摘要:
The present invention relates to an electronic device, especially an electroluminescent devices, comprising a compound of Formula (I), especially as host for phosphorescent compounds. The hosts may function with phosphorescent materials to provide improved efficiency, stability, manufacturability, or spectral characteristics of electroluminescent devices.
摘要:
The present invention relates to an electronic device, especially an electroluminescent devices, comprising a compound of Formula (I), especially as host for phosphorescent compounds. The hosts may function with phosphorescent materials to provide improved efficiency, stability, manufacturability, or spectral characteristics of electroluminescent devices.
摘要:
The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula (I),(II),(III); wherein R1, to R13, may be hydrogen or a variety of substituents, but R1, and R11 are not simultaneously hydrogen;Ym− is an inorganic, organic or organometallic anion, or a mixture thereof; Zn+ is a proton or a metal, ammonium or phosphonium cation, or a mixture thereof; m, n and o are each independently of the others an integer from 1 to 3; and p and q are each a number from 0 to 4, the ratio of o, p and q to one another, depending on the charge of the associated sub-structures, being such that there is no excess positive or negative charge in formula (I), (II) or (III). Also claimed are the use of a xanthene perchlorate in the preparation of compounds of formula (I), (II) or (III) having organometallic anions, and the use of lactates in the application of layers of dye to grooved substrates by spin-coating.
摘要翻译:本发明涉及一种包括基底,反射层和记录层的光学记录介质,其中记录层包括式(I),(II),(III)的化合物; 其中R 1至R 13可以是氢或各种取代基,但R 1和R 11都可以是氢, SUB>不同时为氢; Y为无机,有机或有机金属阴离子或其混合物; Z + N +是质子或金属,铵或鏻阳离子或其混合物; m,n和o各自独立地为1〜3的整数; 并且p和q各自为0至4的数,根据相关子结构的电荷,o,p和q彼此的比例使得在式(1)中不存在过量的正电荷或负电荷 I),(II)或(III)。 还要求的是使用高氯酸呫吨酯来制备具有有机金属阴离子的式(I),(II)或(III)化合物,以及使用乳酸盐通过旋涂将染料层施加到凹槽基材上 。
摘要:
The present invention relates to metal complexes of formula I, compositions comprising the metal complexes, to recording media comprising the metal complexes or compositions and to the use of the compositions in the production of optical recording media: wherein the substituent are, as defined in the description. Use of the metal complexes formula (I) in combination with oxonol dyes results, surprisingly, in a comparatively weak tendency of the oxonol dyes to aggregate in the solid state so that the absorption curve remains advantageously narrow event in the solid state, as a result of which recording media having high reflectivity as well as high sensitivity and good playback characteristics in the desired spectral range are made available.
摘要:
The invention relates to an optical recording medium comprising a substrate and a recording layer, wherein the recording layer comprises a complex of formula (I), or wherein Q2 is a ligand of formula (II), or a tautomer thereof, and R1, R2, R3, R4, R5, R6, R7, and R8 are each dependently of the others H, halogen, cyano, COOR9, CONHR9, CONR9R10, R9, OR9, SR9, NHR9 or NR9R10, wherein R9 and R10 are each independently of the other C6-C10aryl, C4-C9heteroaryl or linear or branched C1-C24alkyl, C3-C24cycloallyl, C2-C24alkenyl, C3-C24cycloalkenyl, C2-C24alkynyl, C1-C12heterocycloalkyl, C1-C12heterocycloalkenyl, unsubstituted or substituted, it also being possible for R1 and R2, R3 and R4, R5 and R6, and R7 and R8, independently of one another, to be bonded by a direct bond or via a bridge O or S, Mm+ is a transition metal cation having 5 or 6 electrons in the outermost occupied d-shell, L1 is a ligand having a sub-structure N—C, P—C or As—C, L2, independently of L1, is a further ligand containing at least one hetero atom N, P, As, O, S, Se or Te, L3− is CN−, SCN−, NCS−, OCN−, NCO−, N3—, L1-O−, L1-S—, L1-CO2−, L1-S03− or L1-P03−, L4−, independently of L3−, is CN−, SCN−, NCS−, OCN−, NCO−, N3−, L3-O−, L3-S−, L3-CO2− L3-SO3− or L3-PO3−, p and q are each independently of the other a number 0 or 1 (formula III), are each a counter-ion, m is a number 1, 2, 3 or 4 equal to the positive charge in Mm+ and n is a number −2, −1, +1 or +2, so that the quotient (formula IV) is not negative. Amorphous solid layers having excellent optical properties are obtained.
摘要:
Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines: with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media.
摘要:
The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula [L1Mr-4L-2]o [Am]p [Zn+q(I), [L1Mr−3L−3]0 [Am]P[Zn+]q(II) or [L3Mr−2L4]0 [Am]p[Zn+]q (III), or where applicable a mesomeric or tautomeric form thereof, wherein L1 and L2 are each independently of the other and L3 and L4 are each independently of the other wherein Q1 is CR1 or N, Q2 is O, S, NR10 or Q5═Q8, Q3 is CR3 or N, Q4 is O, S, NR10 or Q7═Q8, Q5 is CR5 or N, Q6 is CR6 or N, Q7 is CR7 or N, Q8 is CR8 or N, and Q9 is 0, S, NR10 or Q6═Q8; Mr, Am−, Zn+, R2, R9 are as defined in the claims.
摘要:
Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines (I) and (II) with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media
摘要:
Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines: with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media.
摘要:
The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula: (Formula I), (Formula II) or (Formula III); wherein R, to R, may be hydrogen or a variety of substituents, but R1 and R9 are not simultaneously hydrogen; Ym-— is an inorganic, organic or organometallic anion, or a mixture thereof; Zn+ is a proton or a metal, ammonium or phosphonium cation, or a mixture thereof; m, n and o are each independently of the others an integer from 1 to 3; and p and q are each a number from 0 to 4, the ratio of o, p and q to one another, depending on the charge of the associated sub-structures, being such that there is no excess positive or negative charge in formula (I), (II) or (III). Also claimed are the use of a xanthene perchlorate in the preparation of compounds of formula (I), (II) or (III) having organometallic anions, and the use of lactates in the application of layers of dye of compounds of formula (I), (II) or (III) to grooved substrates by spin-coating.
摘要翻译:本发明涉及一种包括基底,反射层和记录层的光学记录介质,其中记录层包含式(I)化合物,(式II)或(式III)化合物。 其中R 1至R 3可以是氢或各种取代基,但R 1和R 9不同时为氢; 是无机,有机或有机金属阴离子或其混合物; Z + N +是质子或金属,铵或鏻阳离子或其混合物; m,n和o各自独立地为1〜3的整数; 并且p和q各自为0至4的数,根据相关子结构的电荷,o,p和q彼此的比例使得在式(1)中不存在过量的正电荷或负电荷 I),(II)或(III)。 还要求保护的是高氯酸呫吨酯在制备具有有机金属阴离子的式(I),(II)或(III)的化合物中的用途,以及在施用式(I)化合物的染料层时使用乳酸盐, ,(II)或(III))通过旋涂进行开槽基板。