本发明的结构体包含（A）包含含氟聚合物的层，基本上不含含氟聚合物以外的粘合剂材料，（B）基材，其中层（A）为 在不插入粘合剂的情况下直接粘附到基板（B）上，并且包括含氟聚合物的层（A）和基板（B）之间的纵向剪切强度在150°时不小于0.98N / mm 2 C.包含含氟聚合物和彼此粘合的基材的结构件，特别是具有改善的高温粘合强度的结构件和使用结构件制成的滑动材料。

公开(公告)号：USRE41110E1

公开(公告)日：2010-02-09

申请号：US11512391

申请日：2006-08-30

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

IPC分类号： B32B27/00

CPC分类号： C08F214/262 ,  C08F293/00 ,  C08L53/00 ,  C09D153/00 ,  G03G15/2057 ,  Y10T428/1352

摘要： It is possible to provide the heat resistant material and coating material for OA equipment which comprise a fluorine-containing multi-segment polymer having heat resistance, abrasion resistance, non-sticking property against toner and oil resistance in addition to flexibility and are used particularly on surfaces of fuser roll and belt. Those materials comprise a fluorine-containing multi-segment polymer having an elastomeric fluorine-containing polymer chain segment A and a non-elastomeric fluorine-containing polymer chain segment B, and the elastomeric fluorine-containing polymer chain segment A comprises not less than 90% by mole of perhaloolefin unit as a recurring unit and imparts flexibility to the whole polymer.

摘要翻译： 可以提供包含含氟多层聚合物的OA设备的耐热材料和涂层材料，其具有耐热性，耐磨性，对调色剂的不粘附性和耐油性以及柔性，并且特别用于 定影辊和皮带的表面。 这些材料包括具有弹性体含氟聚合物链段A和非弹性含氟聚合物链段B的含氟多段聚合物，弹性体含氟聚合物链段A包含不少于90％ 的全卤代烯烃单元作为重复单元，并赋予整个聚合物柔性。

公开(公告)号：US06838139B2

公开(公告)日：2005-01-04

申请号：US10241490

申请日：2002-09-12

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

IPC分类号： C08F214/26 ,  C08F293/00 ,  C08L53/00 ,  C09D153/00 ,  G03G15/20 ,  B32B27/00

CPC分类号： C08F214/262 ,  C08F293/00 ,  C08L53/00 ,  C09D153/00 ,  G03G15/2057 ,  Y10T428/1352

摘要： It is possible to provide the heat resistant material and coating material for OA equipment which comprise a fluorine-containing multi-segment polymer having heat resistance, abrasion resistance, non-sticking property against toner and oil resistance in addition to flexibility and are used particularly on surfaces of fuser roll and belt. Those materials comprise a fluorine-containing multi-segment polymer having an elastomeric fluorine-containing polymer chain segment A and a non-elastomeric fluorine-containing polymer chain segment B, and the elastomeric fluorine-containing polymer chain segment A comprises not less than 90% by mole of perhaloolefin unit as a recurring unit and imparts flexibility to the whole polymer.

摘要翻译： 可以提供包含含氟多层聚合物的OA设备的耐热材料和涂层材料，其具有耐热性，耐磨性，对调色剂的不粘附性和耐油性以及柔性，并且特别用于 定影辊和皮带的表面。 这些材料包括具有弹性体含氟聚合物链段A和非弹性含氟聚合物链段B的含氟多段聚合物，弹性体含氟聚合物链段A包含不少于90％ 的全卤代烯烃单元作为重复单元，并赋予整个聚合物柔性。

公开(公告)号：US06476151B1

公开(公告)日：2002-11-05

申请号：US09582417

申请日：2000-08-11

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

IPC分类号： C08F25900

CPC分类号： C08F214/262 ,  C08F293/00 ,  C08L53/00 ,  C09D153/00 ,  G03G15/2057 ,  Y10T428/1352

摘要： It is possible to provide the heat resistant material and coating material for OA equipments which comprise a fluorine-containing multi-segment polymer having heat resistance, abrasion resistance, non-sticking property against toner and oil resistance in addition to flexibility and are used particularly on surfaces of fuser roll and belt. Those materials comprise a fluorine-containing multi-segment polymer having an elastomeric fluorine-containing polymer chain segment A and a non-elastomeric fluorine-containing polymer chain segment B, and the elastomeric fluorine-containing polymer chain segment A comprises not less than 90% by mole of perhaloolefin unit as a recurring unit and imparts flexibility to the whole polymer.

摘要翻译： 可以提供包含具有耐热性，耐磨性，对调色剂的不粘附性和耐油性的含氟多段聚合物的OA设备的耐热材料和涂料以及柔软性，并且特别地用于 定影辊和皮带的表面。 这些材料包括具有弹性体含氟聚合物链段A和非弹性含氟聚合物链段B的含氟多段聚合物，弹性体含氟聚合物链段A包含不少于90％ 的全卤代烯烃单元作为重复单元，并赋予整个聚合物柔性。

公开(公告)号：US5986150A

公开(公告)日：1999-11-16

申请号：US856594

申请日：1997-05-15

申请人： Takayuki Araki ,  Tetsuo Shimizu ,  Takafumi Yamato ,  Masahiro Kumegawa ,  Yoshihisa Yamamoto

发明人： Takayuki Araki ,  Tetsuo Shimizu ,  Takafumi Yamato ,  Masahiro Kumegawa ,  Yoshihisa Yamamoto

IPC分类号： C07C33/42 ,  C07C43/178 ,  C07C57/52 ,  C07C69/708 ,  C07D303/24 ,  C08F14/18 ,  C08F214/18 ,  C08F216/14 ,  C08F220/22 ,  C08L27/12 ,  C08L67/00 ,  C08L67/02 ,  C08L69/00 ,  C08L77/00 ,  C07C41/00 ,  C07D303/08

CPC分类号： C08L27/12 ,  C07C33/423 ,  C07C43/178 ,  C07C57/52 ,  C07C69/708 ,  C07D303/24 ,  C08F14/185 ,  C08F214/184 ,  C08L67/00 ,  C08L67/02 ,  C08L69/00 ,  C08L2205/02 ,  C08L77/00

摘要： To provide a fluorine-containing olefin represented, for example, by CH.sub.2 .dbd.CFCF.sub.2 --R.sub.f.sup.6 --(CH.sub.2).sub.k --X.sup.2 [wherein, X.sup.2 is ##STR1## R.sub.f.sup.6 is a fluorine-substituted fluorine-containing alkyl group having 1 to 40 carbon atoms or --OR.sub.f.sup.7 --(Rf.sup.7 is a fluorine-substituted fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-substituted fluorine-containing ether group having 3 to 50 carbon atoms), k is 0 or an integer of 1 to 6]; a fluorine-containing polymer with functional group which is prepared by polymerizing the above-mentioned olefin, has good affinity with various heat-resisting thermoplastic resins and is capable of forming homogeneous dispersion with the thermoplastic resin; and a thermoplastic resin composition comprising the above-mentioned fluorine-containing polymer with functional group and an aromatic polyester or the like as the heat-resisting thermoplastic resin.

摘要翻译： 提供例如通过CH 2 = CFCF 2 -R f 6 - （CH 2）k -X 2表示的含氟烯烃[其中，X 2是Rf 6是具有1〜40个碳原子的氟取代的含氟烷基或-OR f7 - （Rf7为碳原子数为1〜40的氟取代的含氟烷基或碳原子数为3〜50的氟取代的含氟醚基），k为0或1〜6的整数]。 通过聚合上述烯烃制备的具有官能团的含氟聚合物与各种耐热性热塑性树脂具有良好的亲和性，并且能够与热塑性树脂形成均匀的分散体; 以及包含上述具有官能团的含氟聚合物和芳族聚酯等作为耐热性热塑性树脂的热塑性树脂组合物。

公开(公告)号：US5869574A

公开(公告)日：1999-02-09

申请号：US838063

申请日：1997-04-17

申请人： Tetsuo Shimizu ,  Yoshihisa Yamamoto ,  Seitaro Yamaguchi ,  Nobuhiko Tsuda ,  Noriyasu Yamane ,  Takafumi Yamato ,  Masahiro Kumegawa ,  Takayuki Araki

发明人： Tetsuo Shimizu ,  Yoshihisa Yamamoto ,  Seitaro Yamaguchi ,  Nobuhiko Tsuda ,  Noriyasu Yamane ,  Takafumi Yamato ,  Masahiro Kumegawa ,  Takayuki Araki

IPC分类号： C08G59/30 ,  C08G59/32 ,  C08G61/12 ,  C08L27/12 ,  C08L27/16 ,  C08L67/00 ,  C08L67/02 ,  C08L67/03 ,  C08L69/00 ,  C08L71/10 ,  C08L77/00 ,  C08L77/02 ,  C08L77/06 ,  C08L81/04 ,  C08L101/00

CPC分类号： C08L77/06 ,  C08G59/30 ,  C08G59/3254 ,  C08G61/12 ,  C08L101/00 ,  C08L27/12 ,  C08L27/16 ,  C08L67/00 ,  C08L67/02 ,  C08L67/03 ,  C08L69/00 ,  C08L77/00 ,  C08L77/02 ,  C08L81/04 ,  C08L2201/00

摘要： A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150.degree. C. The present invention can provide a composition comprising various heat resisting thermoplastic resins and a fluorine-containing polymer having a functional group which is capable of developing an affinity with said resins and forming a uniform dispersion.

公开(公告)号：US06207236B1

公开(公告)日：2001-03-27

申请号：US09202592

申请日：1998-12-17

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Tetsuo Shimizu

IPC分类号： B05D302

CPC分类号： C09D127/12 ,  C09D127/18 ,  C08L2666/54

摘要： To provide the water-repellent coating film having excellent transparency, abrasion resistance, weather resistance and water repellency, the method for producing the coating film, the multi-functional composite material provided with the coating film and the coating composition used therefor which has excellent dispersion stability. The coating composition comprises (A) the fluorine-containing ethylenic polymer prepared by copolymerizing a fluorine-containing ethylenic monomer having at least one functional group selected from hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, (B-1) the metal oxide sol, and (C) the solvent.

摘要翻译： 为了提供具有优异的透明性，耐磨性，耐候性和防水性的防水涂膜，涂膜的制备方法，设置有涂膜的多功能复合材料及其所用的涂料组合物具有优异的分散性 稳定性。 涂料组合物包含（A）通过共聚含有至少一个选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基的官能团的含氟乙烯性单体制备的含氟乙烯性聚合物（B-1 ）金属氧化物溶胶，和（C）溶剂。

公开(公告)号：US5750626A

公开(公告)日：1998-05-12

申请号：US284548

申请日：1994-08-09

申请人： Tetsuo Shimizu ,  Yoshihisa Yamamoto ,  Seitaro Yamaguchi ,  Nobuhiko Tsuda ,  Noriyasu Yamane ,  Takafumi Yamato ,  Masahiro Kumegawa ,  Takayuki Araki

发明人： Tetsuo Shimizu ,  Yoshihisa Yamamoto ,  Seitaro Yamaguchi ,  Nobuhiko Tsuda ,  Noriyasu Yamane ,  Takafumi Yamato ,  Masahiro Kumegawa ,  Takayuki Araki

IPC分类号： C08G59/30 ,  C08G59/32 ,  C08G61/12 ,  C08L27/12 ,  C08L27/16 ,  C08L67/00 ,  C08L67/02 ,  C08L67/03 ,  C08L69/00 ,  C08L71/10 ,  C08L77/00 ,  C08L77/02 ,  C08L77/06 ,  C08L81/04 ,  C08L101/00

CPC分类号： C08L77/06 ,  C08G59/30 ,  C08G59/3254 ,  C08G61/12 ,  C08L101/00 ,  C08L27/12 ,  C08L27/16 ,  C08L67/00 ,  C08L67/02 ,  C08L67/03 ,  C08L69/00 ,  C08L77/00 ,  C08L77/02 ,  C08L81/04 ,  C08L2201/00

摘要： A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150.degree. C. The present invention can provide a composition comprising various heat resisting thermoplastic resins and a fluorine-containing polymer having a functional group which is capable of developing an affinity with said resins and forming a uniform dispersion.

摘要翻译： PCT No.PCT / JP93 / 01784 Sec。 371日期1994年8月9日 102（e）日期1994年8月9日PCT提交1993年12月8日PCT公布。 第WO94 / 13738号公报 日期1994年6月23日一种热塑性树脂组合物，其包含通过将（a）数均分子量为2000〜1000000的含氟聚合物与至少具有羟基或环氧基的0.1〜99重量％ 在聚合物的主链和侧链的一个端部和1至99.9重量％的（b）具有不低于150℃的结晶熔点或玻璃化转变温度的耐热性热塑性树脂。 本发明可以提供包含各种耐热性热塑性树脂的组合物和具有能够与所述树脂形成亲和性并形成均匀分散体的官能团的含氟聚合物。