Hydrogenated polymers having acid functionality
    3.
    发明授权
    Hydrogenated polymers having acid functionality 失效
    具有酸官能度的氢化聚合物

    公开(公告)号:US5418307A

    公开(公告)日:1995-05-23

    申请号:US176174

    申请日:1994-01-03

    IPC分类号: C08F8/04 C08F220/18

    CPC分类号: C08F8/04 Y10T428/29

    摘要: An acid-functional polymer is obtained by the hydrolysis or half-ester ring opening reaction of an anhydride-functional polymer obtained by at least partially hydrogenating an unsaturated polymer which was obtained by reacting under ene reaction conditions:(i) an unsaturated anhydride having the structure: ##STR1## wherein R.sub.1 and R.sub.2 are each independently hydrogen, alkyl of 1 to about 6 carbons, or alkoxy of 1 to about 6 carbons, or a halogen; and(ii) at least one polyolefin having at least two carbon-carbon double bonds in the polyolefin backbone and having an average of at least three carbon atoms in the polyolefin backbone between the carbon-carbon double bonds.

    摘要翻译: 酸官能聚合物是通过将烯属反应条件下的反应得到的不饱和聚合物进行至少部分氢化得到的酸酐官能聚合物的水解或半酯开环反应得到的:(i)具有 结构:其中R 1和R 2各自独立地为氢,1至约6个碳的烷基或1至约6个碳的烷氧基或卤素; 和(ii)至少一种在聚烯烃骨架中具有至少两个碳 - 碳双键的聚烯烃,并且在碳 - 碳双键之间的聚烯烃骨架中平均具有至少三个碳原子。

    Isocyanate functional polymers
    5.
    发明授权
    Isocyanate functional polymers 失效
    异氰酸酯官能聚合物

    公开(公告)号:US4861853A

    公开(公告)日:1989-08-29

    申请号:US814336

    申请日:1985-12-27

    IPC分类号: C08F20/36 C08G18/72

    摘要: Isocyanate functional polymers useful as crosslinking agents or as moisture curing polymers, which comprise the addition polymerization reaction product of:(a) 1 to 100% by weight of at least one isocyanate functional ethylenically unsaturated monomer which comprises the reaction product obtained by the gradual addition of an ethylenically unsaturated monomer having a single active hydrogen to a diisocyanate selected from the group consisting of isophorone diisocyanate and 2,4 toluene diisocyanate wherein the final molar ratio of active hydrogen containing monomer to diisocyanate is essentially 1 to 1; and(b) 0 to 99% by weight of at least one ethylenically unsaturated monomer which is free of active hydrogen functionality and which is copolymerizable with the ethylenically unsaturated isocyanate functional monomer.

    摘要翻译: 可用作交联剂或湿固化聚合物的异氰酸酯官能聚合物,其包含加成聚合反应产物:(a)1至100重量%的至少一种异氰酸酯官能的烯属不饱和单体,其包含通过逐渐加成获得的反应产物 的具有单一活性氢的烯键式不饱和单体与选自异佛尔酮二异氰酸酯和2,4-甲苯二异氰酸酯的二异氰酸酯反应,其中含活性氢单体与二异氰酸酯的最终摩尔比基本上为1:1; 至少一种烯属不饱和单体,其不含活性氢官能团并且可与烯属不饱和异氰酸酯官能单体共聚。

    Acid-functional polymers derived from cellulose ester-unsaturated
alcohol copolymers, which are reacted with cyclic anhydrides
    6.
    发明授权
    Acid-functional polymers derived from cellulose ester-unsaturated alcohol copolymers, which are reacted with cyclic anhydrides 失效
    衍生自与环状酸酐反应的纤维素酯 - 不饱和醇共聚物的酸官能聚合物

    公开(公告)号:US4859758A

    公开(公告)日:1989-08-22

    申请号:US121265

    申请日:1987-11-16

    IPC分类号: C08F251/02

    CPC分类号: C08F251/02

    摘要: Novel carboxylic acid-functional polymers are obtained by reacting:(a) a hydroxy-functional polymer having an average of at least two hydroxyl groups per molecule; and(b) a cyclic anhydride under reaction conditions to produce acid groups and ester groups; andwherein the hydroxy-functional polymer is obtained by the copolymerization of:(i) 1-95 weight percent of a cellulose ester; and(ii) 5-99 weight percent of at least one ethylenically unsaturated alcohol copolymerizable with the cellulose acetate butyrate; and(iii) 0-94 weight percent of at least one other ethylenically unsaturated monomer copolymerizable with the cellulose ester and the ethylenically unsaturated alcohol.Curable compositions especially useful as coatings are prepared by mixing the novel carboxylic acid-functional polymers with epoxy-functional compounds and, optionally, with anhydride-functional compounds and, optionally, hydroxy-functional compounds. The coatings are especially useful in clearcoat/basecoat compositions.

    摘要翻译: 通过以下方法获得新型羧酸官能聚合物:(a)每分子平均具有至少两个羟基的羟基官能聚合物; 和(b)在酸性基团和酯基团的反应条件下的环状酸酐; 并且其中所述羟基官能聚合物通过以下共聚获得:(i)1-95重量%的纤维素酯; 和(ii)5-99重量%的可与乙酸丁酸纤维素共聚的至少一种烯属不饱和醇; 和(iii)0-94重量%的可与纤维素酯和烯键式不饱和醇共聚的至少一种其它烯属不饱和单体。 通过将新型羧酸官能聚合物与环氧官能化合物和任选的酸酐官能化合物和任选的羟基官能化合物混合来制备特别用作涂层的可固化组合物。 涂料在透明涂料/底漆组合物中特别有用。

    Hydrogenated polymers having anhydride functionality
    7.
    发明授权
    Hydrogenated polymers having anhydride functionality 失效
    具有酸酐官能度的氢化聚合物

    公开(公告)号:US5679742A

    公开(公告)日:1997-10-21

    申请号:US703180

    申请日:1996-08-26

    CPC分类号: C08F8/04 Y10T428/31855

    摘要: An anhydride-functional polymer is obtained by at least partially hydrogenating an unsaturated polymer which was obtained by reacting under ene reaction conditions: (i) an unsaturated anhydride having the structure: ##STR1## wherein R.sub.1 and R.sub.2 are each independently hydrogen, alkyl of 1 to about 6 carbons, or alkoxy of 1 to about 6 carbons, or a halogen; and (ii) at least one polyolefin having at least two carbon--carbon double bonds in the polyolefin backbone and having an average of at least three carbon atoms in the polyolefin backbone between the carbon--carbon double bonds.

    摘要翻译: 酸酐官能聚合物是通过至少部分氢化不饱和聚合物获得的,该不饱和聚合物是在烯醇反应条件下反应获得的:(i)具有以下结构的不饱和酸酐:其中R 1和R 2各自独立地为氢,烷基为1 至约6个碳原子,或1至约6个碳原子的烷氧基,或卤素; 和(ii)至少一种在聚烯烃骨架中具有至少两个碳 - 碳双键的聚烯烃,并且在碳 - 碳双键之间的聚烯烃骨架中平均具有至少三个碳原子。

    Dispersant polymers
    9.
    发明授权
    Dispersant polymers 失效
    分散剂聚合物

    公开(公告)号:US5554682A

    公开(公告)日:1996-09-10

    申请号:US455447

    申请日:1995-05-31

    CPC分类号: C09D7/02 C08F220/12

    摘要: A hydroxy-functional polymeric dispersant which is substantially free of acid groups, amine groups, and ethylenic unsaturation, the dispersant being especially adapted for dispersing pigments therein and being compatible with a variety of film-forming polymers, said dispersant being the free radical addition polymerization reaction product of a mixture of monomers consisting essentially of:(a) 15-30% by weight styrene; and(b) 15-30% by weight of at least one alkyl methacrylate monomer having 1 to 16 carbon atoms in the alkyl group; and(c) 20-60% by weight of at least one alkyl acrylate monomer having 1 to 16 carbon atoms in the alkyl group; and(d) 7-25% by weight of at least one hydroxy-functional ethylenically unsaturated monomer copolymerizable with monomers (a) (b) and (c);wherein said polymeric dispersant has a weight average molecular weight of 18,000 to 24,000, a number average molecular weight of 4,500 to 7,400, and a polydispersity of 2.9 to 4.2.

    摘要翻译: 基本上不含酸基,胺基和烯属不饱和度的羟基官能聚合物分散剂,该分散剂特别适于在其中分散颜料并与各种成膜聚合物相容,所述分散剂是自由基加成聚合 基本上由以下组成的单体混合物的反应产物:(a)15-30%(重量)苯乙烯; 和(b)15-30重量%的烷基中具有1至16个碳原子的至少一种甲基丙烯酸烷基酯单体; 和(c)20-60重量%的至少一种在烷基中具有1至16个碳原子的丙烯酸烷基酯单体; 和(d)7-25重量%的至少一种可与单体(a)(b)和(c)共聚的羟基官能的烯属不饱和单体; 其中所述聚合物分散剂的重均分子量为18,000至24,000,数均分子量为4,500至7400,多分散性为2.9至4.2。

    Ester-functional monomers and polymers prepared from same
    10.
    发明授权
    Ester-functional monomers and polymers prepared from same 失效
    酯官能单体和由其制备的聚合物

    公开(公告)号:US5349080A

    公开(公告)日:1994-09-20

    申请号:US176609

    申请日:1994-01-03

    申请人: Rodney M. Harris

    发明人: Rodney M. Harris

    IPC分类号: C07C69/604 C07C69/76

    CPC分类号: C07C69/604

    摘要: An unsaturated ester monomer having the structure: ##STR1## wherein R.sup.1 is hydrogen or methyl; R.sup.2, R.sup.3 and R.sup.4 are each independently lower alkyl of 1 to about 4 carbons; and Z is nothing or is a divalent radical having 1 to about 20 carbons.

    摘要翻译: 具有以下结构的不饱和酯单体:其中R 1是氢或甲基; R2,R3和R4各自独立地为1至约4个碳的低级烷基; 并且Z不是或是具有1至约20个碳的二价基团。