摘要:
An object of the present invention is to provide an energy device excellent in input/output characteristics at a low temperature and various applications using the same. The present invention consists in an energy device comprising a positive electrode having a region where a faradic reaction occurs, and a negative electrode having a region where a faradic reaction occurs, wherein at least one of the positive and negative electrodes has a region where a faradic reaction having a reaction rate higher than that of the faradic reaction occurs or a region where a non-faradic reaction occurs.
摘要:
An object of the present invention is to provide an energy storage device excellent in input/output characteristics at low temperatures, a module thereof and a vehicle using the module. The present invention provides an energy storage device comprising: a positive electrode having a region where a reaction accompanied by charge exchange occurs; a negative electrode having a region where a reaction accompanied by charge exchange occurs; a separator electrically separating the positive and negative electrodes and allowing mobile ions to pass therethrough; an electrolytic solution having an aprotic nonaqueous solvent comprising the mobile ions; and a region in at least one of the positive and negative electrodes where a charge adsorbing/desorbing reaction occurs.
摘要:
An energy device having high input-output performance, in particular being excellent in low temperature performance. An energy device characterized by storing and discharging electric energy by both a faradaic reaction mechanism wherein mainly the oxidation state of an active material changes and electric charge transfers inside said active material and a non-faradaic reaction mechanism wherein mainly ions are physically absorbed and desorbed on the surface of an active material and resultantly electric charge is accumulated and discharged. Further, output performance at a low temperature is improved by providing an energy device characterized by storing and discharging electric energy by at least two kinds of reaction mechanisms that show low and high reaction rates respectively in faradaic reaction wherein mainly the oxidation state of an active material changes and electric charge transfers to said active material through an electrode interface. Furthermore, an energy device characterized by storing and discharging electric energy by at least two kinds of reaction mechanisms that show low and high reaction rates respectively in faradaic reaction wherein mainly the oxidation state of an active material changes and electric charge transfers to said active material through an electrode interface.
摘要:
An energy device with high input/output characteristics and superior characteristics particularly at low temperature. The energy device stores and releases electric energy by means of a faradaic reaction mechanism based mainly on the alteration of the oxidation state of an active material whereby charges move into the active material, and a non-faradaic reaction based mainly on the physical adsorption and separation of ions on the surface of an active material for storing or releasing charges. The output characteristics at low temperature are improved by employing at least two kinds of faradaic reaction mechanism, namely, one with low reaction rate and the other with high reaction rate, which is mainly based on the alteration of the oxide state of an active material for the transfer of charges into the active material via an electrode interface.
摘要:
A long-life electric energy storage device with superior high-input/output load resistance includes a cathode including a region having a faradic reaction mechanism and a region having a non-faradic reaction mechanism, and an anode including a region having a faradic reaction mechanism. When carbon material contained in the anode is represented by a diffraction line according to X-ray diffraction method, mainly the (001) plane is substantially detected.
摘要:
An energy storage device of excellent input/output characteristics and having high density of stored energy, the device having a cathode comprising a material conducting faradic reaction and a material conducting non-faradic reaction, and an anode comprising a material conducting faradic reaction, in which the faradic reaction is desorption/intercalation reaction of lithium ions, higher input/output characteristics being obtainable by providing a mix layer comprising a material conducting faradic reaction on a cathode collector and providing a material layer conducting non-faradic reaction further to the surface layer thereof.
摘要:
An energy storage device comprising a positive active material layer having a positive active material capable of inserting and releasing lithium ions, a positive electrode plate having a layer capable of effecting non-faradic like reaction upon physical adsorption and desorption of the ions to accumulate and discharge charges, and a negative plate having a negative active material layer made of carbonaceous material that is capable of absorbing and releasing mainly lithium in the ionized state in a collector, and an insulator layer for electrically insulating the positive electrode plate from the negative electrode plate that causes only mobile ions permeate.
摘要:
An energy storage device comprising a negative electrode plate having a negative electrode active material layer of a carbonaceous composite material formed on a negative electrode collector, a positive electrode plate having a positive electrode active material layer capable of inserting and releasing lithium ions and a non-faradic reaction layer capable of accumulating and releasing electric charges upon physical adsorption-desorption of ions on the surface layer of the positive electrode active material layer and an insulator layer for electrically insulating the positive electrode plate from the negative electrode plate, the insulator layer being capable of permeating only mobile ions. The carbonaceous composite material comprises particles of graphite and/or amorphous carbon and activated charcoal, and the particles of the graphite and/or amorphous carbon and particles of the activated charcoal are united.
摘要:
To acquire a high-output electrochemical energy storage device the range of operating voltage of which is large, a positive electrode provided with a positive electrode collector and positive electrode active material which is held by the positive electrode collector and can occlude/emit a metal ion, a negative electrode provided with a negative electrode collector and negative electrode active material which is held by the negative electrode collector and can occlude/emit the metal ion, a minutely porous separator held between the positive electrode and the negative electrode and an organic electrolyte are provided, and a range of operating voltage is equivalent to a range from below 2 V to 4 V or more.
摘要:
In a charging/discharging unit provided with: a lithium secondary battery, a voltage detecting sensor for detecting a voltage and a current detecting sensor; the charging/discharging control unit is further provided with a controller, and a discharging element for performing a constant voltage discharging operation of 3 V. A voltage, V0, of the battery when a discharging operation is terminated (t=0) is measured by the voltage detecting sensor. If V0≦3.6 V, within a rest time during which the battery is not charged/discharged until a next charging operation, a voltage, V1, of the battery when a time, t1, has elapsed is measured by the voltage detecting sensor. If this voltage charge is in a range of V1-V0≧0.2 V, then the constant voltage discharging operation of 3 V is carried out for a time duration longer than or equal to 1 hour.