公开(公告)号：US08080683B2

公开(公告)日：2011-12-20

申请号：US12401225

申请日：2009-03-10

申请人： Takeshi Shibuya ,  Shigenobu Hirano ,  Hiroshi Kondo ,  Yuki Nakamura ,  Yukiko Abe ,  Tohru Yashiro

发明人： Takeshi Shibuya ,  Shigenobu Hirano ,  Hiroshi Kondo ,  Yuki Nakamura ,  Yukiko Abe ,  Tohru Yashiro

IPC分类号： C07C69/00

CPC分类号： C09K9/02 ,  C09K2211/1007

摘要： An electrochromic compound represented by the following General Formula (1). A-(CX2)n—B  General Formula (1) In the formula, A is a monovalent binding group, B is a redox chromophore, X is a halogen atom, and n is an integer of 1 or more.

摘要翻译： 由以下通式（1）表示的电致变色化合物。 A-（CX2）n-B通式（1）式中，A为单价结合基团，B为氧化还原色素，X为卤素原子，n为1以上的整数。

公开(公告)号：US07894118B2

公开(公告)日：2011-02-22

申请号：US12401156

申请日：2009-03-10

申请人： Shigenobu Hirano ,  Takeshi Shibuya ,  Hiroshi Kondo ,  Yuki Nakamura ,  Yukiko Abe ,  Tohru Yashiro

发明人： Shigenobu Hirano ,  Takeshi Shibuya ,  Hiroshi Kondo ,  Yuki Nakamura ,  Yukiko Abe ,  Tohru Yashiro

IPC分类号： G02F1/153 ,  G02F1/15 ,  G02B26/00

CPC分类号： C09K9/02 ,  C09K2211/1007 ,  C09K2211/1014 ,  G02F1/15

摘要： An electrochromic compound having in the molecule at least an adsorbable group, a redox chromophore and a spacer portion, and represented by the following General Formula (1): wherein A represents the adsorbable group, C represents the redox chromophore, and X represents the spacer portion represented by the following formula; wherein R1 and R3 each represent an aliphatic hydrocarbon group or an aromatic derivative group, R2 represents a hydrogen atom or a monovalent group.

摘要翻译： 在分子中具有至少一个可吸附基团的电致变色化合物，氧化还原发色团和间隔物部分，并由以下通式（1）表示：其中A表示可吸附基团，C表示氧化还原色团，X表示间隔基 部分由下式表示; 其中R 1和R 3各自表示脂族烃基或芳族衍生物基团，R 2表示氢原子或一价基团。

公开(公告)号：US07830584B2

公开(公告)日：2010-11-09

申请号：US12204520

申请日：2008-09-04

申请人： Takeshi Shibuya ,  Shigenobu Hirano

发明人： Takeshi Shibuya ,  Shigenobu Hirano

IPC分类号： G02F1/153 ,  B32B9/04 ,  C09K9/00

CPC分类号： G02F1/155 ,  C09K9/02 ,  Y10T428/31663

摘要： The present invention provides an organic-inorganic composite material containing a metal oxide, and a functional organic material located on the metal oxide, wherein the functional organic material and the metal oxide are bound via a silanol bond. An aspect that the silanol bond is formed by reacting a silane coupling agent with the metal oxide, and an aspect that the silane coupling agent has a reactive terminal are preferred. The present invention also provides a display electrode for electrochromic display device and electrode for photoelectric conversion device using the organic-inorganic composite material, an electrochromic display device using the display electrode and a photoelectric conversion device using the electrode.

摘要翻译： 本发明提供一种含有金属氧化物的有机 - 无机复合材料和位于金属氧化物上的功能性有机材料，其中功能性有机材料和金属氧化物通过硅烷醇键结合。 硅烷偶联剂与金属氧化物反应形成硅烷醇键的一个方面以及硅烷偶联剂具有反应性末端的方面是优选的。 本发明还提供了一种用于电致变色显示装置的显示电极和使用有机 - 无机复合材料的光电转换装置的电极，使用该显示电极的电致变色显示装置和使用该电极的光电转换装置。

公开(公告)号：US20090002802A1

公开(公告)日：2009-01-01

申请号：US12204520

申请日：2008-09-04

申请人： Takeshi Shibuya ,  Shigenobu Hirano

发明人： Takeshi Shibuya ,  Shigenobu Hirano

IPC分类号： H01J40/04 ,  G02F1/155 ,  C07F7/08

CPC分类号： G02F1/155 ,  C09K9/02 ,  Y10T428/31663

摘要： The present invention provides an organic-inorganic composite material containing a metal oxide, and a functional organic material located on the metal oxide, wherein the functional organic material and the metal oxide are bound via a silanol bond. An aspect that the silanol bond is formed by reacting a silane coupling agent with the metal oxide, and an aspect that the silane coupling agent has a reactive terminal are preferred. The present invention also provides a display electrode for electrochromic display device and electrode for photoelectric conversion device using the organic-inorganic composite material, an electrochromic display device using the display electrode and a photoelectric conversion device using the electrode.

摘要翻译： 本发明提供一种含有金属氧化物的有机 - 无机复合材料和位于金属氧化物上的功能性有机材料，其中功能性有机材料和金属氧化物通过硅烷醇键结合。 硅烷偶联剂与金属氧化物反应形成硅烷醇键的一个方面以及硅烷偶联剂具有反应性末端的方面是优选的。 本发明还提供了一种用于电致变色显示装置的显示电极和使用有机 - 无机复合材料的光电转换装置的电极，使用该显示电极的电致变色显示装置和使用该电极的光电转换装置。

公开(公告)号：US20070024948A1

公开(公告)日：2007-02-01

申请号：US11540763

申请日：2006-10-02

申请人： Shigenobu Hirano ,  Takuji Kato ,  Hiroyuki Takahashi ,  Ikue Kawashima ,  Takeshi Shibuya

发明人： Shigenobu Hirano ,  Takuji Kato ,  Hiroyuki Takahashi ,  Ikue Kawashima ,  Takeshi Shibuya

IPC分类号： G02F1/15

CPC分类号： G02F1/163 ,  G02F1/15 ,  G02F1/1521 ,  G02F2203/34

摘要： Multicolor display elements are disclosed that are adapted to full color electric papers, which comprises a display electrode, counter electrode, electrolyte, and display layer, wherein the counter electrode is disposed oppositely to the display electrode, the electrolyte is filled into a space provided between the display electrode and the counter electrode, the display layer is disposed on the surface, which faces the counter electrode, of the display electrode, the display layer contains plural electrochromic compositions in a condition that the plural electrochromic compositions are separated into plural layers within the display layer or are mixed together within the display layer, and at least one of threshold voltage for coloring condition and threshold voltage for decoloring condition, or at least one of charge amount required for coloring into a sufficient color density and charge amount required for sufficiently decoloring, are substantially different each other between the plural electrochromic compositions.

摘要翻译： 公开了适用于全彩电纸的多色显示元件，其包括显示电极，对电极，电解质和显示层，其中对电极与显示电极相对设置，电解质填充在 显示电极和对电极，显示层设置在显示电极的面对对电极的表面上，显示层包含多个电致变色组合物，条件是多个电致变色组合物分离成多个电致变色组合物 显示层或在显示层内混合在一起，以及用于着色条件的着色条件和阈值电压的阈值电压中的至少一个，或用于着色成为充分消色所需的充足色彩浓度和电荷量所需的电荷量中的至少一种 ，在p之间基本上彼此不同 油性电致变色组合物。

公开(公告)号：US20060215250A1

公开(公告)日：2006-09-28

申请号：US11384667

申请日：2006-03-21

申请人： Takeshi Shibuya ,  Shigenobu Hirano ,  Satoshi Uchida ,  Yoshitaka Sanehira

发明人： Takeshi Shibuya ,  Shigenobu Hirano ,  Satoshi Uchida ,  Yoshitaka Sanehira

IPC分类号： G02F1/153

CPC分类号： G02F1/15 ,  G02F1/155

摘要： To provide an electrochromic display device which includes a display electrode formed of a substrate having a transparent conductive film; a counter electrode formed of a substrate having a transparent conductive film; and a metal oxide layer which contains a metal oxide and is disposed on the display electrode, the metal oxide layer having an organic electrochromic compound attached, wherein the metal oxide is a long fibrous metal oxide.

公开(公告)号：US20120050838A1

公开(公告)日：2012-03-01

申请号：US13258503

申请日：2009-05-01

申请人： Shigenobu Hirano ,  Tohru Yashiro ,  Takeshi Shibuya ,  Hiroshi Kondo ,  Yuki Nakamura ,  Yukiko Abe

发明人： Shigenobu Hirano ,  Tohru Yashiro ,  Takeshi Shibuya ,  Hiroshi Kondo ,  Yuki Nakamura ,  Yukiko Abe

IPC分类号： G02F1/155

CPC分类号： G02F1/155 ,  G02F2001/1552

摘要： An electrochromic display apparatus includes a display substrate; an opposite substrate disposed opposite the display substrate; an opposite electrode disposed on the opposite substrate; a plurality of display electrodes disposed between the display substrate and the opposite electrode, the display electrodes being electrically isolated from each other; a plurality of electrochromic layers disposed on the corresponding display electrodes; and an electrolyte disposed between the display electrodes and the opposite electrode. An electric resistance between one display electrode and another display electrode is greater than an electric resistance of the one or the other display electrode. One or more display electrodes that are disposed between the display electrode closest to the display substrate and the opposite electrode are configured to be permeable to the electrolyte.

摘要翻译： 电致变色显示装置包括显示基板; 与显示基板相对布置的相对基板; 设置在相对基板上的相对电极; 多个显示电极，设置在显示基板和相对电极之间，显示电极彼此电隔离; 设置在对应的显示电极上的多个电致变色层; 以及设置在显示电极和相对电极之间的电解质。 一个显示电极与另一个显示电极之间的电阻大于一个或另一个显示电极的电阻。 设置在最靠近显示基板的显示电极和相对电极之间的一个或多个显示电极构造成对电解液是可渗透的。

公开(公告)号：US07663797B2

公开(公告)日：2010-02-16

申请号：US11856311

申请日：2007-09-17

申请人： Shigenobu Hirano ,  Takuji Kato ,  Hiroyuki Takahashi ,  Ikue Kawashima ,  Takeshi Shibuya

发明人： Shigenobu Hirano ,  Takuji Kato ,  Hiroyuki Takahashi ,  Ikue Kawashima ,  Takeshi Shibuya

IPC分类号： G02F1/15 ,  G02F1/153

CPC分类号： G02F1/163 ,  G02F1/15 ,  G02F1/1521 ,  G02F2203/34

摘要： Multicolor display elements are disclosed that are adapted to full color electric papers, which comprises a display electrode, counter electrode, electrolyte, and display layer, wherein the counter electrode is disposed oppositely to the display electrode, the electrolyte is filled into a space provided between the display electrode and the counter electrode, the display layer is disposed on the surface, which faces the counter electrode, of the display electrode, the display layer contains plural electrochromic compositions in a condition that the plural electrochromic compositions are separated into plural layers within the display layer or are mixed together within the display layer, and at least one of threshold voltage for coloring condition and threshold voltage for decoloring condition, or at least one of charge amount required for coloring into a sufficient color density and charge amount required for sufficiently decoloring, are substantially different each other between the plural electrochromic compositions.

摘要翻译： 公开了适用于全彩电纸的多色显示元件，其包括显示电极，对电极，电解质和显示层，其中对电极与显示电极相对设置，电解质填充在 显示电极和对电极，显示层设置在显示电极的面对对电极的表面上，显示层包含多个电致变色组合物，条件是多个电致变色组合物分离成多个电致变色组合物 显示层或在显示层内混合在一起，以及用于着色条件的着色条件和阈值电压的阈值电压中的至少一个，或用于着色成为充分消色所需的充分颜色密度和电荷量所需的电荷量中的至少一种 ，在p之间基本上彼此不同 油性电致变色组合物。

公开(公告)号：US20090256157A1

公开(公告)日：2009-10-15

申请号：US12419362

申请日：2009-04-07

申请人： Hiroshi KONDO ,  Tohru Yashiro ,  Yuki Nakamura ,  Takeshi Shibuya ,  Shigenobu Hirano ,  Yukiko Abe

发明人： Hiroshi KONDO ,  Tohru Yashiro ,  Yuki Nakamura ,  Takeshi Shibuya ,  Shigenobu Hirano ,  Yukiko Abe

IPC分类号： H01L33/00

CPC分类号： G02F1/1345 ,  G02F2201/42

摘要： A display device includes a first substrate on which a semiconductor circuit is formed. A second substrate is disposed over the first substrate to include a first electrode formed on a first surface to perform image displaying, and a second electrode exposed to a second surface and bonded to the first electrode via a contact hole. A third substrate is disposed over the second substrate to include a third electrode formed to perform image displaying in association with the first electrode of the second substrate. An image displaying layer is disposed between the second substrate and the third substrate to perform image displaying. An electrode on a surface of the first substrate on which the semiconductor circuit is formed is electrically connected to the second electrode exposed to the second surface of the second substrate.

摘要翻译： 显示装置包括其上形成有半导体电路的第一基板。 第二基板设置在第一基板上方，以包括形成在第一表面上以执行图像显示的第一电极，以及暴露于第二表面并通过接触孔接合到第一电极的第二电极。 第三衬底设置在第二衬底上，以包括形成为与第二衬底的第一电极相关联地执行图像显示的第三电极。 图像显示层设置在第二基板和第三基板之间以执行图像显示。 在其上形成有半导体电路的第一基板的表面上的电极电连接到暴露于第二基板的第二表面的第二电极。

公开(公告)号：US07570412B2

公开(公告)日：2009-08-04

申请号：US11935674

申请日：2007-11-06

申请人： Takeshi Shibuya ,  Shigenobu Hirano

发明人： Takeshi Shibuya ,  Shigenobu Hirano

IPC分类号： G02F1/15 ,  G02F1/153

CPC分类号： C09K9/02 ,  C09K2211/1007 ,  C09K2211/1033 ,  C09K2211/104 ,  Y10S359/90

摘要： A reversible recording material is disclosed. The reversible recording material includes one or more kinds of compounds having a structure shown in Chemical Formula (1) on a surface of metal oxide particles. In Chemical Formula (1), X shows a linkage including an element selected from Si, Ti, and Al; Y shows a linkage including a structure selected from Chemical Formula (2); Z shows a methylene group or a sulfide group capable of having a substituent group; Ar shows an aromatic group capable of having a substituent group; R1 and R2 show corresponding alkylene groups; R3 shows an alkylene group capable of forming a ring structure linked with —N—C—O— and able to have a substituent group; and “n” is an integer which is 1 or more.

摘要翻译： 公开了可逆记录材料。 可逆记录材料包括在金属氧化物颗粒的表面上具有化学式（1）所示结构的一种或多种化合物。 在化学式（1）中，X表示包含选自Si，Ti和Al的元素的键; Y表示包含选自化学式（2）的结构的键; Z表示能够具有取代基的亚甲基或硫醚基; Ar表示能够具有取代基的芳香族基团; R1和R2表示相应的亚烷基; R3表示能够形成与-N-C-O-连接且能够具有取代基的环结构的亚烷基; “n”为1以上的整数。