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1.发明申请ANTI-BLOCKING AGENT MASTER BATCH AND POLYOLEFIN-BASED RESIN FILM USING THE SAME 审中-公开使用它的防堵剂主母料和基于聚烯烃的树脂膜公开(公告)号：US20100273951A1
公开(公告)日：2010-10-28
申请号：US12681478
申请日：2008-10-01
申请人： Toshikatsu Shoko , Shozo Hayashi , Hideko Hayashi , Yasuo Togami , Akira Takagi
发明人： Toshikatsu Shoko , Shozo Hayashi , Hideko Hayashi , Yasuo Togami , Akira Takagi
CPC分类号： C08L23/04 , C08F2/22 , C08J3/226 , C08J5/18 , C08J2323/02 , C08J2423/00 , C08L23/02 , C08L23/06 , C08L23/10 , C08L33/12 , C08L2666/04 , C08L2666/02
摘要： An anti-blocking agent master batch is provided, obtained by compounding 100 parts by mass of a polyolefin-based resin with 1 to 40 parts by mass of polymer fine particles, the polymer fine particles obtained by: causing two or more fluids including a liquid medium, a monomer or monomers, and a polymerization initiator to continuously and successively pass through a plurality of net bodies which are disposed at given intervals in a cylindrical passage and each have a surface crossing a direction of the passage to obtain an emulsion including liquid droplets containing the monomer or monomers and the polymerization initiator, the liquid droplets being dispersed in the liquid medium; and heating this emulsion to polymerize the monomer or monomers. Also provided is a manufacturing method thereof. The anti-blocking agent master batch can prevent the generation of die build-up during the manufacture of a master batch for a polyolefin-based resin film by compounding an anti-blocking agent into a polyolefin-based resin.
摘要翻译： 提供防粘剂母料，其通过将100质量份聚烯烃类树脂与1〜40质量份聚合物细颗粒混合而获得，所述聚合物细颗粒通过以下方法获得：将两种或更多种流体，包括液体 介质，单体或单体，以及聚合引发剂，以连续和连续的方式通过在圆柱形通道中以给定间隔设置的多个网体，并且每个网体具有与通道方向交叉的表面，以获得包含液滴的乳液 含有单体或单体和聚合引发剂，液滴分散在液体介质中; 并加热该乳液以聚合单体或单体。 还提供其制造方法。 防粘剂母料可以通过将防粘连剂复合到聚烯烃基树脂中来防止在制造聚烯烃基树脂膜的母料期间产生模具积聚。
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2.发明申请公开(公告)号：US20110135933A1
公开(公告)日：2011-06-09
申请号：US12681484
申请日：2008-10-01
申请人： Toshikatsu Shoko , Shozo Hayashi , Hideko Hayashi , Yasuo Togami , Akira Takagi
发明人： Toshikatsu Shoko , Shozo Hayashi , Hideko Hayashi , Yasuo Togami , Akira Takagi
IPC分类号： C08F120/18 , B32B1/00 , B01J13/06 , B05C11/02
CPC分类号： C08F2/22 , B01F3/0807 , B01F5/0682 , B01F5/0693 , B01F13/1013 , B01F13/1016 , B01J13/16 , Y10T428/2984
摘要： A method for controlling a particle diameter and a particle diameter distribution of emulsion particles during manufacturing of an emulsion dispersion is provided. The method includes causing two or more types of liquids substantially immiscible with each other to continuously and sequentially pass through net bodies. The net bodies are disposed in a cylindrical flow passage at intervals of 5 to 200 mm, and the number of the net bodies is more than 50 and 200 or less. Each of the net bodies is equivalent to a gauze having a mesh number of 35 mesh to 4000 mesh in accordance with an ASTM standard and has a surface that intersects the direction of the flow passage. An emulsification apparatus used for the method includes a feed pump for feeding two or more types of liquids substantially immiscible with each other; and a cylindrical flow passage to which the two or more types of liquids fed by the feed pump are delivered. A predetermined number of net bodies are disposed in the cylindrical flow passage at predetermined intervals, and each net body has a surface intersecting the direction of the flow passage.
摘要翻译： 提供了在制造乳液分散体期间控制乳液颗粒的粒径和粒径分布的方法。 所述方法包括使两种或多种类型的液体彼此基本上不混溶，以连续且顺序地通过网体。 网体以5〜200mm的间隔设置在圆筒形的流路中，网体的数量为50以上且200以下。 每个网体相当于根据ASTM标准具有35目至4000目的网格的纱布，并且具有与流动通道方向相交的表面。 用于该方法的乳化装置包括用于将两种或多种类型的液体基本上不混溶的进料泵， 以及输送由进料泵供给的两种或更多种类型的液体的圆柱形流动通道。 预定数量的网体以预定的间隔布置在圆柱形流动通道中，并且每个网体具有与流动通道的方向相交的表面。
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3.发明授权公开(公告)号：US08932714B2
公开(公告)日：2015-01-13
申请号：US12681484
申请日：2008-10-01
申请人： Toshikatsu Shoko , Yasuo Togami , Akira Takagi , Hideko Hayashi
发明人： Toshikatsu Shoko , Shozo Hayashi , Yasuo Togami , Akira Takagi
CPC分类号： C08F2/22 , B01F3/0807 , B01F5/0682 , B01F5/0693 , B01F13/1013 , B01F13/1016 , B01J13/16 , Y10T428/2984
摘要： A method for controlling a particle diameter and a particle diameter distribution of emulsion particles during manufacturing of an emulsion dispersion is provided. The method includes causing two or more types of liquids substantially immiscible with each other to continuously and sequentially pass through net bodies. The net bodies are disposed in a cylindrical flow passage at intervals of 5 to 200 mm, and the number of the net bodies is more than 50 and 200 or less. Each of the net bodies is equivalent to a gauze having a mesh number of 35 mesh to 4000 mesh in accordance with an ASTM standard and has a surface that intersects the direction of the flow passage. An emulsification apparatus used for the method includes a feed pump for feeding two or more types of liquids substantially immiscible with each other; and a cylindrical flow passage to which the two or more types of liquids fed by the feed pump are delivered. A predetermined number of net bodies are disposed in the cylindrical flow passage at predetermined intervals, and each net body has a surface intersecting the direction of the flow passage.
摘要翻译： 提供了在制造乳液分散体期间控制乳液颗粒的粒径和粒径分布的方法。 所述方法包括使两种或多种类型的液体彼此基本上不混溶，以连续且顺序地通过网体。 网体以5〜200mm的间隔设置在圆筒形的流路中，网体的数量为50以上且200以下。 每个网体相当于根据ASTM标准具有35目至4000目的网格的纱布，并且具有与流动通道方向相交的表面。 用于该方法的乳化装置包括用于将两种或多种类型的液体基本上不混溶的进料泵， 以及输送由进料泵供给的两种或更多种类型的液体的圆柱形流动通道。 预定数量的网体以预定的间隔布置在圆柱形流动通道中，并且每个网体具有与流动通道的方向相交的表面。
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4.发明授权公开(公告)号：US06586362B1
公开(公告)日：2003-07-01
申请号：US09831062
申请日：2001-05-04
申请人： Toshikatsu Shoko , Yasuo Togami
发明人： Toshikatsu Shoko , Yasuo Togami
IPC分类号： B41M5135
CPC分类号： B41M5/1655 , Y02P20/582
摘要： A hydrocarbon solvent comprising a fraction which is obtained by reacting styrene and cumene in the presence of an acid catalyst and contains 85% by weight or more of 1-phenyl-1-(p-isopropylphenyl)ethane and 5% by weight or less of total styrene dimers, and a pressure-sensitive copying material made using said solvent. The hydrocarbon solvent is inexpensive and excellent in dissolving power for dyes, color-developing rate and so forth, and is satisfactorily odorless.
摘要翻译： 一种烃溶剂，其包含通过苯乙烯和异丙基苯在酸催化剂存在下反应并含有85重量％以上的1-苯基-1-（对异丙基苯基）乙烷和5重量％以下的 总苯乙烯二聚体和使用所述溶剂制备的压敏复印材料。 烃类溶剂廉价，染料的功率优异，显色性等优异，令人满意地无臭。
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5.发明申请POLYMER FINE PARTICLE FOR SUPPRESSING GENERATION OF DIE BUILD-UP DURING EXTRUSION MOLDING 审中-公开聚合物微粒在挤出成型过程中抑制DIE建筑的产生公开(公告)号：US20120065337A1
公开(公告)日：2012-03-15
申请号：US13319881
申请日：2010-05-24
申请人： Toshikatsu Shoko , Yasou Togami , Yasuyuki Shinpo
发明人： Toshikatsu Shoko , Yasou Togami , Yasuyuki Shinpo
IPC分类号： C08L33/12 , C08F122/10
CPC分类号： C08J3/226 , C08J2323/02 , C08J2423/00 , C08J2425/00 , C08J2427/00 , C08J2433/00 , C08J2457/00 , C08L23/0815 , C08L2312/02 , C08L33/062
摘要： During the manufacture of a master batch for a polyolefin resin film, organic polymer fine particles which contain a polyfunctional monomer (cross-linking agent) having at least one kind of two or more functional groups in a monomer unit constituting a polymer and is mixed with a polyolefin resin using an extruder are blended as an anti-blocking agent, thereby preventing the generation of die build-up around the outlet of the extruder.
摘要翻译： 在制造用于聚烯烃树脂膜的母料时，含有在构成聚合物的单体单元中具有至少一种两个或更多个官能团的多官能单体（交联剂）的有机聚合物细颗粒与 将使用挤出机的聚烯烃树脂作为防粘连剂进行混合，从而防止在挤出机的出口周围产生模具积聚。
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公开(公告)号：US20100197970A1
公开(公告)日：2010-08-05
申请号：US12669954
申请日：2008-07-29
CPC分类号： C07C13/605 , C07C2/86 , C07C2/861 , C07C17/266 , C07C2531/24 , C07C2602/42 , C07C2603/86 , C07C2603/90 , C07C13/42 , C07C13/68 , C07C13/64 , C07C25/24
摘要： A method for producing a norbornene derivative wherein, in the presence of palladium and at least one selected from phosphorus compounds represented by the following General Formulae (1) and (2): [in Formula (1), R1, R2, R3 and R4 each independently represent a hydrogen atom or the like, and R5 and R6 each independently represent a branched chain saturated hydrocarbon group having 3 to 10 carbon atoms or the like], and [in Formula (2), R7 represents a branched chain saturated hydrocarbon group having 3 to 10 carbon atoms], a norbornadiene derivative represented by the following General Formula (3): [in Formula (3), R8, R9, R10, R11 and R12 each independently represent a hydrogen atom or the like, l represents an integer of 0 or 1, m represents an integer of 0 or 1, and n represents an integer of 0 or 1], and a bromine compound represented by the following General Formula (4): [Chemical Formula 4] Br—Z—R13 (4) [in Formula (4), Z represents a phenylene group or the like, and R13 represents a hydrogen atom or the like] are reacted with each other, to thereby obtain a norbornene derivative represented by the following General Formula (5): [in Formula (5), R14, R15, R16, R17 and R18 each independently represent a hydrogen atom or the like, Z represents a phenylene group or the like, R19 represents a hydrogen atom or the like, l represents an integer of 0 or 1, m represents an integer of 0 or 1, and n represents an integer of 0 or 1], the norbornene derivative having a configuration of a substituent represented by Z in General Formula (5) that is an exo configuration.
摘要翻译： 一种降冰片烯衍生物的制备方法，其中在钯和选自由以下通式（1）和（2）表示的磷化合物中的至少一种的存在下，[式（1）中，R 1，R 2，R 3和R 4 各自独立地表示氢原子等，R5和R6各自独立地表示碳原子数3〜10的支链饱和烃基等]，[式（2）中，R7表示支链饱和烃基 具有3至10个碳原子]，由以下通式（3）表示的降冰片二烯衍生物：[式（3）中，R 8，R 9，R 10，R 11和R 12各自独立地表示氢原子等，l表示 0或1的整数，m表示0或1的整数，n表示0或1的整数]和由以下通式（4）表示的溴化合物：[化学式4] Br-Z-R13 （4）[式（4）中，Z表示亚苯基等，R 13表示亚苯基等 代表氢原子等]彼此反应，从而得到由以下通式（5）表示的降冰片烯衍生物：[式（5）中，R 14，R 15，R 16，R 17和R 18各自独立地表示 氢原子等，Z表示亚苯基等，R 19表示氢原子等，l表示0或1的整数，m表示0或1的整数，n表示0以上的整数， 1]表示的通式（5）中由Z表示的取代基的降冰片烯衍生物为外部构型。
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公开(公告)号：US08487136B2
公开(公告)日：2013-07-16
申请号：US12669954
申请日：2008-07-29
CPC分类号： C07C13/605 , C07C2/86 , C07C2/861 , C07C17/266 , C07C2531/24 , C07C2602/42 , C07C2603/86 , C07C2603/90 , C07C13/42 , C07C13/68 , C07C13/64 , C07C25/24
摘要： A method for selectively producing a monoaryl norbornene derivative represented by a formula (5) involves having a norbornadiene derivative represented by a formula (3) and a bromine compound represented by a formula (4) react with each other in the presence of a reducing agent, palladium and at least one selected from phosphorus compounds represented by the formulas (1) and (2), whereby the norbornene derivative represented by formula (5) having a monoaryl substituent is an exo configuration.
摘要翻译： 选择性制备由式（5）表示的单芳基降冰片烯衍生物的方法包括使式（3）表示的降冰片二烯衍生物和由式（4）表示的溴化合物在还原剂存在下相互反应 钯和选自由式（1）和（2）表示的磷化合物中的至少一种，其中由具有单芳基取代基的式（5）表示的降冰片烯衍生物是外部构型。
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公开(公告)号：US07867581B2
公开(公告)日：2011-01-11
申请号：US12379533
申请日：2009-02-24
CPC分类号： C08J5/18 , C08G61/08 , C08G2261/3324 , C08G2261/418 , C08J2365/00 , G02B5/3016 , G02B5/3083 , G02F1/13363 , G02F2001/133637 , Y10T428/10
摘要： A retardation film, formed by stretching a film including a norbornene-based, ring-opening polymer containing a structural unit (A) represented by a formula (1), has high transparency, excellent wavelength dispersion characteristics in a single layer, is capable of providing specific retardation to broadband light, is extremely adhesive to other materials, is capable of attaining optical characteristics that are unique among negative birefringence characteristics, and is capable of providing a reverse dispersion of birefringence wavelength dispersion characteristics. The present invention also provides a liquid crystal display device using the foregoing film.
摘要翻译： 通过拉伸含有由式（1）表示的结构单元（A）的降冰片烯系的开环聚合物的膜形成的延迟膜具有高透明性，单层优异的波长分散特性， 提供对宽带光的特定延迟，对其他材料是极其粘合的，能够获得在负双折射特性中独特的光学特性，并且能够提供双折射波长色散特性的反向色散。 本发明还提供一种使用上述膜的液晶显示装置。
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公开(公告)号：US20090156770A1
公开(公告)日：2009-06-18
申请号：US12379533
申请日：2009-02-24
IPC分类号： C08F132/08
CPC分类号： C08J5/18 , C08G61/08 , C08G2261/3324 , C08G2261/418 , C08J2365/00 , G02B5/3016 , G02B5/3083 , G02F1/13363 , G02F2001/133637 , Y10T428/10
摘要： A retardation film, formed by stretching a film including a norbornene-based, ring-opening polymer containing a structural unit (A) represented by a formula (1), has high transparency, excellent wavelength dispersion characteristics in a single layer, is capable of providing specific retardation to broadband light, is extremely adhesive to other materials, is capable of attaining optical characteristics that are unique among negative birefringence characteristics, and is capable of providing a reverse dispersion of birefringence wavelength dispersion characteristics. The present invention also provides a liquid crystal display device using the foregoing film.
摘要翻译： 通过拉伸含有由式（1）表示的结构单元（A）的降冰片烯系的开环聚合物的膜形成的延迟膜具有高透明性，单层优异的波长分散特性， 提供对宽带光的特定延迟，对其他材料是极其粘合的，能够获得在负双折射特性中独特的光学特性，并且能够提供双折射波长色散特性的反向色散。 本发明还提供一种使用上述膜的液晶显示装置。
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