摘要:
A method for preparing a functionalized polymer comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with at least one functionalizing agent defined by the formula (I) where A is a substituent that will undergo an addition reaction with a pseudo-living polymer, R1 is a divalent organic group, R2 is a monovalent organic group, and each R4, which may be the same or different, is a monovalent organic group or a substituent defined by —OR5 where R5 is a monovalent organic group, with the proviso that A, R1, R2, R4, and R5 are substituents that will not protonate a pseudo-living polymer. Also, the functionalized polymer and a vulcanizable composition containing the polymer.
摘要:
A functionalized polymer prepared by a process comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with a functionalizing agent defined by the formula (I) A-R1-Z (I) where R1 is a divalent bond or divalent organic group comprising from 0 to about 20 carbon atoms, A is a substituent that will undergo an addition reaction with a pseudo-living polymer, and Z is a substituent that will react or interact with silica or carbon black reinforcing fillers, with the proviso that A, R1, and Z are substituents that will not protonate a pseudo-living polymer.
摘要:
A method for preparing a functionalized polymer comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, where said pseudo-living polymer is characterized by having greater than about 85 percent of the polymer in the cis microstructure and less than about 3 percent of the polymer is in the 1,2- or 3,4-microstructure, and reacting the pseudo-living polymer with at least one functionalizing agent defined by the formula (I) or (II) where Z is a substituent that will react or interact with organic or inorganic fillers; R1 is a single bond or a divalent organic group; R2 is a monovalent organic group or a divalent organic group that forms a cyclic organic group with R13 or R14; R3 is a single bond, a divalent organic group, or a trivalent organic group that forms a cyclic organic group with R4 or R5; R13 is a single bond, a divalent organic group, or a trivalent organic group that forms a cyclic organic group with R2 or R14; R4 is a monovalent organic group or a divalent organic group that forms a cyclic organic group with R3 or R5; R14 is a monovalent organic group or a divalent organic group that forms a cyclic organic group with R2 or R13; and R5 is a monovalent organic group or a divalent organic group that forms a cyclic organic group with R3 or R4; with the proviso that each group attached to the imino carbon is attached via a carbon atom and R1, R2 R3, R4, R5, R13, R14 and Z are substituents that will not protonate a pseudo-living polymer.
摘要:
A heat pump circuit is installed into the inner cavity of a chimney venting the combustion gases of a burner servicing a dwelling with the exterior heat pump coil mounted in an annular gap formed around the upper chimney end. A fan driven by the chimney draft augmented by the burner then rotates an exterior rank of blade segments above the annular space to draw ambient air across the exterior coil. A set of gated apertures in the chimney wall both above and below the flue damper then directs zoned airflows up into the chimney and across the inner coil that is deployed at, the lower, interior chimney opening with the air heated in a chamber surrounding the burner either selectively routed into the chimney to further increase the chimney draft or routed into the dwelling for warmth.
摘要:
Methods and systems for strategic planning of a first transportation organization such as an airline. A multi-player game model (502-530), such as a model simulating the strategy of the first organization and strategies of competitive organizations reacting to moves made by one another, can be used to derive demographics representing potential sales of transportation by the first organization. The first organization derives a feasible schedule for meeting the requirements for transportation specified by such demographics. The scheduling step provides realistic costs and revenues, allowing realistic evaluation of the strategy. The process can be repeated with multiple possible strategies to select a best strategy. Methods of revenue management can include automatically modifying a strategy based on similar multi-player game modeling.
摘要:
Methods for scheduling a transportation operation such as the operation of an airline. The method desirably selects a demand (100) for transportation specifying an origin, destination, and time of arrival or departure, and selects resources from a database of available resources such as aircraft (508), crew, and departure gates. The resource selection desirably is conducted so as to optimize a result function such as contribution to margin or other financial result from the particular operation specified in the demand. Upon developing a schedule fragment (108), the specified resources are committed, and the database of available resources is modified (110) to indicate that the resources are no longer available at the relevant times. The system then treats another demand and repeats the process so as to develop a full schedule. The system can develop a feasible schedule, even for a complex transportation operation in a brief time, typically in minutes or less. Schedules can be developed using alternative strategies and assumptions, and tested against one another.