公开(公告)号：US20080287703A1

公开(公告)日：2008-11-20

申请号：US12098951

申请日：2008-04-07

申请人： Tao Wang ,  Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

发明人： Tao Wang ,  Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

IPC分类号： C07C67/055

CPC分类号： B01J37/0242 ,  B01J23/44 ,  B01J23/52 ,  B01J23/58 ,  B01J37/0219 ,  B01J37/0221 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

摘要： A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes including production of vinyl acetate.

摘要翻译： 已经开发了可用于各种方法的分层组合物。 该组合物包括内核，例如堇青石芯，外层包含耐火无机氧化物，纤维组分和无机粘合剂。 难熔无机氧化物层可以是氧化铝，氧化锆，二氧化钛等，而纤维成分可以是二氧化钛纤维，二氧化硅纤维，碳纤维等。无机氧化物粘合剂可以是氧化铝，二氧化硅，氧化锆等。该层也可以 含有催化金属如金和铂加其他改性剂。 通过用包含耐火无机氧化物，纤维组分，无机粘合剂前体和有机粘合剂如聚乙烯醇的浆料涂覆内芯来制备层状组合物。 该组合物可用于各种烃转化方法，包括生产乙酸乙烯酯。

公开(公告)号：US08227369B2

公开(公告)日：2012-07-24

申请号：US11137180

申请日：2005-05-25

申请人： Tao Wang ,  Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

发明人： Tao Wang ,  Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

IPC分类号： B01J31/00 ,  C07C51/43 ,  C07C67/05

CPC分类号： B01J37/0242 ,  B01J23/44 ,  B01J23/52 ,  B01J23/58 ,  B01J37/0219 ,  B01J37/0221 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

摘要： A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes including production of vinyl acetate.

摘要翻译： 已经开发了可用于各种方法的分层组合物。 该组合物包括内核，例如堇青石芯，外层包含耐火无机氧化物，纤维组分和无机粘合剂。 难熔无机氧化物层可以是氧化铝，氧化锆，二氧化钛等，而纤维成分可以是二氧化钛纤维，二氧化硅纤维，碳纤维等。无机氧化物粘合剂可以是氧化铝，二氧化硅，氧化锆等。该层也可以 含有催化金属如金和铂加其他改性剂。 通过用包含耐火无机氧化物，纤维组分，无机粘合剂前体和有机粘合剂如聚乙烯醇的浆料涂覆内芯来制备层状组合物。 该组合物可用于各种烃转化方法，包括生产乙酸乙烯酯。

公开(公告)号：US20110152066A1

公开(公告)日：2011-06-23

申请号：US13036517

申请日：2011-02-28

申请人： Tao Wang ,  Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

发明人： Tao Wang ,  Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

IPC分类号： B01J37/02 ,  B01J29/068 ,  B01J37/08

CPC分类号： B01J37/0242 ,  B01J23/44 ,  B01J23/52 ,  B01J23/58 ,  B01J37/0219 ,  B01J37/0221 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

摘要： A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes including production of vinyl acetate.

摘要翻译： 已经开发了可用于各种方法的分层组合物。 该组合物包括内核，例如堇青石芯，外层包含耐火无机氧化物，纤维组分和无机粘合剂。 难熔无机氧化物层可以是氧化铝，氧化锆，二氧化钛等，而纤维成分可以是二氧化钛纤维，二氧化硅纤维，碳纤维等。无机氧化物粘合剂可以是氧化铝，二氧化硅，氧化锆等。该层也可以 含有催化金属如金和铂加其他改性剂。 通过用包含耐火无机氧化物，纤维组分，无机粘合剂前体和有机粘合剂如聚乙烯醇的浆料涂覆内芯来制备层状组合物。 该组合物可用于各种烃转化方法，包括生产乙酸乙烯酯。

公开(公告)号：US07897804B2

公开(公告)日：2011-03-01

申请号：US12098951

申请日：2008-04-07

申请人： Tao Wang ,  Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

发明人： Tao Wang ,  Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

IPC分类号： C07C67/05

CPC分类号： B01J37/0242 ,  B01J23/44 ,  B01J23/52 ,  B01J23/58 ,  B01J37/0219 ,  B01J37/0221 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

摘要： A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes including production of vinyl acetate.

摘要翻译： 已经开发了可用于各种方法的分层组合物。 该组合物包括内核，例如堇青石芯，外层包含耐火无机氧化物，纤维组分和无机粘合剂。 难熔无机氧化物层可以是氧化铝，氧化锆，二氧化钛等，而纤维成分可以是二氧化钛纤维，二氧化硅纤维，碳纤维等。无机氧化物粘合剂可以是氧化铝，二氧化硅，氧化锆等。该层也可以 含有催化金属如金和铂加其他改性剂。 通过用包含耐火无机氧化物，纤维组分，无机粘合剂前体和有机粘合剂如聚乙烯醇的浆料涂覆内芯来制备层状组合物。 该组合物可用于各种烃转化方法，包括生产乙酸乙烯酯。

公开(公告)号：US07799727B2

公开(公告)日：2010-09-21

申请号：US12637810

申请日：2009-12-15

申请人： Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

发明人： Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J20/00 ,  B01J29/00 ,  B01J37/00

CPC分类号： C07C5/321 ,  B01J21/063 ,  B01J21/066 ,  B01J23/38 ,  B01J32/00 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0219 ,  B01J37/0221 ,  C07C5/333 ,  C10G11/04 ,  C10G45/40 ,  C10G45/62 ,  C10G47/14 ,  C07C15/46

摘要： A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.

公开(公告)号：US20100092681A1

公开(公告)日：2010-04-15

申请号：US12637810

申请日：2009-12-15

申请人： Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

发明人： Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

IPC分类号： B05D3/02

CPC分类号： C07C5/321 ,  B01J21/063 ,  B01J21/066 ,  B01J23/38 ,  B01J32/00 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0219 ,  B01J37/0221 ,  C07C5/333 ,  C10G11/04 ,  C10G45/40 ,  C10G45/62 ,  C10G47/14 ,  C07C15/46

摘要： A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.

摘要翻译： 已经开发了可用于各种方法的分层组合物。 该组合物包括内核，例如堇青石芯，外层包含耐火无机氧化物，纤维组分和无机粘合剂。 难熔无机氧化物层可以是氧化铝，氧化锆，二氧化钛等，而纤维成分可以是二氧化钛纤维，二氧化硅纤维，碳纤维等。无机氧化物粘合剂可以是氧化铝，二氧化硅，氧化锆等。该层也可以 含有催化金属如金和铂加其他改性剂。 通过用包含耐火无机氧化物，纤维组分，无机粘合剂前体和有机粘合剂如聚乙烯醇的浆料涂覆内芯来制备层状组合物。 该组合物可用于各种烃转化方法中。

公开(公告)号：US07638459B2

公开(公告)日：2009-12-29

申请号：US11137189

申请日：2005-05-25

申请人： Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

发明人： Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J29/00 ,  B01J20/00

CPC分类号： C07C5/321 ,  B01J21/063 ,  B01J21/066 ,  B01J23/38 ,  B01J32/00 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0219 ,  B01J37/0221 ,  C07C5/333 ,  C10G11/04 ,  C10G45/40 ,  C10G45/62 ,  C10G47/14 ,  C07C15/46

摘要： A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.

摘要翻译： 已经开发了可用于各种方法的分层组合物。 该组合物包括内核，例如堇青石芯，外层包含耐火无机氧化物，纤维组分和无机粘合剂。 难熔无机氧化物层可以是氧化铝，氧化锆，二氧化钛等，而纤维成分可以是二氧化钛纤维，二氧化硅纤维，碳纤维等。无机氧化物粘合剂可以是氧化铝，二氧化硅，氧化锆等。该层也可以 含有催化金属如金和铂加其他改性剂。 通过用包含耐火无机氧化物，纤维组分，无机粘合剂前体和有机粘合剂如聚乙烯醇的浆料涂覆内芯来制备层状组合物。 该组合物可用于各种烃转化方法中。

公开(公告)号：US07807045B2

公开(公告)日：2010-10-05

申请号：US12637823

申请日：2009-12-15

申请人： Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

发明人： Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

IPC分类号： C10G11/00 ,  C10G35/00 ,  C07C5/00 ,  C07C27/00 ,  C07C67/00 ,  B01J23/00 ,  B01J21/00 ,  B01J20/00 ,  B01J37/00

CPC分类号： C07C5/321 ,  B01J21/063 ,  B01J21/066 ,  B01J23/38 ,  B01J32/00 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0219 ,  B01J37/0221 ,  C07C5/333 ,  C10G11/04 ,  C10G45/40 ,  C10G45/62 ,  C10G47/14 ,  C07C15/46

摘要： A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.

摘要翻译： 已经开发了可用于各种方法的分层组合物。 该组合物包括内核，例如堇青石芯，外层包含耐火无机氧化物，纤维组分和无机粘合剂。 难熔无机氧化物层可以是氧化铝，氧化锆，二氧化钛等，而纤维成分可以是二氧化钛纤维，二氧化硅纤维，碳纤维等。无机氧化物粘合剂可以是氧化铝，二氧化硅，氧化锆等。该层也可以 含有催化金属如金和铂加其他改性剂。 通过用包含耐火无机氧化物，纤维组分，无机粘合剂前体和有机粘合剂如聚乙烯醇的浆料涂覆内芯来制备层状组合物。 该组合物可用于各种烃转化方法中。

公开(公告)号：US20100089796A1

公开(公告)日：2010-04-15

申请号：US12637823

申请日：2009-12-15

申请人： Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

发明人： Dean E. Rende ,  James E. Rekoske ,  Jeffery C. Bricker ,  Jeffrey L. Boike ,  Masao Takayama ,  Kouji Hara ,  Nobuyuki Aoi

IPC分类号： C10G11/02 ,  C10G35/06 ,  C07C5/02 ,  C07C5/42 ,  C07C27/10 ,  C01B31/20 ,  C07C29/48 ,  C01B5/00 ,  C07C5/22

CPC分类号： C07C5/321 ,  B01J21/063 ,  B01J21/066 ,  B01J23/38 ,  B01J32/00 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0219 ,  B01J37/0221 ,  C07C5/333 ,  C10G11/04 ,  C10G45/40 ,  C10G45/62 ,  C10G47/14 ,  C07C15/46

摘要： A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.

公开(公告)号：US20110178354A1

公开(公告)日：2011-07-21

申请号：US12689751

申请日：2010-01-19

申请人： Antoine Negiz ,  Edwin Paul Boldingh ,  Gregory J. Gajda ,  Dean E. Rende ,  James E. Rekoske ,  David E. Mackowiak ,  Paul Barger ,  Paula L. Bogdan

发明人： Antoine Negiz ,  Edwin Paul Boldingh ,  Gregory J. Gajda ,  Dean E. Rende ,  James E. Rekoske ,  David E. Mackowiak ,  Paul Barger ,  Paula L. Bogdan

IPC分类号： C07C2/66 ,  C07C2/64 ,  B01J10/00

CPC分类号： C07C2/76 ,  C07C15/06 ,  C07C15/08

摘要： One exemplary embodiment can be a process using an aromatic methylating agent. Generally, the process includes reacting an effective amount of the aromatic methylating agent having at least one of an alkane, a cycloalkane, an alkane radical, and a cycloalkane radical with one or more aromatic compounds. As such, at least one of the one or more aromatic compounds may be converted to one or more higher methyl substituted aromatic compounds to provide a product having a greater mole ratio of methyl to phenyl than a feed.

摘要翻译： 一个示例性实施方案可以是使用芳族甲基化剂的方法。 通常，该方法包括将有效量的具有烷烃，环烷烃，烷烃基和环烷烃基团中的至少一种的芳族甲基化试剂与一种或多种芳族化合物反应。 因此，一种或多种芳族化合物中的至少一种可以转化为一种或多种高级甲基取代的芳族化合物，以提供具有比进料更大的甲基与苯基的摩尔比的产物。