Ion chromatography system with flow-delay eluent recycle
    3.
    发明授权
    Ion chromatography system with flow-delay eluent recycle 有权
    离子色谱系统具有流动延迟洗脱液回收

    公开(公告)号:US07585679B1

    公开(公告)日:2009-09-08

    申请号:US12036147

    申请日:2008-02-22

    IPC分类号: G01N30/02

    摘要: A chromatographic method including chromatographically separating sample ionic species in an eluent stream, detecting the separated sample ionic species, catalytically combining hydrogen and oxygen gases or catalytically decomposing hydrogen peroxide in a catalytic gas elimination chamber, and recycling the effluent stream from the chamber to the chromatography separation column. The residence time between the detector and the chamber is at least about one minute. Also, flowing the recycle sequentially through two detector effluent flow channels of an electrolytic membrane suppressor. Also, applying heat or UV energy between the detector and the chamber. Also, detecting bubbles after the chamber. Also, a Platinum group metal catalyst and ion exchange medium in the chamber. Apparatus for performing the methods.

    摘要翻译: 一种色谱方法,包括在洗脱液流中色谱分离样品离子物质,检测分离的样品离子物质,催化结合氢气和氧气,或催化分解催化气体消除室中的过氧化氢,并将来自室的流出物流再循环至色谱 分离柱。 检测器和腔室之间的停留时间至少约1分钟。 此外,使循环物依次流过电解膜抑制器的两个检测器流出物流动通道。 此外,在检测器和室之间施加热或UV能量。 另外,在室后检测气泡。 此外,铂族金属催化剂和离子交换介质在室内。 用于执行方法的装置。

    Ion chromatography systems with flow-delay eluent recycle
    4.
    发明授权
    Ion chromatography systems with flow-delay eluent recycle 有权
    具有流动延迟洗脱液回收的离子色谱系统

    公开(公告)号:US08802011B2

    公开(公告)日:2014-08-12

    申请号:US13905548

    申请日:2013-05-30

    IPC分类号: G01N30/02 G01N30/26 G01N30/96

    摘要: A chromatographic method including chromatographically separating sample ionic species in an eluent stream, detecting the separated sample ionic species, catalytically combining hydrogen and oxygen gases or catalytically decomposing hydrogen peroxide in a catalytic gas elimination chamber, and recycling the effluent stream from the chamber to the chromatography separation column. The residence time between the detector and the chamber is at least about one minute. Also, flowing the recycle sequentially through two detector effluent flow channels of an electrolytic membrane suppressor. Also, applying heat or UV energy between the detector and the chamber. Also, detecting bubbles after the chamber. Also, a Platinum group metal catalyst and ion exchange medium in the chamber. Apparatus for performing the methods.

    摘要翻译: 一种色谱方法,包括在洗脱液流中色谱分离样品离子物质,检测分离的样品离子物质,催化结合氢气和氧气,或催化分解催化气体消除室中的过氧化氢,并将来自室的流出物流再循环至色谱 分离柱。 检测器和腔室之间的停留时间至少约1分钟。 此外,使循环物依次流过电解膜抑制器的两个检测器流出物流动通道。 此外,在检测器和室之间施加热或UV能量。 另外,在室后检测气泡。 此外,铂族金属催化剂和离子交换介质在室内。 用于执行方法的装置。

    Ion chromatography systems with flow-delay eluent recycle
    5.
    发明申请
    Ion chromatography systems with flow-delay eluent recycle 审中-公开
    具有流动延迟洗脱液回收的离子色谱系统

    公开(公告)号:US20090289009A1

    公开(公告)日:2009-11-26

    申请号:US12511788

    申请日:2009-07-29

    IPC分类号: G01N30/00 B01D15/08 B01J23/38

    摘要: A chromatographic method including chromatographically separating sample ionic species in an eluent stream, detecting the separated sample ionic species, catalytically combining hydrogen and oxygen gases or catalytically decomposing hydrogen peroxide in a catalytic gas elimination chamber, and recycling the effluent stream from the chamber to the chromatography separation column. The residence time between the detector and the chamber is at least about one minute. Also, flowing the recycle sequentially through two detector effluent flow channels of an electrolytic membrane suppressor. Also, applying heat or UV energy between the detector and the chamber. Also, detecting bubbles after the chamber. Also, a Platinum group metal catalyst and ion exchange medium in the chamber. Apparatus for performing the methods.

    摘要翻译: 一种色谱方法,包括在洗脱液流中色谱分离样品离子物质,检测分离的样品离子物质,催化结合氢气和氧气,或催化分解催化气体消除室中的过氧化氢,并将来自室的流出物流再循环至色谱 分离柱。 检测器和腔室之间的停留时间至少约1分钟。 此外,使循环物依次流过电解膜抑制器的两个检测器流出物流动通道。 此外,在检测器和室之间施加热或UV能量。 另外,在室后检测气泡。 此外,铂族金属催化剂和离子交换介质在室内。 用于执行方法的装置。

    ION CHROMATOGRAPHY SYSTEMS WITH FLOW-DELAY ELUENT RECYCLE
    6.
    发明申请
    ION CHROMATOGRAPHY SYSTEMS WITH FLOW-DELAY ELUENT RECYCLE 有权
    离子色谱系统与流延迟回收

    公开(公告)号:US20090211980A1

    公开(公告)日:2009-08-27

    申请号:US12036147

    申请日:2008-02-22

    IPC分类号: B01D15/08

    摘要: A chromatographic method including chromatographically separating sample ionic species in an eluent stream, detecting the separated sample ionic species, catalytically combining hydrogen and oxygen gases or catalytically decomposing hydrogen peroxide in a catalytic gas elimination chamber, and recycling the effluent stream from the chamber to the chromatography separation column. The residence time between the detector and the chamber is at least about one minute. Also, flowing the recycle sequentially through two detector effluent flow channels of an electrolytic membrane suppressor. Also, applying heat or UV energy between the detector and the chamber. Also, detecting bubbles after the chamber. Also, a Platinum group metal catalyst and ion exchange medium in the chamber. Apparatus for performing the methods.

    摘要翻译: 一种色谱方法,包括在洗脱液流中色谱分离样品离子物质,检测分离的样品离子物质,催化结合氢气和氧气,或催化分解催化气体消除室中的过氧化氢,并将来自室的流出物流再循环至色谱 分离柱。 检测器和腔室之间的停留时间至少约1分钟。 此外,使循环物依次流过电解膜抑制器的两个检测器流出物流动通道。 此外,在检测器和室之间施加热或UV能量。 另外,在室后检测气泡。 此外,铂族金属催化剂和离子交换介质在室内。 用于执行方法的装置。

    ION CHROMATOGRAPHY SYSTEMS WITH FLOW-DELAY ELUENT RECYCLE
    7.
    发明申请
    ION CHROMATOGRAPHY SYSTEMS WITH FLOW-DELAY ELUENT RECYCLE 有权
    离子色谱系统与流延迟回收

    公开(公告)号:US20110174737A1

    公开(公告)日:2011-07-21

    申请号:US13075009

    申请日:2011-03-29

    IPC分类号: B01D15/08

    摘要: A chromatographic method including chromatographically separating sample ionic species in an eluent stream, detecting the separated sample ionic species, catalytically combining hydrogen and oxygen gases or catalytically decomposing hydrogen peroxide in a catalytic gas elimination chamber, and recycling the effluent stream from the chamber to the chromatography separation column. The residence time between the detector and the chamber is at least about one minute. Also, flowing the recycle sequentially through two detector effluent flow channels of an electrolytic membrane suppressor. Also, applying heat or UV energy between the detector and the chamber. Also, detecting bubbles after the chamber. Also, a Platinum group metal catalyst and ion exchange medium in the chamber. Apparatus for performing the methods.

    摘要翻译: 一种色谱方法,包括在洗脱液流中色谱分离样品离子物质,检测分离的样品离子物质,催化结合氢气和氧气,或催化分解催化气体消除室中的过氧化氢,并将来自室的流出物流再循环至色谱 分离柱。 检测器和腔室之间的停留时间至少约1分钟。 此外,使循环物依次流过电解膜抑制器的两个检测器流出物流动通道。 此外,在检测器和室之间施加热或UV能量。 另外,在室后检测气泡。 此外,铂族金属催化剂和离子交换介质在室内。 用于执行方法的装置。

    ELECTROSTATICALLY BOUND HYPERBRANCHED ANION EXCHANGE SURFACE COATING PREPARED VIA CONDENSATION POLYMERIZATION USING DITERTIARY AMINE LINKERS FOR IMPROVED DIVALENT ANION SELECTIVITY
    10.
    发明申请
    ELECTROSTATICALLY BOUND HYPERBRANCHED ANION EXCHANGE SURFACE COATING PREPARED VIA CONDENSATION POLYMERIZATION USING DITERTIARY AMINE LINKERS FOR IMPROVED DIVALENT ANION SELECTIVITY 有权
    通过使用文献链式连接器进行冷凝聚合制备的静电粘合的绝缘阴离子交换膜表面涂层,用于改进的多种阴离子选择性

    公开(公告)号:US20120231195A1

    公开(公告)日:2012-09-13

    申请号:US13416891

    申请日:2012-03-09

    IPC分类号: B32B1/08 C08J5/22

    摘要: The present invention provides a new design for high capacity stationary phases for dianion selective ion chromatography. The stationary phases include one or more layers which are products of condensation polymerization. Multiple components are of use in forming the first polymer layer and the condensation polymer structure, thereby providing a stationary phase that can be engineered to have a desired property such as ion capacity, ion selectivity, and the like. Exemplary condensation polymers are formed by the reaction of at least one polyfunctional compound with at least one compound of complimentary reactivity, e.g., a nucleophilic polyfunctional compound reacting with an electrophilic compound.

    摘要翻译: 本发明提供了用于双阴离子选择性离子色谱法的高容量固定相的新设计。 固定相包括一个或多个作为缩聚产物的层。 多个组分可用于形成第一聚合物层和缩聚物结构,从而提供可被工程化以具有所需性质如离子容量,离子选择性等的固定相。 示例性缩合聚合物通过至少一种多官能化合物与至少一种互补反应性化合物的反应形成,例如与亲电子化合物反应的亲核多官能化合物。