公开(公告)号：US20120187382A1

公开(公告)日：2012-07-26

申请号：US13141352

申请日：2009-12-22

申请人： Vsevolod Rostovtsev ,  Weiying Gao ,  Gary A. Johansson ,  Yulong Shen ,  Adam Fennimore ,  Kalindi Dogra ,  Hong Meng ,  Weishi Wu ,  Michael Henry Howard, JR. ,  Ralph Birchard Lloyd ,  Nora Sabina Radu ,  Norman Herron ,  Daniel David Lecloux ,  Eric Maurice Smith ,  Che-Hsiung Hsu ,  Kyung-Ho Park ,  Jeffrey A. Merlo ,  Christina M. Older ,  Jerald Feldman ,  Ying Wang

发明人： Vsevolod Rostovtsev ,  Weiying Gao ,  Gary A. Johansson ,  Yulong Shen ,  Adam Fennimore ,  Kalindi Dogra ,  Hong Meng ,  Weishi Wu ,  Michael Henry Howard, JR. ,  Ralph Birchard Lloyd ,  Nora Sabina Radu ,  Norman Herron ,  Daniel David Lecloux ,  Eric Maurice Smith ,  Che-Hsiung Hsu ,  Kyung-Ho Park ,  Jeffrey A. Merlo ,  Christina M. Older ,  Jerald Feldman ,  Ying Wang

IPC分类号： H01L51/54

CPC分类号： H01L51/0059 ,  H01L51/0035 ,  H01L51/0072 ,  H01L51/5012 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/5088

摘要： An organic light-emitting diode is provided having an anode, a cathode, and an organic active layer therebetween. The organic active layer includes a deuterated compound and the device has a calculated half-life at 1000 nits of at least 5000 hours.

摘要翻译： 提供了在其间具有阳极，阴极和有机活性层的有机发光二极管。 有机活性层包括氘代化合物，该装置的计算半衰期为1000尼特，至少5000小时。

公开(公告)号：US08617720B2

公开(公告)日：2013-12-31

申请号：US12643381

申请日：2009-12-21

申请人： Michael Henry Howard, Jr. ,  Nora Sabina Radu ,  Weishi Wu ,  Weiying Gao ,  Norman Herron ,  Eric Maurice Smith ,  Christina M. Older ,  Adam Fennimore ,  Ying Wang ,  Daniel David Lecloux ,  Kalindi Dogra ,  Vsevolod Rostovtsev ,  Jerald Feldman ,  Siddhartha Shenoy

发明人： Michael Henry Howard, Jr. ,  Nora Sabina Radu ,  Weishi Wu ,  Weiying Gao ,  Norman Herron ,  Eric Maurice Smith ,  Christina M. Older ,  Adam Fennimore ,  Ying Wang ,  Daniel David Lecloux ,  Kalindi Dogra ,  Vsevolod Rostovtsev ,  Jerald Feldman ,  Siddhartha Shenoy

IPC分类号： H01L51/54

CPC分类号： C09B57/008 ,  C09B57/00 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1044 ,  H01L51/0054 ,  H01L51/006 ,  H01L51/0085 ,  H01L51/5016 ,  H05B33/14 ,  H05B33/20

摘要： There is provided an electroactive composition including: a deuterated first host material and an electroluminescent dopant material. The first host is a compound having Formula I: The compound of Formula I is deuterated. In Formula I: Ar1 to Ar4 are the same or different and are aryl; Q is a multivalent aryl group or where T is (CR′)a, SiR2, S, SO2, PR, PO, PO2, BR, or R; R is the same or different at each occurrence and is an alkyl group or an ary group; R′ is the same or different at each occurrence and is selected H, D, or alkyl; a is an integer from 1-6; and m is an integer from 0-6.

摘要翻译： 提供了一种电活性组合物，其包括：氘代第一主体材料和电致发光掺杂剂材料。 第一主体是具有式I的化合物：式I的化合物是氘化的。 在式I中：Ar 1至Ar 4相同或不同，为芳基; Q是多价芳基或其中T是（CR'）a，SiR 2，S，SO 2，PR，PO，PO 2，BR或R; R在每次出现时相同或不同，为烷基或芳基; R'在每次出现时相同或不同，并选择H，D或烷基; a是1-6的整数; m为0-6的整数。

公开(公告)号：US20110147718A1

公开(公告)日：2011-06-23

申请号：US12643381

申请日：2009-12-21

申请人： Michael Henry Howard, JR. ,  Nora Sabina Radu ,  Weishi Wu ,  Weiying Gao ,  Norman Herron ,  Eric Maurice Smith ,  Christina M. Older ,  Adam Fennimore ,  Ying Wang ,  Daniel David Lecloux ,  Kalindi Dogra ,  Vsevolod Rostovtsev ,  Jerald Feldman ,  Siddhartha Shenoy

发明人： Michael Henry Howard, JR. ,  Nora Sabina Radu ,  Weishi Wu ,  Weiying Gao ,  Norman Herron ,  Eric Maurice Smith ,  Christina M. Older ,  Adam Fennimore ,  Ying Wang ,  Daniel David Lecloux ,  Kalindi Dogra ,  Vsevolod Rostovtsev ,  Jerald Feldman ,  Siddhartha Shenoy

IPC分类号： H01L51/54 ,  C09K11/06

CPC分类号： C09B57/008 ,  C09B57/00 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1044 ,  H01L51/0054 ,  H01L51/006 ,  H01L51/0085 ,  H01L51/5016 ,  H05B33/14 ,  H05B33/20

摘要： There is provided an electroactive composition including: a deuterated first host material and an electroluminescent dopant material. The first host is a compound having Formula I: The compound of Formula I is deuterated. In Formula I: Ar1 to Ar4 are the same or different and are aryl; Q is a multivalent aryl group or where T is (CR′)a, SiR2, S, SO2, PR, PO, PO2, BR, or R; R is the same or different at each occurrence and is an alkyl group or an ary group; R′ is the same or different at each occurrence and is selected H, D, or alkyl; a is an integer from 1-6; and m is an integer from 0-6.

摘要翻译： 提供了一种电活性组合物，其包括：氘代第一主体材料和电致发光掺杂剂材料。 第一主体是具有式I的化合物：式I的化合物是氘化的。 在式I中：Ar 1至Ar 4相同或不同，为芳基; Q是多价芳基或其中T是（CR'）a，SiR 2，S，SO 2，PR，PO，PO 2，BR或R; R在每次出现时相同或不同，为烷基或芳基; R'在每次出现时相同或不同，并选择H，D或烷基; a是1-6的整数; m为0-6的整数。

公开(公告)号：US09293716B2

公开(公告)日：2016-03-22

申请号：US13990832

申请日：2011-12-19

申请人： Jerald Feldman ,  Norman Herron ,  Michael Henry Howard, Jr. ,  Nora Sabina Radu ,  Vsevolod Rostovtsev ,  Kerwin D Dobbs ,  Adam Fennimore ,  Weiying Gao ,  Weishi Wu ,  Ying Wang ,  Charles D McLaren

发明人： Jerald Feldman ,  Norman Herron ,  Michael Henry Howard, Jr. ,  Nora Sabina Radu ,  Vsevolod Rostovtsev ,  Kerwin D Dobbs ,  Adam Fennimore ,  Weiying Gao ,  Weishi Wu ,  Ying Wang ,  Charles D McLaren

IPC分类号： H01L51/54 ,  C09K11/06 ,  H01L51/00 ,  H05B33/14 ,  H01L51/05 ,  H01L51/50

CPC分类号： H01L51/0072 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1003 ,  C09K2211/1029 ,  C09K2211/1059 ,  C09K2211/185 ,  H01L51/0061 ,  H01L51/0067 ,  H01L51/0074 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/0558 ,  H01L51/5016 ,  H01L2251/5384 ,  H05B33/14

摘要： This invention relates to a composition including (a) a dopant, (b) a first host having at least one unit of Formula I, and (c) a second host compound. Formula I has the structure where Q is a fused ring linkage having the formula In Formula I: R1 is the same or different at each occurrence and is D, alkyl, aryl, silyl, alkoxy, aryloxy, cyano, vinyl, or allyl; R2 is the same or different at each occurrence and is H, D, alkyl, or aryl, or both R2 are an N-heterocycle; R3 is the same or different at each occurrence and is H, D, cyano, alkyl or aryl; and a is the same or different at each occurrence and is an integer from 0-4.

摘要翻译： 本发明涉及包含（a）掺杂剂，（b）具有至少一个式I单元的第一主体和（c）第二主体化合物的组合物。 式I具有结构式，其中Q为具有式I的稠环键。式I中：R 1在每次出现时相同或不同，为D，烷基，芳基，甲硅烷基，烷氧基，芳氧基，氰基，乙烯基或烯丙基; R2在每次出现时相同或不同，为H，D，烷基或芳基，或两者均为N-杂环; R 3在每次出现时相同或不同，为H，D，氰基，烷基或芳基; 并且a在每次出现时相同或不同，为0-4的整数。

公开(公告)号：US20130248849A1

公开(公告)日：2013-09-26

申请号：US13990832

申请日：2011-12-19

申请人： Jerals Feldman ,  Norman Herron ,  Michael Henry Howard, JR. ,  Nora Sabina Radu ,  Vsevolod Rostovtsev ,  Kerwin D. Dobbs ,  Adam Fennimore ,  Weiying Gao ,  Weishi Wu ,  Ying Wang ,  Charles D. Mclaren

发明人： Jerals Feldman ,  Norman Herron ,  Michael Henry Howard, JR. ,  Nora Sabina Radu ,  Vsevolod Rostovtsev ,  Kerwin D. Dobbs ,  Adam Fennimore ,  Weiying Gao ,  Weishi Wu ,  Ying Wang ,  Charles D. Mclaren

IPC分类号： H01L51/00

CPC分类号： H01L51/0072 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1003 ,  C09K2211/1029 ,  C09K2211/1059 ,  C09K2211/185 ,  H01L51/0061 ,  H01L51/0067 ,  H01L51/0074 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/0558 ,  H01L51/5016 ,  H01L2251/5384 ,  H05B33/14

摘要： This invention relates to a composition including (a) a dopant, (b) a first host having at least one unit of Formula I, and (c) a second host compound. Formula I has the structure where Q is a fused ring linkage having the formula In Formula I: R1 is the same or different at each occurrence and is D, alkyl, aryl, silyl, alkoxy, aryloxy, cyano, vinyl, or allyl; R2 is the same or different at each occurrence and is H, D, alkyl, or aryl, or both R2 are an N-heterocycle; R3 is the same or different at each occurrence and is H, D, cyano, alkyl or aryl; and a is the same or different at each occurrence and is an integer from 0-4.

摘要翻译： 本发明涉及包含（a）掺杂剂，（b）具有至少一个式I单元的第一主体和（c）第二主体化合物的组合物。 式I具有结构式，其中Q为具有式I的稠环键。式I中：R 1在每次出现时相同或不同，为D，烷基，芳基，甲硅烷基，烷氧基，芳氧基，氰基，乙烯基或烯丙基; R2在每次出现时相同或不同，为H，D，烷基或芳基，或两者均为N-杂环; R 3在每次出现时相同或不同，为H，D，氰基，烷基或芳基; 并且a在每次出现时相同或不同，为0-4的整数。

公开(公告)号：US20100207108A1

公开(公告)日：2010-08-19

申请号：US12644362

申请日：2009-12-22

申请人： Norman Herron ,  Mark A. Guidry ,  Vsevolod Rostovtsev ,  Weiying Gao ,  Ying Wang ,  Yulong Shen ,  Jeffrey A. Merlo

发明人： Norman Herron ,  Mark A. Guidry ,  Vsevolod Rostovtsev ,  Weiying Gao ,  Ying Wang ,  Yulong Shen ,  Jeffrey A. Merlo

IPC分类号： H01L51/54 ,  C07D471/04

CPC分类号： C07D471/04 ,  C07D201/00 ,  C07D471/16 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/5012 ,  H01L51/5024 ,  H01L51/5052 ,  H01L51/5072 ,  H01L2251/5384

摘要： There is provided an organic electronic device having an anode, a hole injection layer, a photoactive layer, an electron transport layer, and a cathode. At least one of the photoactive layer and the electron transport layer includes a compound having Formula I where: R1 is the same or different and can be phenyl, biphenyl, naphthyl, naphthylphenyl, triphenylamino, or carbazolylphenyl; and one of the following conditions is met: (i) R2═R3 and is H, phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, or carbazolylphenyl; or (ii) R2 is H or phenyl; and R3 is phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, and carbazolylphenyl; When both R1 are phenyl, R2 and R3 can be 2-naphthyl, naphthylphenyl, arylanthracenyl, 9-phenanthryl, triphenylamino, or m-carbazolylphenyl.

摘要翻译： 提供了具有阳极，空穴注入层，光活性层，电子传输层和阴极的有机电子器件。 光活性层和电子传输层中的至少一个包括具有式I的化合物，其中：R 1相同或不同，可以是苯基，联苯基，萘基，萘基苯基，三苯基氨基或咔唑基苯基; 并且符合以下条件之一：（i）R 2 = R 3且为H，苯基，联苯基，萘基，萘基苯基，芳基蒽基，菲基，三苯基氨基或咔唑基苯基; 或（ii）R 2为H或苯基; 联苯基，萘基，萘基苯基，芳基蒽基，菲基，三苯基氨基和咔唑基苯基; 当R 1都是苯基时，R 2和R 3可以是2-萘基，萘基苯基，芳基蒽基，9-菲基，三苯基氨基或间 - 咔唑基苯基。

公开(公告)号：US08436341B2

公开(公告)日：2013-05-07

申请号：US12644362

申请日：2009-12-22

申请人： Norman Herron ,  Mark A. Guidry ,  Vsevolod Rostovtsev ,  Weiying Gao ,  Ying Wang ,  Yulong Shen ,  Jeffrey A. Merlo

发明人： Norman Herron ,  Mark A. Guidry ,  Vsevolod Rostovtsev ,  Weiying Gao ,  Ying Wang ,  Yulong Shen ,  Jeffrey A. Merlo

IPC分类号： H01L29/08 ,  H01L35/24 ,  H01L51/00

CPC分类号： C07D471/04 ,  C07D201/00 ,  C07D471/16 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/5012 ,  H01L51/5024 ,  H01L51/5052 ,  H01L51/5072 ,  H01L2251/5384

摘要： There is provided an organic electronic device having an anode, a hole injection layer, a photoactive layer, an electron transport layer, and a cathode. At least one of the photoactive layer and the electron transport layer includes a compound having Formula I where: R1 is the same or different and can be phenyl, biphenyl, naphthyl, naphthylphenyl, triphenylamino, or carbazolylphenyl; and one of the following conditions is met: (i) R2═R3 and is H, phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, or carbazolylphenyl; or (ii) R2 is H or phenyl; and R3 is phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, and carbazolylphenyl; When both R1 are phenyl, R2 and R3 can be 2-naphthyl, naphthylphenyl, arylanthracenyl, 9-phenanthryl, triphenylamino, or m-carbazolylphenyl.

摘要翻译： 提供了具有阳极，空穴注入层，光活性层，电子传输层和阴极的有机电子器件。 光活性层和电子传输层中的至少一个包括具有式I的化合物，其中：R 1相同或不同，可以是苯基，联苯基，萘基，萘基苯基，三苯基氨基或咔唑基苯基; 满足以下条件之一：（i）R2 = R3，为H，苯基，联苯基，萘基，萘基苯基，芳基蒽基，菲基，三苯基氨基或咔唑基苯基; 或（ii）R 2为H或苯基; 联苯基，萘基，萘基苯基，芳基蒽基，菲基，三苯基氨基和咔唑基苯基; 当R 1都是苯基时，R 2和R 3可以是2-萘基，萘基苯基，芳基蒽基，9-菲基，三苯基氨基或间 - 咔唑基苯基。

公开(公告)号：US08309731B2

公开(公告)日：2012-11-13

申请号：US13299845

申请日：2011-11-18

申请人： Norman Herron ,  Mark A. Guidry ,  Vsevolod Rostovtsev ,  Weiying Gao ,  Ying Wang ,  Yulong Shen ,  Jeffrey A. Merlo

发明人： Norman Herron ,  Mark A. Guidry ,  Vsevolod Rostovtsev ,  Weiying Gao ,  Ying Wang ,  Yulong Shen ,  Jeffrey A. Merlo

IPC分类号： C07D471/04 ,  C07D519/00

CPC分类号： C07D471/04 ,  C07D201/00 ,  C07D471/16 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/5012 ,  H01L51/5024 ,  H01L51/5052 ,  H01L51/5072 ,  H01L2251/5384

摘要： There is provided an organic electronic device having an anode, a hole injection layer, a photoactive layer, an electron transport layer, and a cathode. At least one of the photoactive layer and the electron transport layer includes a compound having Formula I where: R1 is the same or different and can be phenyl, biphenyl, naphthyl, naphthylphenyl, triphenylamino, or carbazolylphenyl; and one of the following conditions is met: (i) R2=R3 and is H, phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, or carbazolylphenyl; or (ii) R2 is H or phenyl; and R3 is phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, and carbazolylphenyl; When both R1 are phenyl, R2 and R3 can be 2-naphthyl, naphthylphenyl, arylanthracenyl, 9-phenanthryl, triphenylamino, or m-carbazolylphenyl.

摘要翻译： 提供了具有阳极，空穴注入层，光活性层，电子传输层和阴极的有机电子器件。 光活性层和电子传输层中的至少一个包括具有式I的化合物，其中：R 1相同或不同，可以是苯基，联苯基，萘基，萘基苯基，三苯基氨基或咔唑基苯基; 满足以下条件之一：（i）R2 = R3，为H，苯基，联苯基，萘基，萘基苯基，芳基蒽基，菲基，三苯基氨基或咔唑基苯基; 或（ii）R 2为H或苯基; 联苯基，萘基，萘基苯基，芳基蒽基，菲基，三苯基氨基和咔唑基苯基; 当R 1都是苯基时，R 2和R 3可以是2-萘基，萘基苯基，芳基蒽基，9-菲基，三苯基氨基或间 - 咔唑基苯基。

公开(公告)号：US20120065402A1

公开(公告)日：2012-03-15

申请号：US13299845

申请日：2011-11-18

申请人： NORMAN HERRON ,  Mark A. Guidry ,  Vsevolod Rostovtsev ,  Weiying Gao ,  Ying Wang ,  Yulong Shen ,  Jeffrey A. Merlo

发明人： NORMAN HERRON ,  Mark A. Guidry ,  Vsevolod Rostovtsev ,  Weiying Gao ,  Ying Wang ,  Yulong Shen ,  Jeffrey A. Merlo

IPC分类号： C07D471/04 ,  C07D519/00

CPC分类号： C07D471/04 ,  C07D201/00 ,  C07D471/16 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/5012 ,  H01L51/5024 ,  H01L51/5052 ,  H01L51/5072 ,  H01L2251/5384

摘要： There is provided an organic electronic device having an anode, a hole injection layer, a photoactive layer, an electron transport layer, and a cathode. At least one of the photoactive layer and the electron transport layer includes a compound having Formula I where: R1 is the same or different and can be phenyl, biphenyl, naphthyl, naphthylphenyl, triphenylamino, or carbazolylphenyl; and one of the following conditions is met: (i) R2=R3 and is H, phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, or carbazolylphenyl; or (ii) R2 is H or phenyl; and R3 is phenyl, biphenyl, naphthyl, naphthylphenyl, arylanthracenyl, phenanthryl, triphenylamino, and carbazolylphenyl; When both R1 are phenyl, R2 and R3 can be 2-naphthyl, naphthylphenyl, arylanthracenyl, 9-phenanthryl, triphenylamino, or m-carbazolylphenyl.

摘要翻译： 提供了具有阳极，空穴注入层，光活性层，电子传输层和阴极的有机电子器件。 光活性层和电子传输层中的至少一个包括具有式I的化合物，其中：R 1相同或不同，可以是苯基，联苯基，萘基，萘基苯基，三苯基氨基或咔唑基苯基; 满足以下条件之一：（i）R2 = R3，为H，苯基，联苯基，萘基，萘基苯基，芳基蒽基，菲基，三苯基氨基或咔唑基苯基; 或（ii）R 2为H或苯基; 联苯基，萘基，萘基苯基，芳基蒽基，菲基，三苯基氨基和咔唑基苯基; 当R 1都是苯基时，R 2和R 3可以是2-萘基，萘基苯基，芳基蒽基，9-菲基，三苯基氨基或间 - 咔唑基苯基。

公开(公告)号：US20110140092A1

公开(公告)日：2011-06-16

申请号：US13029494

申请日：2011-02-17

申请人： Norman Herron ,  Mark A. Guidry ,  Daniel David Lecloux ,  Nora Sabina Radu ,  Eric Maurice Smith ,  Ying Wang

发明人： Norman Herron ,  Mark A. Guidry ,  Daniel David Lecloux ,  Nora Sabina Radu ,  Eric Maurice Smith ,  Ying Wang

IPC分类号： H01L51/54 ,  H01L51/46

CPC分类号： C07D241/42 ,  C07C211/49 ,  C07C211/52 ,  C07C211/54 ,  C07C215/74 ,  C07C217/80 ,  C07C255/58 ,  C07D209/86 ,  C07D213/38 ,  C07D241/38 ,  C07D401/04 ,  C07D401/14 ,  C07D403/04 ,  C07D409/04 ,  C07D409/14 ,  C07D471/04 ,  C07D471/14 ,  C07D475/00 ,  C07D487/04 ,  C07F7/0838 ,  C08G61/122 ,  C08G61/124 ,  C08L65/00 ,  C09B11/10 ,  C09K11/06 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/0035 ,  H01L51/0043 ,  H01L51/005 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/0094 ,  H01L51/50 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5048 ,  H01L2251/308 ,  H05B33/14 ,  Y10S428/917

摘要： The present invention relates to charge transport compositions. The invention further relates to electronic devices in which there is at least one active layer comprising such charge transport compositions.