公开(公告)号：US07834120B2

公开(公告)日：2010-11-16

申请号：US11242078

申请日：2005-10-04

申请人： Ayumu Kiyomori ,  Tohru Kubota ,  Yasufumi Kubota ,  Takayuki Honma

发明人： Ayumu Kiyomori ,  Tohru Kubota ,  Yasufumi Kubota ,  Takayuki Honma

IPC分类号： C08G77/20

CPC分类号： C07F7/21

摘要： A novel monofunctional monomer having a cage oligosiloxane structure is represented by formula (1) wherein X is a polymerizable oxygen-containing C1-C40 group, R1 is a C1-C20 saturated hydrocarbon group, C6-C20 aromatic hydrocarbon group, C1-C20 organoxy group or halogen atom, and R is a non-polymerizable monovalent C1-C40 hydrocarbon group which is optionally halogenated. The monomer has improved compatibility with various solvents and polymerizable monomers. A method for preparing the same is also provided.

摘要翻译： 具有笼低聚硅氧烷结构的新型单官能单体由式（1）表示，其中X为可聚合含氧C1-C40基团，R1为C1-C20饱和烃基，C6-C20芳族烃基，C1-C20有机氧基 基团或卤素原子，R是任选卤代的不可聚合的单价C1-C40烃基。 单体具有改善的与各种溶剂和可聚合单体的相容性。 还提供了制备该方法。

公开(公告)号：US08927754B2

公开(公告)日：2015-01-06

申请号：US13445074

申请日：2012-04-12

申请人： Takayuki Honma ,  Ayumu Kiyomori ,  Tohru Kubota ,  Daijitsu Harada ,  Hiroyuki Yamazaki ,  Masaki Takeuchi

发明人： Takayuki Honma ,  Ayumu Kiyomori ,  Tohru Kubota ,  Daijitsu Harada ,  Hiroyuki Yamazaki ,  Masaki Takeuchi

IPC分类号： C07F7/12 ,  C07F7/10

CPC分类号： C07F7/10

摘要： Disclosed are silazane compounds having two fluoroalkyl groups, represented by the following general formula (1): wherein Rf and Rf′ are each a fluoroalkyl group, R1 is a hydrogen atoms or an aliphatic monovalent hydrocarbon group, R2 and R3 are each an aliphatic monovalent hydrocarbon group, R4 is a hydrogen atom or an aliphatic monovalent hydrocarbon group, a and b are each 0 or 1, m, n and p are each an integer of 0 to 6, q is an integer of 1 to 6, and r is 1 or 2. By treating an inorganic material with the silazane compound having two fluoroalkyl groups, high water and oil repellency and high sliding properties can be imparted to the inorganic material in good balance.

摘要翻译： 公开了具有两个氟烷基的硅氮烷化合物，由以下通式（1）表示：其中Rf和Rf'各自为氟烷基，R 1为氢原子或脂族一价烃基，R 2和R 3各自为脂族一价 烃基，R4为氢原子或脂肪族一价烃基，a和b分别为0或1，m，n和p分别为0〜6的整数，q为1〜6的整数，r为 通过用具有两个氟代烷基的硅氮烷化合物处理无机材料，可以很好地赋予无机材料高斥水性和高滑动性。

公开(公告)号：US20120006229A1

公开(公告)日：2012-01-12

申请号：US13179142

申请日：2011-07-08

申请人： Takayuki Honma ,  Tohru Kubota ,  Ayumu Kiyomori

发明人： Takayuki Honma ,  Tohru Kubota ,  Ayumu Kiyomori

IPC分类号： C09K3/00 ,  C09J1/00

CPC分类号： C07F7/0836 ,  C08G77/26

摘要： An aqueous solution contains a piperazinyl-containing silanol compound having formula (1) wherein R1 is a monovalent hydrocarbon group and n is 0, 1 or 2 and a dehydrated condensate thereof, with a volatile alcohol content being less than 10 wt %.

摘要翻译： 水溶液含有具有式（1）的含哌嗪基的硅烷醇化合物，其中R1是一价烃基，n是0,1或2，其脱水缩合物的挥发性醇含量小于10重量％。

公开(公告)号：US20100099866A1

公开(公告)日：2010-04-22

申请号：US12582026

申请日：2009-10-20

申请人： Takayuki Honma ,  Tohru Kubota ,  Ayumu Kiyomori

发明人： Takayuki Honma ,  Tohru Kubota ,  Ayumu Kiyomori

IPC分类号： C07F7/08 ,  C07F7/02 ,  C07F7/10

CPC分类号： C07F7/1804

摘要： An organosilicon compound having an amino group is provided. This compound is represented by the following general formula (1): wherein R1 and R2 respectively represent an unsubstituted or substituted aliphatic monovalent hydrocarbon group containing 1 to 10 carbon atoms with the proviso that the R1 and R2 may together form a ring with the nitrogen atom to which they are bonded, and that R1 and R2 may contain a heteroatom; R3 and R4 independently represent an unsubstituted or substituted monovalent hydrocarbon group containing 1 to 10 carbon atoms; and n represents an integer of 0 to 2. Use of this compound enables production of a polymer product having excellent mechanical properties, high heat resistance, and high transparency. The solution of this compound is stable, and can be stored for a long time, and when used for a polymer modifying agent, it facilitates introduction of amino group and hydroxy group.

摘要翻译： 提供具有氨基的有机硅化合物。 该化合物由以下通式（1）表示：其中R 1和R 2分别表示含有1至10个碳原子的未取代或取代的脂族一价烃基，条件是R 1和R 2可以与氮原子一起形成环 它们与它们键合，并且R 1和R 2可以含有杂原子; R3和R4独立地表示含有1至10个碳原子的未取代或取代的一价烃基; n表示0〜2的整数。该化合物的使用能够制造具有优异的机械性能，高耐热性和高透明性的聚合物制品。 该化合物的溶液是稳定的，可以长时间储存​​，当用于聚合物改性剂时，有利于氨基和羟基的引入。

公开(公告)号：US20060074213A1

公开(公告)日：2006-04-06

申请号：US11242078

申请日：2005-10-04

申请人： Ayumu Kiyomori ,  Tohru Kubota ,  Yasufumi Kubota ,  Takayuki Honma

发明人： Ayumu Kiyomori ,  Tohru Kubota ,  Yasufumi Kubota ,  Takayuki Honma

IPC分类号： C08G77/12 ,  C08G77/20

CPC分类号： C07F7/21

摘要： A novel monofunctional monomer having a cage oligosiloxane structure is represented by formula (1) wherein X is a polymerizable oxygen-containing C1-C40 group, R1 is a C1-C20 saturated hydrocarbon group, C6-C20 aromatic hydrocarbon group, C1-C20 organoxy group or halogen atom, and R is a non-polymerizable monovalent C1-C40 hydrocarbon group which is optionally halogenated. The monomer has improved compatibility with various solvents and polymerizable monomers. A method for preparing the same is also provided.

摘要翻译： 具有笼寡聚硅氧烷结构的新型单官能单体由式（1）表示，其中X是可聚合的含氧C 1 -C 40 - 基团，R 1 C 1 -C 20饱和烃基，C 6 -C 20芳族烃基，C 1 -C 20 - 饱和烃基，C 6 -C 20饱和烃基，C 6 -C 20 - 基团，C 1 -C 20有机氧基或卤素原子，R是不可聚合的单价C 1 -C 40 任选卤代的烃基。 单体具有改善的与各种溶剂和可聚合单体的相容性。 还提供了制备该方法。

公开(公告)号：US08049027B2

公开(公告)日：2011-11-01

申请号：US12582026

申请日：2009-10-20

申请人： Takayuki Honma ,  Tohru Kubota ,  Ayumu Kiyomori

发明人： Takayuki Honma ,  Tohru Kubota ,  Ayumu Kiyomori

IPC分类号： C07F7/04 ,  C07F7/07 ,  C07F7/08

CPC分类号： C07F7/1804

摘要： An organosilicon compound having an amino group is provided. This compound is represented by the following general formula (1): wherein R1 and R2 respectively represent an unsubstituted or substituted aliphatic monovalent hydrocarbon group containing 1 to 10 carbon atoms with the proviso that the R1 and R2 may together form a ring with the nitrogen atom to which they are bonded, and that R1 and R2 may contain a heteroatom; R3 and R4 independently represent an unsubstituted or substituted monovalent hydrocarbon group containing 1 to 10 carbon atoms; and n represents an integer of 0 to 2. Use of this compound enables production of a polymer product having excellent mechanical properties, high heat resistance, and high transparency. The solution of this compound is stable, and can be stored for a long time, and when used for a polymer modifying agent, it facilitates introduction of amino group and hydroxy group.

摘要翻译： 提供具有氨基的有机硅化合物。 该化合物由以下通式（1）表示：其中R 1和R 2分别表示含有1至10个碳原子的未取代或取代的脂族一价烃基，条件是R 1和R 2可以与氮原子一起形成环 它们与它们键合，并且R 1和R 2可以含有杂原子; R3和R4独立地表示含有1至10个碳原子的未取代或取代的一价烃基; n表示0〜2的整数。该化合物的使用能够制造具有优异的机械性能，高耐热性和高透明性的聚合物制品。 该化合物的溶液是稳定的，可以长时间储存​​，当用于聚合物改性剂时，有利于氨基和羟基的引入。

公开(公告)号：US20120264964A1

公开(公告)日：2012-10-18

申请号：US13444254

申请日：2012-04-11

申请人： Takayuki Honma ,  Ayumu Kiyomori ,  Tohru Kubota ,  Daijitsu Harada ,  Hiroyuki Yamazaki ,  Masaki Takeuchi

发明人： Takayuki Honma ,  Ayumu Kiyomori ,  Tohru Kubota ,  Daijitsu Harada ,  Hiroyuki Yamazaki ,  Masaki Takeuchi

IPC分类号： C07F7/18

CPC分类号： C07F7/1804

摘要： Alkoxysilane compounds having two fluoroalkyl groups and represented by the formula (1): wherein Rf and Rf′ are each a fluoroalkyl group of 1 to 10 carbon atoms, R1 is a hydrogen atom or an aliphatic monovalent hydrocarbon group of 1 to 6 carbon atoms, R2 and R3 are each methyl group or ethyl group, X and Y are each an ether linkage or an ester linkage, a and b are each 0 or 1, m, n and p are each an integer of 0 to 6, q is an integer of 1 to 6, and r is an integer of 0 to 2. By treating an inorganic material with the alkoxysilane compound having ether linkage and two fluoroalkyl groups, high water and oil repellency and high sliding properties are imparted to the inorganic material. The alkoxysilane compounds are easily purified, owing to enhanced volatility by the branched structure.

摘要翻译： 具有两个氟代烷基并由式（1）表示的烷氧基硅烷化合物：其中Rf和Rf'分别为1-10个碳原子的氟代烷基，R1是氢原子或1至6个碳原子的脂肪族单价烃基， R2和R3各自为甲基或乙基，X和Y各自为醚键或酯键，a和b各自为0或1，m，n和p各自为0至6的整数，q为 1〜6的整数，r为0〜2的整数。通过用具有醚键的烷氧基硅烷化合物和2个氟代烷基处理无机材料，赋予无机材料高拒油拒油性和高滑动性。 由于分支结构的挥发性增强，烷氧基硅烷化合物容易纯化。

公开(公告)号：US09090502B2

公开(公告)日：2015-07-28

申请号：US13444138

申请日：2012-04-11

申请人： Hiroyuki Yamazaki ,  Daijitsu Harada ,  Masaki Takeuchi ,  Takayuki Honma ,  Ayumu Kiyomori ,  Tohru Kubota

发明人： Hiroyuki Yamazaki ,  Daijitsu Harada ,  Masaki Takeuchi ,  Takayuki Honma ,  Ayumu Kiyomori ,  Tohru Kubota

IPC分类号： C07F7/04 ,  B29C59/00 ,  C03C17/30 ,  B29C37/00 ,  B82Y40/00 ,  C07F7/10 ,  C07F7/18

CPC分类号： C03C17/30 ,  B29C37/0067 ,  B82Y40/00 ,  C03C2217/76 ,  C03C2218/111 ,  C03C2218/15 ,  C03C2218/31 ,  C07F7/10 ,  C07F7/1804

摘要： A nanoimprint-mold release agent including an alkoxysilane compound represented by general formula (1) is provided wherein Rf and Rf′ are each independently a fluoroalkyl group of 1 to 10 carbon atoms; R1 is a hydrogen atom or an aliphatic monovalent hydrocarbon group of 1 to 6 carbon atoms; R2 and R3 are each independently methyl group or ethyl group; X and Y are each independently an ether linkage or an ester linkage; a and b are each 0 or 1; m, n, and p are each an integer of 0 to 6; q is an integer of 1 to 6 and r is an integer of 0 to 2.

摘要翻译： 提供了包含通式（1）表示的烷氧基硅烷化合物的纳米压印脱模剂，其中Rf和Rf'各自独立地为1-10个碳原子的氟代烷基; R1是氢原子或1〜6个碳原子的脂族一价烃基; R2和R3各自独立地为甲基或乙基; X和Y各自独立地是醚键或酯键; a和b分别为0或1; m，n和p分别为0〜6的整数。 q为1〜6的整数，r为0〜2的整数。

公开(公告)号：US08536359B2

公开(公告)日：2013-09-17

申请号：US13444254

申请日：2012-04-11

申请人： Takayuki Honma ,  Ayumu Kiyomori ,  Tohru Kubota ,  Daijitsu Harada ,  Hiroyuki Yamazaki ,  Masaki Takeuchi

发明人： Takayuki Honma ,  Ayumu Kiyomori ,  Tohru Kubota ,  Daijitsu Harada ,  Hiroyuki Yamazaki ,  Masaki Takeuchi

IPC分类号： C07F7/02

CPC分类号： C07F7/1804

摘要： Disclosed are alkoxysilane compounds having two fluoroalkyl groups and represented by the following general formula (1): wherein Rf and Rf′ are each a fluoroalkyl group of 1 to 10 carbon atoms, R1 is a hydrogen atom or an aliphatic monovalent hydrocarbon group of 1 to 6 carbon atoms, R2 and R3 are each methyl group or ethyl group, X and Y are each an ether linkage or an ester linkage, a and b are each 0 or 1, m, n and p are each an integer of 0 to 6, q is an integer of 1 to 6, and r is an integer of 0 to 2. By treating an inorganic material with the alkoxysilane compound having ether linkage and two fluoroalkyl groups, high water and oil repellency and high sliding properties can be imparted to the inorganic material. The alkoxysilane compounds can be easily purified, owing to enhancement of volatility by the branched structure.

摘要翻译： 公开了具有两个氟代烷基并由以下通式（1）表示的烷氧基硅烷化合物：其中Rf和Rf'分别为1-10个碳原子的氟代烷基，R1是氢原子或1至 6个碳原子，R2和R3各自为甲基或乙基，X和Y各自为醚键或酯键，a和b各自为0或1，m，n和p各自为0至6的整数 ，q为1〜6的整数，r为0〜2的整数。通过用具有醚键的烷氧基硅烷化合物和2个氟代烷基处理无机材料，可以赋予高拒油性和高滑动性 无机材料。 由于分支结构的挥发性增强，烷氧基硅烷化合物可以容易地纯化。

公开(公告)号：US20120264962A1

公开(公告)日：2012-10-18

申请号：US13445074

申请日：2012-04-12

申请人： Takayuki Honma ,  Ayumu Kiyomori ,  Tohru Kubota ,  Daijitsu Harada ,  Hiroyuki Yamazaki ,  Masaki Takeuchi

发明人： Takayuki Honma ,  Ayumu Kiyomori ,  Tohru Kubota ,  Daijitsu Harada ,  Hiroyuki Yamazaki ,  Masaki Takeuchi

IPC分类号： C07F7/10

CPC分类号： C07F7/10

摘要： Disclosed are silazane compounds having two fluoroalkyl groups, represented by the following general formula (1): wherein Rf and Rf′ are each a fluoroalkyl group, R1 is a hydrogen atoms or an aliphatic monovalent hydrocarbon group, R2 and R3 are each an aliphatic monovalent hydrocarbon group, R4 is a hydrogen atom or an aliphatic monovalent hydrocarbon group, a and b are each 0 or 1, m, n and p are each an integer of 0 to 6, q is an integer of 1 to 6, and r is 1 or 2. By treating an inorganic material with the silazane compound having two fluoroalkyl groups, high water and oil repellency and high sliding properties can be imparted to the inorganic material in good balance.

摘要翻译： 公开了具有两个氟烷基的硅氮烷化合物，由以下通式（1）表示：其中Rf和Rf'各自为氟烷基，R 1为氢原子或脂族一价烃基，R 2和R 3各自为脂族一价 烃基，R4为氢原子或脂肪族一价烃基，a和b分别为0或1，m，n和p分别为0〜6的整数，q为1〜6的整数，r为 通过用具有两个氟代烷基的硅氮烷化合物处理无机材料，可以很好地赋予无机材料高斥水性和高滑动性。