摘要:
A process for indicating the likelihood of cook-off for energetic materials by calculating the heat flux and chemical venting relative to known crial parameters for the energetic materials. The process further may include an alarm.
摘要:
An unsaturated acid-functional monomer having the structure: ##STR1## wherein R.sup.1 is hydrogen or methyl and Z is a direct bond or is a divalent radical having 1 to about 20 carbon atoms.
摘要:
An acid-functional polymer is obtained by the hydrolysis or half-ester ring opening reaction of an anhydride-functional polymer obtained by at least partially hydrogenating an unsaturated polymer which was obtained by reacting under ene reaction conditions:(i) an unsaturated anhydride having the structure: ##STR1## wherein R.sub.1 and R.sub.2 are each independently hydrogen, alkyl of 1 to about 6 carbons, or alkoxy of 1 to about 6 carbons, or a halogen; and(ii) at least one polyolefin having at least two carbon-carbon double bonds in the polyolefin backbone and having an average of at least three carbon atoms in the polyolefin backbone between the carbon-carbon double bonds.
摘要:
A substrate coated with a multi-layer decorative and/or protective coating which comprises:(a) a basecoat comprising a pigmented film-forming polymer; and(b) a transparent clearcoat comprising a film-forming polymer applied to the surface of the basecoat composition;the improvement which comprises utilizing as the clearcoat a multicomponent curable composition which is reactive upon mixing of the components, wherein the curable composition comprises:(i) an anhydride-functional compound having an average of at least two cyclic carboxylic acid anhydride groups per molecule; and(ii) a hydroxy-functional compound havng an average of at least two hydroxyl groups per molecule;wherein at least one of the compounds (i) or (ii) comprises a film forming polymer.
摘要:
Isocyanate functional polymers useful as crosslinking agents or as moisture curing polymers, which comprise the addition polymerization reaction product of:(a) 1 to 100% by weight of at least one isocyanate functional ethylenically unsaturated monomer which comprises the reaction product obtained by the gradual addition of an ethylenically unsaturated monomer having a single active hydrogen to a diisocyanate selected from the group consisting of isophorone diisocyanate and 2,4 toluene diisocyanate wherein the final molar ratio of active hydrogen containing monomer to diisocyanate is essentially 1 to 1; and(b) 0 to 99% by weight of at least one ethylenically unsaturated monomer which is free of active hydrogen functionality and which is copolymerizable with the ethylenically unsaturated isocyanate functional monomer.
摘要:
Novel carboxylic acid-functional polymers are obtained by reacting:(a) a hydroxy-functional polymer having an average of at least two hydroxyl groups per molecule; and(b) a cyclic anhydride under reaction conditions to produce acid groups and ester groups; andwherein the hydroxy-functional polymer is obtained by the copolymerization of:(i) 1-95 weight percent of a cellulose ester; and(ii) 5-99 weight percent of at least one ethylenically unsaturated alcohol copolymerizable with the cellulose acetate butyrate; and(iii) 0-94 weight percent of at least one other ethylenically unsaturated monomer copolymerizable with the cellulose ester and the ethylenically unsaturated alcohol.Curable compositions especially useful as coatings are prepared by mixing the novel carboxylic acid-functional polymers with epoxy-functional compounds and, optionally, with anhydride-functional compounds and, optionally, hydroxy-functional compounds. The coatings are especially useful in clearcoat/basecoat compositions.
摘要:
An anhydride-functional polymer is obtained by at least partially hydrogenating an unsaturated polymer which was obtained by reacting under ene reaction conditions: (i) an unsaturated anhydride having the structure: ##STR1## wherein R.sub.1 and R.sub.2 are each independently hydrogen, alkyl of 1 to about 6 carbons, or alkoxy of 1 to about 6 carbons, or a halogen; and (ii) at least one polyolefin having at least two carbon--carbon double bonds in the polyolefin backbone and having an average of at least three carbon atoms in the polyolefin backbone between the carbon--carbon double bonds.
摘要:
An unsaturated acid-functional monomer having the structure: ##STR1## wherein R.sup.1 is hydrogen or methyl and Z is nothing or is a divalent radical of 1 to about 20 carbons.
摘要:
A hydroxy-functional polymeric dispersant which is substantially free of acid groups, amine groups, and ethylenic unsaturation, the dispersant being especially adapted for dispersing pigments therein and being compatible with a variety of film-forming polymers, said dispersant being the free radical addition polymerization reaction product of a mixture of monomers consisting essentially of:(a) 15-30% by weight styrene; and(b) 15-30% by weight of at least one alkyl methacrylate monomer having 1 to 16 carbon atoms in the alkyl group; and(c) 20-60% by weight of at least one alkyl acrylate monomer having 1 to 16 carbon atoms in the alkyl group; and(d) 7-25% by weight of at least one hydroxy-functional ethylenically unsaturated monomer copolymerizable with monomers (a) (b) and (c);wherein said polymeric dispersant has a weight average molecular weight of 18,000 to 24,000, a number average molecular weight of 4,500 to 7,400, and a polydispersity of 2.9 to 4.2.
摘要:
An unsaturated ester monomer having the structure: ##STR1## wherein R.sup.1 is hydrogen or methyl; R.sup.2, R.sup.3 and R.sup.4 are each independently lower alkyl of 1 to about 4 carbons; and Z is nothing or is a divalent radical having 1 to about 20 carbons.