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公开(公告)号：US08465877B2
公开(公告)日：2013-06-18
申请号：US12382651
申请日：2009-03-20
申请人： Yoko Hase , Tohru Shiga , Mitsuru Nakano , Kensuke Takechi , Norihiko Setoyama
发明人： Yoko Hase , Tohru Shiga , Mitsuru Nakano , Kensuke Takechi , Norihiko Setoyama
IPC分类号： H01M8/22
CPC分类号： H01M12/08 , H01M4/382 , H01M4/8605 , H01M4/9008 , H01M2004/8689 , Y02E60/128
摘要： A F-type electrochemical cell, which is a lithium air battery, includes a positive electrode facing a negative electrode composed of metallic lithium with a separator provided therebetween in a casing. Air is capable of flow to the positive electrode. A nonaqueous electrolytic solution is charged into a space between the positive electrode and the negative electrode. At least one of the positive electrode and the nonaqueous electrolytic solution of the lithium air battery contains a compound having a stable radical skeleton. The compound also serves as a redox catalyst for oxygen.
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公开(公告)号：US20090239113A1
公开(公告)日：2009-09-24
申请号：US12382651
申请日：2009-03-20
申请人： Yoko Hase , Tohru Shiga , Mitsuru Nakano , Kensuke Takechi , Norihiko Setoyama
发明人： Yoko Hase , Tohru Shiga , Mitsuru Nakano , Kensuke Takechi , Norihiko Setoyama
IPC分类号： H01M4/02
CPC分类号： H01M12/08 , H01M4/382 , H01M4/8605 , H01M4/9008 , H01M2004/8689 , Y02E60/128
摘要： A F-type electrochemical cell, which is a lithium air battery, includes a positive electrode facing a negative electrode composed of metallic lithium with a separator provided therebetween in a casing. Air is capable of flow to the positive electrode. A nonaqueous electrolytic solution is charged into a space between the positive electrode and the negative electrode. At least one of the positive electrode and the nonaqueous electrolytic solution of the lithium air battery contains a compound having a stable radical skeleton. The compound also serves as a redox catalyst for oxygen.
摘要翻译： 作为锂空气电池的F型电化学电池包括在壳体内设置有分隔件的由金属锂构成的负极的正电极。 空气能够流到正极。 将非水电解液填充到正极和负极之间的空间中。 锂空气电池的正极和非水电解液中的至少一种含有具有稳定的自由基骨架的化合物。 该化合物还用作氧的氧化还原催化剂。
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公开(公告)号：US06194650B1
公开(公告)日：2001-02-27
申请号：US09297051
申请日：1999-04-27
申请人： Hiroaki Wakayama , Yoshiaki Fukushima , Narihito Tatsuda , Yoshitsugu Kojima , Osami Kamigaito , Yasutomo Goto , Shinji Inagaki , Kenichirou Suzuki , Megumi Sasaki , Hiroaki Hayashi , Kazuo Higuchi , Norihiko Setoyama
发明人： Hiroaki Wakayama , Yoshiaki Fukushima , Narihito Tatsuda , Yoshitsugu Kojima , Osami Kamigaito , Yasutomo Goto , Shinji Inagaki , Kenichirou Suzuki , Megumi Sasaki , Hiroaki Hayashi , Kazuo Higuchi , Norihiko Setoyama
IPC分类号： H01L3100
CPC分类号： H01G4/005 , B01J20/3204 , B01J20/321 , B01J20/3212 , B01J20/3236 , B01J21/06 , B01J21/063 , B01J21/08 , B01J21/18 , B01J23/38 , B01J23/42 , B01J37/0215 , B01J37/0219 , B01J37/033 , H01G4/10 , H01G4/12
摘要： A coated material comprising a substrate which has micropores and a reaction product coated thereon along the surface configuration of the substrate and an inner wall of the micropores thereof. The coated material is preferably produced by performing a supercritical coating step wherein a reaction precursor is dissolved in a supercritical fluid to form a precursor fluid and then the precursor fluid is brought into contact with a substrate in the presence with a reaction initiator to allow a reaction between the reaction precursor and the reaction initiator, thereby coating a reaction product onto the substrate.
摘要翻译： 一种涂覆材料，其包括具有微孔的基底和沿着基底的表面形状涂覆在其上的反应产物及其微孔的内壁。 涂覆的材料优选通过进行超临界涂覆步骤来制备，其中将反应前体溶解在超临界流体中以形成前体流体，然后在反应引发剂存在下将前体流体与底物接触以允许反应 在反应前体和反应引发剂之间，从而将反应产物涂覆到基材上。
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公开(公告)号：US20080090128A1
公开(公告)日：2008-04-17
申请号：US11793309
申请日：2005-12-22
申请人： Katsushi Saito , Hiroaki Takahashi , Hideyasu Kawai , Toshiharu Tabata , Takahiro Nagata , Tomoaki Terada , Yosuke Horiuchi , Norihiko Setoyama , Takahiko Asaoka
发明人： Katsushi Saito , Hiroaki Takahashi , Hideyasu Kawai , Toshiharu Tabata , Takahiro Nagata , Tomoaki Terada , Yosuke Horiuchi , Norihiko Setoyama , Takahiko Asaoka
CPC分类号： B01J23/89 , B01J21/18 , B01J23/58 , B01J35/0013 , B01J35/006 , H01M4/86 , H01M4/921 , H01M4/926 , H01M2008/1095
摘要： A flooding phenomenon is suppressed in a high current density loading region so as to attempt the improvement of cell performance of fuel cells. An electrode catalyst for fuel cells, in which a catalyst comprising an alloy catalyst composed of a noble metal and one or more transition metals and having surface characteristics such that it shows a pH value in water of 6.0 or more is supported on conductive carriers, and a fuel cell using such electrode catalyst for fuel cells, are provided.
摘要翻译： 在高电流密度加载区域中抑制了泛洪现象，从而试图提高燃料电池的电池性能。 一种燃料电池用电极催化剂，其中，包含由贵金属和一种或多种过渡金属组成的合金催化剂，具有使其在水中的pH值为6.0以上的表面特性的催化剂负载在导电性载体上， 提供了使用这种燃料电池用电极催化剂的燃料电池。
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公开(公告)号：US06619071B2
公开(公告)日：2003-09-16
申请号：US10163732
申请日：2002-06-06
申请人： Hideaki Sato , Katsuya Ishii , Atsushi Kosaka , Shigeo Numazawa , Seiji Inoue , Kouji Inagaki , Kazuhisa Yano , Norihiko Setoyama , Yoshiaki Fukuyama
发明人： Hideaki Sato , Katsuya Ishii , Atsushi Kosaka , Shigeo Numazawa , Seiji Inoue , Kouji Inagaki , Kazuhisa Yano , Norihiko Setoyama , Yoshiaki Fukuyama
IPC分类号： F25B1500
CPC分类号： F25B17/083 , B60H1/3201 , F25B2500/29
摘要： In an adsorption-type refrigerating apparatus, an adsorber includes therein an adsorbent having a temperature-dependent characteristic in which an amount adsorbed in an adsorption step is larger than an amount adsorbed in a desorption step, even when a vapor pressure rate in the adsorption step is equal to or lower than a vapor pressure rate in the desorption step. Therefore, even when the cooling temperature of outside air for cooling the adsorbent increases, a sufficient cooling capacity can be obtained. In addition, a difference between the amount adsorbed in the adsorption step and the amount adsorbed in the desorption step can be made larger.
摘要翻译： 在吸附式制冷装置中，吸附塔具有吸附步骤中吸附的吸附量大于脱附工序吸附量的温度依赖特性的吸附剂，即使吸附工序中的蒸汽压力 等于或低于解吸步骤中的蒸汽压力速率。 因此，即使用于冷却吸附剂的外部空气的冷却温度升高，也能够获得足够的冷却能力。 此外，可以使吸附步骤中吸附的量与解吸步骤吸附量之间的差较大。
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公开(公告)号：US08361662B2
公开(公告)日：2013-01-29
申请号：US12440089
申请日：2007-09-05
申请人： Tsutomu Kajino , Norihiko Setoyama , Keiko Uemura , Hisao Kato , Kenji Kano , Seiya Tsujimura , Takeshi Sakurai , Kunishige Kataoka
发明人： Tsutomu Kajino , Norihiko Setoyama , Keiko Uemura , Hisao Kato , Kenji Kano , Seiya Tsujimura , Takeshi Sakurai , Kunishige Kataoka
CPC分类号： C12N11/14 , C12N9/0091 , G01N27/3271 , H01M4/8605 , H01M4/9008 , H01M4/9083 , H01M8/16 , Y02E60/527
摘要： A novel electrocatalyst made of an oxidase having high electron transfer efficiency and an enzymatic electrode using the same are provided. The electrocatalyst is made of CueO. The enzymatic electrode comprises a carbonaceous porous body and an electrocatalyst made of CueO supported on the surface of the carbonaceous porous body. CueO is preferably CueO from Escherichia coli. The carbonaceous porous body constituting the enzymatic electrode is preferably carbonaceous gel. Also, the enzymatic electrode may further comprise a mediator which facilitates transfer of electron between the carbonaceous porous body and said CueO.
摘要翻译： 提供了由具有高电子转移效率的氧化酶制成的新型电催化剂和使用其的酶电极。 电催化剂由CueO制成。 酶电极包括碳质多孔体和由碳质多孔体的表面上负载的CueO制成的电催化剂。 CueO优选来自大肠杆菌的CueO。 构成酶电极的碳质多孔体优选为碳质凝胶。 此外，酶电极还可以包含促进碳质多孔体和CueO之间的电子传递的介体。
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公开(公告)号：US20100040910A1
公开(公告)日：2010-02-18
申请号：US12440089
申请日：2007-09-05
申请人： Tsutomu Kajino , Norihiko Setoyama , Keiko Uemura , Hisao Kato , Kenji Kano , Seiya Tsujimura , Takeshi Sakurai , Kunishige Kataoka
发明人： Tsutomu Kajino , Norihiko Setoyama , Keiko Uemura , Hisao Kato , Kenji Kano , Seiya Tsujimura , Takeshi Sakurai , Kunishige Kataoka
CPC分类号： C12N11/14 , C12N9/0091 , G01N27/3271 , H01M4/8605 , H01M4/9008 , H01M4/9083 , H01M8/16 , Y02E60/527
摘要： A novel electrocatalyst made of an oxidase having high electron transfer efficiency and an enzymatic electrode using the same are provided. The electrocatalyst is made of CueO. The enzymatic electrode comprises a carbonaceous porous body and an electrocatalyst made of CueO supported on the surface of the carbonaceous porous body. CueO is preferably CueO from Escherichia coli. The carbonaceous porous body constituting the enzymatic electrode is preferably carbonaceous gel. Also, the enzymatic electrode may further comprise a mediator which facilitates transfer of electron between the carbonaceous porous body and said CueO.
摘要翻译： 提供了由具有高电子转移效率的氧化酶制成的新型电催化剂和使用其的酶电极。 电催化剂由CueO制成。 酶电极包括碳质多孔体和由碳质多孔体的表面上负载的CueO制成的电催化剂。 CueO优选来自大肠杆菌的CueO。 构成酶电极的碳质多孔体优选为碳质凝胶。 此外，酶电极还可以包含促进碳质多孔体和CueO之间的电子传递的介体。
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公开(公告)号：US20070196659A1
公开(公告)日：2007-08-23
申请号：US11218285
申请日：2005-08-31
CPC分类号： H01M4/926 , C01B32/00 , H01M4/90 , H01M4/9083 , Y10T428/30
摘要： A carbon gel composite material including: a carbon gel which is composed of primary particles with an average particle diameter of 2 to 50 nm, where no x-ray diffraction peaks are observed over a scan angle (2θ) range of 0.5 to 10° (CuK60 radiation) and where in a pore size distribution calculated from an adsorption/desorption isotherm, if a pore diameter corresponding to the peak of the pore size distribution is not smaller than 1 nm and is smaller than 10 nm (pore diameter (d)), pores accounting for 60% or more of the total pore volume have a pore diameter within plus or minus 2 nm of the pore diameter (d), and if a pore diameter corresponding to the peak of the pore size distribution is in a range of 10 to 50 nm (pore diameter (D)), pores accounting for 60% or more of the total pore volume have a pore diameter in a range of (0.75×D) to (1.25×D); and at least one adsorbed component selected from the group consisting of proteins, metal complexes and metals, which is adsorbed on the carbon gel.
摘要翻译： 一种碳凝胶复合材料，包括：由平均粒径为2〜50nm的一次粒子构成的碳凝胶，在0.5〜10°的扫描角（2θ）范围内不观察到x射线衍射峰 （CuK <60>辐射），并且在由吸附/解吸等温线计算的孔径分布中，如果对应于孔径分布的峰值的孔径不小于1nm并且小于 10nm（孔径（d）），占孔体积的60％以上的孔的孔径（d）的孔径在±2nm以内，如果孔径对应于 孔径分布在10〜50nm的范围（孔径（D）），占孔体积的60％以上的孔的孔径在（0.75×D）〜（1.25×D）的范围内， ; 以及吸附在碳凝胶上的至少一种选自蛋白质，金属络合物和金属的吸附组分。
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