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1.发明授权Synthesis of phenolic monomers containing imide or diimide moieties and high heat carbonate polymers prepared therefrom 有权含有酰亚胺或二酰亚胺部分的酚单体和由其制备的高热碳酸酯聚合物的合成
公开(公告)号：US6096853A
公开(公告)日：2000-08-01
申请号：US217026
申请日：1998-12-21
IPC分类号： C07D487/04 , C07D209/48 , C08G73/10 , C08G73/16 , C08G64/00
CPC分类号： C07D209/48 , C08G73/105
摘要： A process has been surprisingly discovered that can produce a high heat carbonate polymer (i.e., one with a Tg greater that 150.degree. C.), without the drawbacks encountered in attempts to produce a high heat carbonate polymer. The process of the instant invention comprises the steps of:(1) reacting an aromatic amine with a dihydric phenol to prepare an aminophenol;(2) reacting an anhydride or dianhydride with the aminophenol to prepare a phenolic precursor; and(3) reacting the phenolic precursor with a carbonate precursor to prepare a high heat carbonate polymer.
摘要翻译： 惊奇地发现，可以产生高热碳酸酯聚合物（即Tg高于150℃的聚碳酸酯）的方法，而没有在制造高热碳酸酯聚合物时遇到的缺点。 本发明的方法包括以下步骤：（1）使芳族胺与二元酚反应制备氨基苯酚; （2）使酸酐或二酐与氨基苯酚反应以制备酚类前体; 和（3）使酚类前体与碳酸酯前体反应以制备高热碳酸酯聚合物。
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2.发明授权公开(公告)号：US06194497B1
公开(公告)日：2001-02-27
申请号：US08899025
申请日：1997-07-23
IPC分类号： C08K542
CPC分类号： C08K5/50 , Y10S524/912 , C08L69/00
摘要： An anti-static thermoplastic resin composition of 90-99.95 weight % of a thermoplastic resin and correspondingly 10 to 0.05 weight % of a halogenated carbon sulfonic acid salt of a polysubstituted phosphonium compound such as a fluorinated phosphonium sulfonate and wherein the thermoplastic resin is either an aromatic polycarbonate, polyetherimide, polyester, polyphenylene ether, polyphenylene ether/styrene polymer blend, polyamide, polyketone, acrylonitrile-butadiene-styrene, blends thereof and blends thereof with other materials. Preferably the thermoplastic resin is a transparent aromatic polycarbonate.
摘要翻译： 一种热塑性树脂为90-99.95重量％的抗静电热塑性树脂组合物，相当于10至0.05重量％的多取代鏻化合物如氟化鏻磺酸盐的卤代碳酸磺酸盐，其中热塑性树脂为 芳族聚碳酸酯，聚醚酰亚胺，聚酯，聚苯醚，聚苯醚/苯乙烯聚合物共混物，聚酰胺，聚酮，丙烯腈 - 丁二烯 - 苯乙烯，它们的共混物以及它们与其它材料的共混物。 优选地，热塑性树脂是透明芳族聚碳酸酯。
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3.再颁专利公开(公告)号：USRE38530E1
公开(公告)日：2004-06-08
申请号：US10376923
申请日：2003-02-27
IPC分类号： C08K542
CPC分类号： C08K5/50
摘要： An anti-static thermoplastic resin composition of 90-99.95 weight % of a thermoplastic resin and correspondingly 10 to 0.05 weight % of a halogenated carbon sulfonic acid salt of a polysubstituted phosphonium compound such as a fluorinated phosphonium sulfonate and wherein the thermoplastic resin is either an aromatic polycarbonate, polyetherimide, polyester, polyphenylene ether, polyphenylene ether/styrene polymer blend, polyamide, polyketone, acrylonitrile-butadiene-styrene, blends thereof and blends thereof with other materials. Preferably the thermoplastic resin is a transparent aromatic polycarbonate.
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公开(公告)号：US6087468A
公开(公告)日：2000-07-11
申请号：US954458
申请日：1997-10-20
申请人： Theodorus L. Hoeks , Adrianus A. M. Kusters , Ye-Gang Lin , Patrick J. McCloskey , Raphael Mestanza , Pin-pin Wu
发明人： Theodorus L. Hoeks , Adrianus A. M. Kusters , Ye-Gang Lin , Patrick J. McCloskey , Raphael Mestanza , Pin-pin Wu
CPC分类号： C08G64/14
摘要： The disclosure describes reacting a multi-functional phenolic or carboxylic branching agent with a transesterification catalyst to form an organic salt prior to reactive extrusion of said organic salt branching agent with linear polycarbonate resin as a means to dramatically increase the efficiency of the branching agent in the preparation of branched polycarbonate.
摘要翻译： 本公开内容描述了在将所述有机盐支化剂与线性聚碳酸酯树脂反应性挤出之前，使多官能酚或羧基支化剂与酯交换催化剂反应以形成有机盐，以显着提高支链剂在 支链聚碳酸酯的制备。
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公开(公告)号：US5576413A
公开(公告)日：1996-11-19
申请号：US233285
申请日：1994-04-25
申请人： Jan Bussink , Henricus G. C. Denissen , Erwin M. A. Gijzen , Hendrik T. van de Grampel , Theodorus L. Hoeks , Henricus H. M. van Hout
发明人： Jan Bussink , Henricus G. C. Denissen , Erwin M. A. Gijzen , Hendrik T. van de Grampel , Theodorus L. Hoeks , Henricus H. M. van Hout
CPC分类号： C08G64/06
摘要： Polycarbonate compositions comprising copolymers of bis-(4-hydroxyphenyl)methane and 2,2-bis-(4-hydroxyphenyl)propane are described and they unexpectedly display high glass transition temperatures, high impact resistances, flame retardant properties and superior brittle ductile transition temperature.
摘要翻译： 描述了包含双 - （4-羟基苯基）甲烷和2,2-双 - （4-羟基苯基）丙烷的共聚物的聚碳酸酯组合物，并且它们意外地显示出高玻璃化转变温度，高抗冲击性，阻燃性能和优异的脆性延性转变温度 。
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6.发明授权公开(公告)号：US06562433B1
公开(公告)日：2003-05-13
申请号：US09663857
申请日：2000-09-18
申请人： Hiromi Ishida , Kenichi Ishiwa , Mitsuyasu Okamura , Tomoaki Shimoda , Theodorus L. Hoeks , Henricus H. M. van Hout , Monica M. Marugan , Patrick J. McCloskey , Joseph A. King, Jr. , Paul M. Smigelski, Jr.
发明人： Hiromi Ishida , Kenichi Ishiwa , Mitsuyasu Okamura , Tomoaki Shimoda , Theodorus L. Hoeks , Henricus H. M. van Hout , Monica M. Marugan , Patrick J. McCloskey , Joseph A. King, Jr. , Paul M. Smigelski, Jr.
IPC分类号： C08G6430
CPC分类号： G11B7/2534 , C08G64/06 , C08G64/307 , G11B7/2533 , G11B7/26
摘要： The present invention provides a composition comprising polycarbonate wherein the polycarbonate has a very low Fries content (e.g., above 5 ppm and below 360 ppm). The present invention also provides a polycarbonate having a very low Fries content which is made by the melt process. This polycarbonate has high ductility and high impact strength. The invention also provides a method for making these compositions. Another aspect of the invention is an optical disk comprising polycarbonate having a very low Fries content which is made by the melt process. Such optical disks resist breakage due to bending.
摘要翻译： 本发明提供包含聚碳酸酯的组合物，其中聚碳酸酯具有非常低的薯条含量（例如高于5ppm和低于360ppm）。 本发明还提供了通过熔融法制造的具有非常低的薯条含量的聚碳酸酯。 该聚碳酸酯具有高延展性和高冲击强度。 本发明还提供了制备这些组合物的方法。 本发明的另一方面是包括通过熔融法制造的具有非常低的薯条含量的聚碳酸酯的光盘。 这种光盘由于弯曲而抵抗破损。
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7.发明授权Optical quality polycarbonates with reduced static charge and method for making same 有权具有降低静电荷的光学质量聚碳酸酯及其制造方法
公开(公告)号：US6022943A
公开(公告)日：2000-02-08
申请号：US287668
申请日：1999-04-07
申请人： Kazushige Inoue , Hiromi Ishida , Tomoaki Shimoda , Theodorus L. Hoeks , Henricus H. M. van Hout , Monica M. Marugan , David M. Dardaris , Patrick J. McCloskey
发明人： Kazushige Inoue , Hiromi Ishida , Tomoaki Shimoda , Theodorus L. Hoeks , Henricus H. M. van Hout , Monica M. Marugan , David M. Dardaris , Patrick J. McCloskey
CPC分类号： C08G64/14 , C08G64/307 , G11B7/2534
摘要： Increasing the endcap level to a level greater than about 90% for Optical Quality (OQ) Melt Polycarbonate significantly reduces the as-molded static charge for injection molded parts for Optical Disc applications. The use of resins with higher endcap levels in combination with antistatic additives provides a highly robust formulation suitable for even the most demanding emerging formats as Digital Versatile Disc (DVD) and in all commercial Optical media molding machines. Thus, optical quality polycarbonates are prepared by performing a base-catalyzed polymerization of a diaryl carbonate and a dihydric phenol under conditions effective to produce a polycarbonate product having an endcap level of 90% or greater.
摘要翻译： 将端盖水平提高到光学质量（OQ）的大约90％以上熔融聚碳酸酯显着降低了用于光盘应用的注塑部件的模制静电荷。 使用具有更高端帽水平的树脂与抗静电添加剂相结合提供了高度鲁棒的配方，适用于甚至最苛刻的新兴格式，如数字多功能光盘（DVD）和所有商业光学介质成型机。 因此，通过在有效地制备端帽水平为90％以上的聚碳酸酯制品的条件下进行碳酸二芳基酯和二元酚的碱催化聚合来制备光学质量的聚碳酸酯。
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公开(公告)号：US5936047A
公开(公告)日：1999-08-10
申请号：US912712
申请日：1997-08-18
IPC分类号： C08G64/16 , C08G64/42 , C08G283/02
CPC分类号： C08G64/1616 , C08G64/42
摘要： The weight average molecular weight of a polycarbonate resin is predictably reduced by reaction with a multifunctional aliphatic compound at a temperature of 250 C. to 350 C.
摘要翻译： 聚碳酸酯树脂的重均分子量可以通过在250℃至350℃的温度下与多官能脂族化合物反应来预测地降低。
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9.发明授权Polymer mixture which comprises polyphenylene ether, polyoctenylene and TiO.sub.2 or BaSO.sub.4 失效聚合物混合物，其中包含聚苯乙烯，聚碳酸酯和TIO2或BASO4
公开(公告)号：US5166249A
公开(公告)日：1992-11-24
申请号：US682493
申请日：1991-04-09
申请人： Theodorus L. Hoeks , Christian M. E. Bailly , Johannes H. G. M. Lohmeijer , Wilhelmus M. M. Roovers
发明人： Theodorus L. Hoeks , Christian M. E. Bailly , Johannes H. G. M. Lohmeijer , Wilhelmus M. M. Roovers
CPC分类号： C08K3/18 , C08L65/00 , C08L71/123
摘要： The invention relates to polymer mixtures which comprise a polyphenylene ether, a polyoctenylene and TiO.sub.2 or BaSO.sub.4. The presence of TiO.sub.2 or BaSO.sub.4 leads to an improvement of the mechanical properties.
摘要翻译： 本发明涉及包含聚苯醚，聚辛烯和TiO 2或BaSO 4的聚合物混合物。 TiO 2或BaSO 4的存在导致机械性能的改善。
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10.发明授权Optical quality polycarbonates with reduced static charge and method for making same 有权具有降低静电荷的光学质量聚碳酸酯及其制造方法公开(公告)号：US06262218B1
公开(公告)日：2001-07-17
申请号：US09450408
申请日：1999-11-29
申请人： Kazushige Inoue , Hiromi Ishida , Tomoaki Shimoda , Theodorus L. Hoeks , Henricus H. M. van Hout , Monica M. Marugan , David M. Dardaris , Patrick J. McCloskey
发明人： Kazushige Inoue , Hiromi Ishida , Tomoaki Shimoda , Theodorus L. Hoeks , Henricus H. M. van Hout , Monica M. Marugan , David M. Dardaris , Patrick J. McCloskey
IPC分类号： C08G6400
CPC分类号： C08G64/14 , C08G64/307 , G11B7/2534
摘要： Increasing the endcap level to a level greater than about 90% for Optical Quality (OQ) Melt Polycarbonate significantly reduces the as-molded static charge for injection molded parts for Optical Disc applications. The use of resins with higher endcap levels in combination with antistatic additives provides a highly robust formulation suitable for even the most demanding emerging formats as Digital Versatile Disc (DVD) and in all commercial Optical media molding machines. Thus, optical quality polycarbonates are prepared by performing a base-catalyzed polymerization of a diaryl carbonate and a dihydric phenol under conditions effective to produce a polycarbonate product having an endcap level of 90% or greater.
摘要翻译： 将端盖水平提高到光学质量（OQ）的大约90％以上熔融聚碳酸酯显着降低了用于光盘应用的注塑部件的模制静电荷。 使用具有更高端帽水平的树脂与抗静电添加剂相结合提供了高度鲁棒的配方，适用于甚至最苛刻的新兴格式，如数字多功能光盘（DVD）和所有商业光学介质成型机。 因此，通过在有效地制备端帽水平为90％以上的聚碳酸酯制品的条件下进行碳酸二芳基酯和二元酚的碱催化聚合来制备光学质量的聚碳酸酯。
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