Diquaternary ammonium cellulosic fabrics with wrinkle resistant
properties
    2.
    发明授权
    Diquaternary ammonium cellulosic fabrics with wrinkle resistant properties 失效
    具有抗皱性能的二季铵纤维素织物

    公开(公告)号:US4067689A

    公开(公告)日:1978-01-10

    申请号:US728104

    申请日:1976-09-30

    摘要: Diethylaminoethyl (DEAE)-Cotton, prepared so that the tertiary amine nitrogens have unshared electrons and are thus in the Lewis-base form, is reacted with an alcoholic solution of an alpha-omega dihaloalkane to quaternize amino groups. The fabric produced by this process is crosslinked between tertiary amine nitrogen groups in cellulose and every alkylene group introduced is connected to two quaternary ammonium ions. The products of this process have strong base anion exchange properties and fabrics of high nitrogen content are imparted both wet and dry crease resistance.

    摘要翻译: 二乙基氨基乙基(DEAE)-Cotton,使得叔胺氮具有非共享电子并因此处于路易斯碱形式,与α-ω二卤代烷烃的醇溶液反应以季铵化氨基。 通过该方法生产的织物在纤维素中的叔胺氮基团之间交联,并且引入的每个亚烷基连接到两个季铵离子。 该方法的产品具有强碱性阴离子交换性能,并且具有高氮含量的织物赋予湿和抗折皱性。

    Preparation of stable strong base cellulosic anion exchangers with
red-ox potentials
    3.
    发明授权
    Preparation of stable strong base cellulosic anion exchangers with red-ox potentials 失效
    稳定的强碱性红细胞阴离子交换剂的制备

    公开(公告)号:US4032293A

    公开(公告)日:1977-06-28

    申请号:US504646

    申请日:1974-09-09

    摘要: Strong base quaternary ammonium cellulose derivatives prepared under anhydrous conditions are further chemically modified in selected organic solvents by a sequential process that produces a partial cellulose ether in fibrous form that can be used in electro-chemical reactions covering a range of oxidation-reduction potentials. These new derivatives can be prepared such that they stabilize a given anion in the cellulose matrix until such time as its oxidation or reduction power is needed in desired chemical reactions. Although prepared in nonaqueous media, these red-ox cellulosic anion exchangers can be used to regulate oxidation-reduction reactions in aqueous media. Some of these new red-ox anion exchangers are dispersible in water and can be reprecipitated by organic solvents without losing their red-ox abilities during the process. Others are water insoluble. Thus these red-ox cellulosic exchangers can be tailor made to specific end uses such as for applications in separation of biochemical or organic mixtures, the identification of reducible or oxidizable chemicals, purification of polluted liquids by oxidation or reduction of contaminants.