公开(公告)号：US06426427B1

公开(公告)日：2002-07-30

申请号：US09935659

申请日：2001-08-24

申请人： Yoichi Tonomura ,  Tohru Kubota ,  Mikio Endo

发明人： Yoichi Tonomura ,  Tohru Kubota ,  Mikio Endo

IPC分类号： C07F708

CPC分类号： C07F7/14

摘要： A bissilylnorbornane compound is prepared by reacting 2,5-norbornadiene with a hydrogenchlorosilane in the presence of a mixture of a palladium compound and a phosphite or a palladium complex having a phosphate ligand as a catalyst. The bissilylnorbornane compound can be produced in high yields while suppressing formation of by-product nortricyclene.

摘要翻译： 通过在钯化合物和亚磷酸盐或具有磷酸盐配体作为催化剂的钯络合物的混合物存在下使2,5-降冰片二烯与氢氯硅烷反应来制备二苯基降冰片烷化合物。 双降冰片烷基化合物可以以高产率生产，同时抑制副产物诺里克林的形成。

公开(公告)号：US06359161B2

公开(公告)日：2002-03-19

申请号：US09852638

申请日：2001-05-11

申请人： Yoichi Tonomura ,  Tohru Kubota ,  Mikio Endo

发明人： Yoichi Tonomura ,  Tohru Kubota ,  Mikio Endo

IPC分类号： C07F708

CPC分类号： C07F7/14

摘要： A halopropyldimethylchlorosilane is prepared by reacting dimethylchlorosilane with an allyl halide in the presence of an iridium catalyst. The reaction is effected in the presence of an internal olefin compound, typically 1,5-cyclooctadiene. The internal olefin compound suppresses deactivation of the iridium catalyst during reaction. Using a smaller amount of the iridium catalyst, the process produces the halopropyldimethylchlorosilane in high yields.

摘要翻译： 卤代丙基二甲基氯硅烷通过使二氯甲硅烷与烯丙基卤化物在铱催化剂存在下反应来制备。 反应在内部烯烃化合物（通常为1,5-环辛二烯）的存在下进行。 内部烯烃化合物抑制反应期间铱催化剂的失活。 使用较少量的铱催化剂，该方法以高产率生产卤代丙基二甲基氯硅烷。

公开(公告)号：US06245925B1

公开(公告)日：2001-06-12

申请号：US09627074

申请日：2000-07-27

申请人： Yoichi Tonomura ,  Tohru Kubota ,  Mikio Endo

发明人： Yoichi Tonomura ,  Tohru Kubota ,  Mikio Endo

IPC分类号： C07F708

CPC分类号： C07F7/14

摘要： By reacting 4-vinyl-1-cyclohexene with a hydrogenchlorosilane compound in the presence of a platinum catalyst to give a reaction solution containing a monosilyl compound, removing the residual 4-vinyl-1-cyclohexene and isomers thereof from the reaction solution, and reacting the monosilyl compound again with the hydrogenchlorosilane compound, an organic silicon compound in which the two double bonds in 4-vinyl-1-cyclohexene have been hydrosilylated is produced in high yields.

摘要翻译： 通过在铂催化剂存在下使4-乙烯基-1-环己烯与氢氯硅烷化合物反应，得到含有单甲硅烷基化合物的反应溶液，从反应溶液中除去残留的4-乙烯基-1-环己烯及其异构体， 再次与高氯代硅烷化合物（其中4-乙烯基-1-环己烯中的两个双键已经被氢化硅烷化）的有机硅化合物再次产生单甲硅烷基化合物。

公开(公告)号：US06334935B1

公开(公告)日：2002-01-01

申请号：US09335772

申请日：1999-06-18

申请人： Katsuhiro Uehara ,  Mikio Endo ,  Tohru Kubota ,  Satoshi Uchida ,  Kanji Murofushi

发明人： Katsuhiro Uehara ,  Mikio Endo ,  Tohru Kubota ,  Satoshi Uchida ,  Kanji Murofushi

IPC分类号： B01D310

CPC分类号： C07F7/20 ,  C07F7/1804

摘要： A (meth)acryloxy-bearing alkoxysilane is isolated and purified to a high purity by distilling a reaction solution containing the (meth)acryloxy-bearing alkoxysilane in a thin-layer distillation device at a temperature of 90-160° C. and a vacuum of 1-15 mmHg. The resulting alkoxysilane product does not give rise to the quality problem that the product will gradually whiten during storage owing to contact with air. The occurrence of self-polymerization of the alkoxysilane is restrained.

摘要翻译： 含有（甲基）丙烯酰氧基的烷氧基硅烷通过在90-160℃的温度下在薄层蒸馏装置中蒸馏含有（甲基）丙烯酰氧基的烷氧基硅烷的反应溶液和真空，分离和纯化至高纯度 为1-15 mmHg。 所得到的烷氧基硅烷产物不会引起质量问题，即由于与空气接触，产品在储存期间将逐渐变白。 抑制烷氧基硅烷的自聚合的发生。

公开(公告)号：US5258537A

公开(公告)日：1993-11-02

申请号：US16289

申请日：1993-02-11

申请人： Masaki Takeuchi ,  Toshinobu Ishihara ,  Tohru Kubota ,  Mikio Endo

发明人： Masaki Takeuchi ,  Toshinobu Ishihara ,  Tohru Kubota ,  Mikio Endo

IPC分类号： B01J31/02 ,  C07B61/00 ,  C07F7/12 ,  C07F7/08

CPC分类号： C07F7/123

摘要： An organodisiloxane represented by the general formula: R.sup.1 R.sup.2 R.sup.3 SiOSiR.sup.4 R.sup.5 R.sup.6 is reacted with thionyl chloride in the presence of an ammonium salt represented by the general formula: R.sup.7 R.sup.8 R.sup.9 R.sup.10 NX wherein R.sup.1 to R.sup.5 and R.sup.10 may be the same or different and each represents a monovalent hydrocarbon group or a hydrogen atom; R.sup.7 to R.sup.9 may be the same or different and each represents a monovalent hydrocarbon group; and X represents a monovalent anion. Thus, organomonochlorosilanes represented by R.sup.1 R.sup.2 R.sup.3 SiCl and R.sup.4 R.sup.5 R.sup.6 SiCl can be obtained.

公开(公告)号：US5081260A

公开(公告)日：1992-01-14

申请号：US508570

申请日：1990-04-13

申请人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo

发明人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo

IPC分类号： C07F7/18 ,  C09K3/18

CPC分类号： C07F7/1824 ,  C09K3/18

摘要： 3-(2-oxo-1-pyrrolidinyl)-propylsilane compounds represented by the following general formula (I) are herein disclosed: ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrocarbon group having 1 to 4 carbon atoms; and n is an integer ranging from 0 to 2. The propylsilane compounds may be prepared by, for instance, reacting 1-allyl-2-oxopyrrolidine with a hydrogen silane such as trimethoxysilane or trichlorosilane in the presence of a platinum catalyst or further optionally reacting the resulting 3-(2-oxo-1-pyrrolidinyl)-propyl halogenosilane (in the case where a halogenosilane is used) with an alcohol such as methanol. These propylsilane compounds are effective as anti-clouding agent for treating the surface of a variety of substrate.

公开(公告)号：US5342984A

公开(公告)日：1994-08-30

申请号：US083288

申请日：1993-06-29

申请人： Tohru Kubota ,  Mikio Endo

发明人： Tohru Kubota ,  Mikio Endo

IPC分类号： B01J23/44 ,  B01J31/12 ,  B01J31/22 ,  C07B61/00 ,  C07F7/12 ,  C07F7/08

CPC分类号： C07F7/123

摘要： A triorganomonohalogenosilane is prepared by reacting a triorganomonohydrosilane represented by the following general formula (I):R.sup.1.sub.3 S i H (I)with a halogenated allyl compound represented by the following general formula (II): ##STR1## in the presence of metal palladium, or a salt or complex of palladium to replace the hydrogen atom directly bonded to the silicon atom of the triorganomonohydrosilane with a halogen atom. In Formula ( I ), the substituents R.sup.1 's directly bonded to the silicon atom may be identical to or different from one another and each represents a monovalent organic group. In Formula (II), the substituents R.sup.2 's may likewise be identical to or different from one another and each represents a hydrogen atom or a monovalent alkyl group and X represents a chlorine atom, a bromine atom or an iodine atom.

摘要翻译： 通过使由以下通式（I）表示的三有机单体硅烷：R 13 S i H（I）与由以下通式（II）表示的卤代烯丙基化合物：在金属存在下反应制备三有机单卤代硅烷： 钯或钯的盐或络合物，以与卤素原子直接键合到三有机基氢硅烷的硅原子上的氢原子。 式（I）中，与硅原子直接结合的取代基R 1'可以相同也可以不同，表示1价有机基团。 在式（II）中，取代基R2可以同样地彼此相同或不同，各自表示氢原子或一价烷基，X表示氯原子，溴原子或碘原子。

公开(公告)号：US5210252A

公开(公告)日：1993-05-11

申请号：US933665

申请日：1992-08-24

申请人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo ,  Katsuhiro Uehara

发明人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo ,  Katsuhiro Uehara

IPC分类号： C07F7/18 ,  C08F30/08

CPC分类号： C07F7/1832

摘要： The object of the present invention is to provide a styrene type alkoxysilane compound which is useful as a silane coupling agent or a polymerizable monomer and which can easily be synthesized and is not expensive.A 3-(vinylphenyloxy)propylsilane compound represented by the following general formula: ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrocarbon group having 1 to 4 carbon atoms and n is an integer ranging from 0 to 2.

公开(公告)号：US4895966A

公开(公告)日：1990-01-23

申请号：US387923

申请日：1989-08-01

申请人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo

发明人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo

IPC分类号： C07F7/08 ,  C07F7/18 ,  C08F30/08

CPC分类号： C07F7/0852 ,  C07F7/0818 ,  C07F7/182 ,  C08F30/08

摘要： The organosilane compound of the invention is represented by the general formulaCIFC.dbd.CF--O--(R.sup.1 --O--).sub.m --(--R.sup.2 --).sub.n --CHR.sup.3 --CH.sub.2 --SiR.sub.3,in which, for example, each R.sup.1 is an ethylene group, R.sup.2 is a methylene group, R.sup.3 is a hydrogen atom, each R is an alkyl or alkoxy group, the subscript m is zero, 1, 2 or 3 and the subscript n is zero or 1. The terminal group of CIFC.dbd.CF--O-- has copolymerizability with conventional fluorine-containing polymerizable unsaturated compounds, e.g., tetrafluoroethylene, so that it is useful as a modifying agent of fluorine-containing polymers. A synthetic method for the compound is disclosed.

摘要翻译： 本发明的有机硅烷化合物由通式CIFC = CF-O-（R1-O-）m - （ - R2-）n-CHR3-CH2-SiR3表示，其中，例如，每个R 1是乙烯 基团，R 2是亚甲基，R 3是氢原子，每个R是烷基或烷氧基，下标m是0,1,2或3，下标n是0或1.CFCFC的末端基团= CF -O-与常规含氟可聚合不饱和化合物（例如四氟乙烯）具有共聚性，因此其可用作含氟聚合物的改性剂。 公开了该化合物的合成方法。

公开(公告)号：US5455360A

公开(公告)日：1995-10-03

申请号：US107886

申请日：1993-08-18

申请人： Norihisa Mino ,  Kazufumi Ogawa ,  Toshinobu Ishihara ,  Mikio Endo ,  Tohru Kubota ,  Katsuya Takemura

发明人： Norihisa Mino ,  Kazufumi Ogawa ,  Toshinobu Ishihara ,  Mikio Endo ,  Tohru Kubota ,  Katsuya Takemura

IPC分类号： C08G77/26 ,  B05D1/18 ,  C07F7/12 ,  C07F7/18 ,  C08G77/28 ,  C08J5/18 ,  C09K3/16 ,  H01B1/12 ,  C07F7/10 ,  C07D207/323

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y10/00 ,  B82Y40/00 ,  C07F7/12 ,  C07F7/182 ,  C07F7/1836 ,  C07F7/1868

摘要： Disclosed are a conductive pyrrole derivative monomolecular film covalently bonded to a substrate surface and method of manufacturing the same, and a monomer used for forming the conductive pyrrole derivative monomolecular film and method of manufacturing the same. The invention relates to a monomolecular ultrathin film comprising 1-pyrrolyl groups and silicon groups. The monomer used for forming the film is provided by reacting .omega.-(1-pyrrolyl)-1-alkene compound to a monosilane derivative compound, in which three out of four hydrogen atoms of monosilane are replaced with halogen or alkoxy groups, in the presence of a transition metal catalyst. A substrate is dipped and held in a nonaqueous solution of the above-noted monomer, thus chemically bonding a monomolecular film to a substrate surface. Furthermore, a polypyrrole derivative ultrathin film is formed by the electrolytic or catalytic polymerization of the monomolecular film.

摘要翻译： 公开了共价键合到基材表面的导电吡咯衍生物单分子膜及其制备方法，以及用于形成导电吡咯衍生物单分子膜的单体及其制造方法。 本发明涉及包含1-吡咯基和硅基团的单分子超薄膜。 用于形成膜的单体是通过使ω-（1-吡咯基）-1-烯烃化合物与甲硅烷衍生物化合物反应而得到的，其中甲硅烷的四个氢原子中的三个被卤素或烷氧基取代， 的过渡金属催化剂。 将基材浸渍并保持在上述单体的非水溶液中，从而将单分子膜化学键合到基材表面。 此外，通过单分子膜的电解或催化聚合形成聚吡咯衍生物超薄膜。