公开(公告)号：US06498264B2

公开(公告)日：2002-12-24

申请号：US10087822

申请日：2002-03-05

申请人： Yoichi Tonomura ,  Tohru Kubota ,  Yasufumi Kubota

发明人： Yoichi Tonomura ,  Tohru Kubota ,  Yasufumi Kubota

IPC分类号： C07F718

CPC分类号： C07F7/1896

摘要： Silyl (meth)acrylate compounds each having attached to a silicon atom one very bulky tertiary hydrocarbon group and two branched hydrocarbon groups each having a hydrocarbon group at &agr;- or &bgr;-position or two cyclic hydrocarbon groups are very stable to hydrolysis and are useful raw materials from which hydrolyzable, self-erodible polymers for ship bottom paints are prepared.

摘要翻译： 各自具有连接到硅原子上的（甲基）丙烯酸甲硅烷酯化合物，一个非常大的叔烃基和两个在α或β-位或两个环烃基上具有烃基的支链烃基对于水解是非常稳定的，并且是有用的 制备用于船底涂料的可水解的自溶性聚合物的材料。

公开(公告)号：US06518447B2

公开(公告)日：2003-02-11

申请号：US09985528

申请日：2001-11-05

申请人： Yoichi Tonomura ,  Tohru Kubota ,  Yasufumi Kubota

发明人： Yoichi Tonomura ,  Tohru Kubota ,  Yasufumi Kubota

IPC分类号： C07F708

CPC分类号： C07F7/12 ,  C07F7/188

摘要： Chlorosilane compounds having a thexyl group which is a bulky substituent group are novel. The compounds are useful silylating agents because stable silylated products are obtained due to the bulky substituent group.

公开(公告)号：US07569691B2

公开(公告)日：2009-08-04

申请号：US11406239

申请日：2006-04-19

申请人： Yoichi Tonomura ,  Tohru Kubota

发明人： Yoichi Tonomura ,  Tohru Kubota

IPC分类号： C07D295/00 ,  C07D241/04

CPC分类号： C07F7/1804

摘要： A novel organoxysilane compound bearing a protected piperazino group is provided. It can impart rigidity, high mechanical strength, and transparency in the UV region when used in paints, adhesives and the like.

摘要翻译： 提供一种带有受保护的哌嗪基的新型有机氧基硅烷化合物。 当用于油漆，粘合剂等时，它可以赋予UV区域的刚性，高机械强度和透明度。

公开(公告)号：US20060241294A1

公开(公告)日：2006-10-26

申请号：US11406239

申请日：2006-04-19

申请人： Yoichi Tonomura ,  Tohru Kubota

发明人： Yoichi Tonomura ,  Tohru Kubota

IPC分类号： C07F7/02

CPC分类号： C07F7/1804

摘要： A novel organoxysilane compound bearing a protected piperazino group is provided. It can impart rigidity, high mechanical strength, and transparency in the UV region when used in paints, adhesives and the like.

公开(公告)号：US08178710B2

公开(公告)日：2012-05-15

申请号：US12606520

申请日：2009-10-27

申请人： Yoichi Tonomura ,  Tohru Kubota

发明人： Yoichi Tonomura ,  Tohru Kubota

IPC分类号： C07F7/18

CPC分类号： C07F7/0838

摘要： A silyl (meth)acrylate compound containing a siloxy group having a bulky substituent is provided. The compound is represented by the following general formula (1): wherein R1 and R2 are independently a C3-10 monovalent branched hydrocarbon group having a hydrocarbon group at α or β position or a monovalent C3-10 cyclic hydrocarbon group; R3, R4, and R5 are independently an unsubstituted or substituted C1-20 hydrocarbon group or a siloxy group represented by the following general formula (2): —OSiR7R8R9  (2) wherein R7, R8, and R9 are independently an unsubstituted or substituted C1-20 hydrocarbon group; and R6 is hydrogen atom or methyl group. This compound is hydrolyzed at a reduced speed, and use of a polymer obtained by copolymerization with an alkyl methacrylate is capable of suppressing attachment of marine organisms to the ship with no or reduced biocide, and this polymer is useful for a hydrolytic self-polishing paint.

摘要翻译： 提供含有大体积取代基的甲硅烷氧基的甲基（甲基）丙烯酸酯化合物。 该化合物由以下通式（1）表示：其中R 1和R 2独立地为在α或bgr具有烃基的C 3-10单价支链烃基; 位置或一价C 3-10环烃基; R3，R4和R5独立地为未取代或取代的C 1-20烃基或由以下通式（2）表示的甲硅烷氧基：-OSiR7R8R9（2）其中R7，R8和R9独立地为未取代或取代的C1 -20烃基; R6是氢原子或甲基。 该化合物以降低的速度水解，并且使用通过与甲基丙烯酸烷基酯共聚得到的聚合物能够抑制海洋生物与没有或减少的杀生物剂的船舶的附着，并且该聚合物可用于水解自抛光涂料 。

公开(公告)号：US20050234254A1

公开(公告)日：2005-10-20

申请号：US11104588

申请日：2005-04-13

申请人： Yoichi Tonomura ,  Tohru Kubota

发明人： Yoichi Tonomura ,  Tohru Kubota

IPC分类号： C07B61/00 ,  C07F7/10 ,  C07F7/18 ,  C07F7/02

CPC分类号： C07F7/10 ,  C07F7/1804

摘要： A silane compound of the following formula (1) having two or more protected functional groups A-R—Si(CH3)nX3-n  (1) wherein A represents a group of the following formula wherein R1, R2 and R3 each independently represent a monovalent hydrocarbon group having 1 to 10 carbon atoms, a is an integer of 1 to 10, and b is an integer of 1 to 10, or wherein R1, R2 and R3 are as defined above, R represents a linear or branched, divalent hydrocarbon group having 2 to 10 carbon atoms, X represents a halogen atom or an organoxy group having 1 to 10 carbon atoms, and n is 0, 1 or 2 is prevented from the reaction of the functional groups per self when undergoing modification or treatment. When the protection is removed after introduction of the protected functional groups, quantitative and efficient introduction of the two or more functional groups is ensured, resulting in more developed effects of modification and addition.

摘要翻译： 具有两个以上被保护官能团的下式（1）的硅烷化合物<？in-line-formula description =“In-line Formula”end =“lead”→> AR-Si（CH 3） （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A表示 下式的基团其中R 1，R 2和R 3各自独立地表示具有1至10个碳原子的一价烃基， a为1〜10的整数，b为1〜10的整数，或者R 1，R 2，R 3， R表示碳原子数2〜10的直链状或支链状的二价烃基，X表示卤素原子或碳原子数1〜10的有机氧基，n为0,1或2， 当进行改性或处理时，每个自身的官能团的反应。 引入保护的官能团之后，当保护被去除时，确保了两个或更多个官能团的定量和有效的引入，从而导致更显着的改性和添加效果。

公开(公告)号：US09567354B2

公开(公告)日：2017-02-14

申请号：US13370426

申请日：2012-02-10

申请人： Yoichi Tonomura ,  Tohru Kubota ,  Takayuki Honma

发明人： Yoichi Tonomura ,  Tohru Kubota ,  Takayuki Honma

IPC分类号： C07F7/18

CPC分类号： C07F7/1804

摘要： Novel amino acid-modified silane compounds having a weakly acidic amino group and a weakly basic carboxyl group are useful as a surface treating agent or textile treating agent.

摘要翻译： 具有弱酸性氨基和弱碱性羧基的新型氨基酸改性硅烷化合物可用作表面处理剂或纺织品处理剂。

公开(公告)号：US09126838B2

公开(公告)日：2015-09-08

申请号：US13822673

申请日：2011-09-02

申请人： Masayuki Hasegawa ,  Yoichi Tonomura ,  Tohru Kubota ,  Takeshi Aoyama ,  Shuji Tanaka

发明人： Masayuki Hasegawa ,  Yoichi Tonomura ,  Tohru Kubota ,  Takeshi Aoyama ,  Shuji Tanaka

IPC分类号： C01B33/08 ,  C01B33/107

CPC分类号： C01B33/10794 ,  C01B33/1071 ,  C01B33/10763 ,  C01B33/10778

摘要： The method comprises at least three steps of a hydrogenation step (101) and/or a chlorination step (102), an impurity conversion step (103), and a purification step (104). In the impurity conversion step (103), an aldehyde compound represented by the general formula Ar—R—CHO (Ar; denotes a substituted or unsubstituted aryl group, R; denotes an organic group having two or more carbon atoms) is added to convert donor impurities and acceptor impurities contained in a chlorosilane distillate to a high-boiling substance. The chlorosilane distillate after the donor impurities and acceptor impurities have been converted to a high-boiling substance is sent to the purification step (104). In the purification step (104), high purity chlorosilanes from which the donor impurities and acceptor impurities have been thoroughly removed are obtained by using a distillation column or the like, where the high purity chlorosilanes are recovered outside the system from the top of the column.

摘要翻译： 该方法包括氢化步骤（101）和/或氯化步骤（102），杂质转化步骤（103）和纯化步骤（104）的至少三个步骤。 在杂质转化步骤（103）中，添加由通式Ar-R-CHO（Ar;表示取代或未取代的芳基R表示具有两个或更多个碳原子的有机基团）表示的醛化合物以转化 供体杂质和包含在氯硅烷馏出物中的受主杂质转化成高沸点物质。 将供体杂质和受体杂质转化为高沸点物质后的氯硅烷馏出物送至纯化步骤（104）。 在纯化步骤（104）中，通过使用蒸馏塔等获得供体杂质和受体杂质被彻底除去的高纯度氯硅烷，其中高纯度氯硅烷从塔顶返回到系统外部 。

公开(公告)号：US20100317852A1

公开(公告)日：2010-12-16

申请号：US12797721

申请日：2010-06-10

申请人： Yoichi Tonomura ,  Tohru Kubota

发明人： Yoichi Tonomura ,  Tohru Kubota

IPC分类号： C07F7/10

CPC分类号： C08K5/544 ,  C07F7/081

摘要： Vinylsilane compounds having a specific amino group, typically diethylaminopropyldimethylvinylsilane, N-methylpiperazinylpropyldimethylvinylsilane, and bistrimethylsilylaminopropyldimethylvinylsilane are novel and useful as a modifier for polymers.

摘要翻译： 具有特定氨基的乙烯基硅烷化合物通常是二乙基氨基丙基二甲基乙烯基硅烷，N-甲基哌嗪基丙基二甲基乙烯基硅烷和双三甲基甲硅烷基氨基丙基二甲基乙烯基硅烷作为聚合物的改性剂。

公开(公告)号：US20130177492A1

公开(公告)日：2013-07-11

申请号：US13822673

申请日：2011-09-02

申请人： Masayuki Hasegawa ,  Yoichi Tonomura ,  Tohru Kubota ,  Takeshi Aoyama ,  Shuji Tanaka

发明人： Masayuki Hasegawa ,  Yoichi Tonomura ,  Tohru Kubota ,  Takeshi Aoyama ,  Shuji Tanaka

IPC分类号： C01B33/107

CPC分类号： C01B33/10794 ,  C01B33/1071 ,  C01B33/10763 ,  C01B33/10778

摘要： The method comprises at least three steps of a hydrogenation step (101) and/or a chlorination step (102), an impurity conversion step (103), and a purification step (104). In the impurity conversion step (103), an aldehyde compound represented by the general formula Ar—R—CHO (Ar; denotes a substituted or unsubstituted aryl group, R; denotes an organic group having two or more carbon atoms) is added to convert donor impurities and acceptor impurities contained in a chlorosilane distillate to a high-boiling substance. The chlorosilane distillate after the donor impurities and acceptor impurities have been converted to a high-boiling substance is sent to the purification step (104). In the purification step (104), high purity chlorosilanes from which the donor impurities and acceptor impurities have been thoroughly removed are obtained by using a distillation column or the like, where the high purity chlorosilanes are recovered outside the system from the top of the column.

摘要翻译： 该方法包括氢化步骤（101）和/或氯化步骤（102），杂质转化步骤（103）和纯化步骤（104）的至少三个步骤。 在杂质转化步骤（103）中，添加由通式Ar-R-CHO（Ar;表示取代或未取代的芳基R表示具有两个或更多个碳原子的有机基团）表示的醛化合物以转化 供体杂质和包含在氯硅烷馏出物中的受主杂质转化成高沸点物质。 将供体杂质和受体杂质转化为高沸点物质后的氯硅烷馏出物送至纯化步骤（104）。 在纯化步骤（104）中，通过使用蒸馏塔等获得供体杂质和受体杂质被彻底除去的高纯度氯硅烷，其中高纯度氯硅烷从塔顶返回到系统外部 。