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    FLUORINATED COMPOSITIONS AND SURFACE TREATMENTS MADE THEREFROM
    6.
    发明申请
    FLUORINATED COMPOSITIONS AND SURFACE TREATMENTS MADE THEREFROM 有权
    氟化组合物和表面处理

    公开(公告)号：US20100183889A1

    公开(公告)日：2010-07-22

    申请号：US12663027

    申请日：2008-06-05

    申请人： Rudolf J. Dams ,  Steven J. Martin ,  Mark J. Pellerite ,  Chetan P. Jariwala ,  Gregory D. Clark ,  Jason T. Petrin

    发明人： Rudolf J. Dams ,  Steven J. Martin ,  Mark J. Pellerite ,  Chetan P. Jariwala ,  Gregory D. Clark ,  Jason T. Petrin

    IPC分类号： B32B15/04 ,  C09D7/12

    CPC分类号： C08F14/185 ,  C08F8/40 ,  C08F220/10 ,  C08F220/18 ,  C08F220/22 ,  C08F220/36 ,  C08J3/09 ,  C08J2333/16 ,  C09D127/12 ,  C09D133/06 ,  C09D133/14 ,  C09D133/16 ,  C09D143/02 ,  Y10T428/3154 ,  Y10T428/31678 ,  C08F20/22 ,  C08F230/02

    摘要： A composition comprising at least one first divalent unit represented by formula (A) or formula (B); and at least one of a second divalent unit comprising a pendant Z group or a monovalent unit comprising a thioether linkage and a terminal Z group, wherein each Z group is independently selected from the group consisting of —P(O)(OY)2 and —O—P(O)(OY)2. Rf is a perfluoropolyether group. Q is selected from the group consisting of a bond, —C(O)—N(R1)—, and —C(O)—O—. R″, R′″, R and R1 are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. X is selected from the group consisting of alkylene, arylalkylene, and alkylarylene, wherein alkylene, arylalkylene, and alkylarylene are each optionally interrupted by at least one ether linkage. Y is selected from the group consisting of hydrogen, alkyl, trialkylsilyl, and a counter cation. Methods of treating a surface using these compositions and articles with a surface in contact with these compositions are provided. Methods of making these compositions are also provided.

    摘要翻译： 包含由式（A）或式（B）表示的至少一种第一二价单元的组合物; 和包含Z侧基团或包含硫醚键和末端Z基团的一价单元的第二二价单元中的至少一个，其中每个Z基团独立地选自-P（O）（OY）2和 -O-P（O）（OY）2。 Rf是全氟聚醚基团。 Q选自-C（O）-N（R 1） - 和-C（O）-O-。 R“，R”“，R”和“R”各自独立地选自氢和具有1至4个碳原子的烷基。 X选自亚烷基，芳基亚烷基和烷基亚芳基，其中亚烷基，芳基亚烷基和烷基亚芳基各自任选地被至少一个醚键中断。 Y选自氢，烷基，三烷基甲硅烷基和抗衡阳离子。 提供了使用这些组合物和具有与这些组合物接触的表面的制品处理表面的方法。 还提供制备这些组合物的方法。

    Abrasion and stain resistant curable fluorinated coating
    8.
    发明授权
    Abrasion and stain resistant curable fluorinated coating 有权
    耐磨和耐污染的可固化氟化涂层

    公开(公告)号：US06168866A

    公开(公告)日：2001-01-02

    申请号：US09136185

    申请日：1998-08-19

    申请人： Gregory D. Clark

    发明人： Gregory D. Clark

    IPC分类号： B32B1508

    CPC分类号： C09D161/20 ,  C08L61/20 ,  C09D133/16 ,  Y10T428/3154 ,  C08L2666/02

    摘要： A curable fluorine-containing coating composition comprising: (i) an amino resin; (ii) an addition fluoropolymer comprising a copolymer of a fluorinated monomer having a fluorocarbon group of at least 3 carbons, and a non-fluorinated monomer having a crosslinking group capable of reacting with said amino resin at elevated temperatures; and (iii) a hardening agent capable of crosslinking with said amino resin at elevated temperatures.

    摘要翻译： 一种可固化含氟涂料组合物，其包含：（i）氨基树脂;（ii）包含含有至少3个碳的碳氟化合物基团的氟化单体的共聚物的加成含氟聚合物和具有交联基团的非氟化单体 在升高的温度下与所述氨基树脂反应; 和（iii）能够在高温下与所述氨基树脂交联的硬化剂。

    FLUOROCHEMICAL URETHANE COMPOUNDS HAVING PENDENT SILYL GROUPS USED FOR SURFACE TREATMENT
    9.
    发明申请
    FLUOROCHEMICAL URETHANE COMPOUNDS HAVING PENDENT SILYL GROUPS USED FOR SURFACE TREATMENT 有权
    具有用于表面处理的相关SILYL组的荧光化学URETHANE化合物

    公开(公告)号：US20100089290A1

    公开(公告)日：2010-04-15

    申请号：US12444863

    申请日：2007-11-21

    申请人： Gregory D. Clark

    发明人： Gregory D. Clark

    IPC分类号： C09D5/00 ,  C07F7/10

    CPC分类号： C07F7/1804

    摘要： Fluorochemical urethane compounds and coating compositions derived therefrom are described. The compounds and composition may be used in treating substrates, in particular substrates having a hard surface such as ceramics or glass, to render them water, oil, stain, and/or dirt repellent. The compounds have the formula (Rf)xR1—(R2)y]z wherein Rf is a fluorine-containing group, R1 is the residue of a polyisocyanate. R2 is of the formula —NH—CO—X1—R3(CH2CH2—S—R5—Si(Y)p(R)3p)q wherein X1 is —O— or —NR4—, where R4 is H or C1-C4 alkyl, R3 is a polyvalent alkylene or arylene group, or combinations thereof, said alkylene groups optionally containing one or more catenary oxygen atoms, R5 is a divalent alkylene group, said alkylene group optionally containing one or more catenary oxygen atoms, Y is a hydrolysable group, R6 is a monovalent alkyl or aryl group, p is 1, 2 or 3, q is 1 to 5, x and y are each independently at least 1, and z is 1 or 2.

    摘要翻译： 描述了衍生自其的氟化学氨基甲酸酯化合物和涂料组合物。 化合物和组合物可用于处理基材，特别是具有硬表面的基材如陶瓷或玻璃，以使其具有水，油，污渍和/或防污性能。 化合物具有式（Rf）xR1-（R2）y] z其中Rf是含氟基团，R1是多异氰酸酯的残基。 R2是式-NH-CO-X1-R3（CH2CH2-S-R5-Si（Y）p（R）3p）q，其中X1是-O-或-NR4-，其中R4是H或C1-C4 烷基，R3是多价亚烷基或亚芳基或其组合，所述亚烷基任选地含有一个或多个链状氧原子，R 5是二价亚烷基，所述亚烷基任选地含有一个或多个链状氧原子，Y是可水解的 基团，R6是一价烷基或芳基，p是1,2或3，q是1至5，x和y各自独立地为至少1，z是1或2。