Production process of poly(arylene sulfide) and poly(arylene sulfide)
    1.
    发明授权
    Production process of poly(arylene sulfide) and poly(arylene sulfide) 有权
    聚(亚芳基硫醚)和聚(亚芳基硫醚)的生产工艺

    公开(公告)号:US09096723B2

    公开(公告)日:2015-08-04

    申请号:US13989714

    申请日:2011-10-18

    IPC分类号: C08G75/16 C08G75/02

    CPC分类号: C08G75/16 C08G75/02

    摘要: A production process of a poly(arylene sulfide), including (a) a polymerization step of polymerizing at least one sulfur source selected from the group consisting of alkali metal sulfides and alkali metal hydrosulfides and a dihalo-aromatic compound in an organic amide solvent to form a polymer; (b) a separation step of separating the polymer from a liquid reaction mixture containing the polymer formed after the polymerization step; (c) a washing step of washing the polymer with at least one washing liquid selected from the group consisting of water, an organic solvent and a mixed solution of water and an organic solvent as desired; and (d) an aqueous oxidizing solution treatment step of treating the polymer by bringing the polymer into contact with an aqueous oxidizing solution.

    摘要翻译: 一种聚(亚芳基硫醚)的制造方法,包括(a)聚合步骤,将选自碱金属硫化物和碱金属氢硫化物中的至少一种硫源和二卤代芳族化合物在有机酰胺溶剂中聚合, 形成聚合物; (b)从含有聚合步骤后形成的聚合物的液体反应混合物分离聚合物的分离步骤; (c)洗涤步骤,根据需要用至少一种选自水,有机溶剂和水与有机溶剂的混合溶液的洗涤液洗涤聚合物; 和(d)通过使聚合物与氧化水溶液接触来处理聚合物的水性氧化溶液处理步骤。

    Production Process of Poly(Arylene Sulfide) and Poly(Arylene Sulfide)
    2.
    发明申请
    Production Process of Poly(Arylene Sulfide) and Poly(Arylene Sulfide) 有权
    聚(亚硫酰基)和聚(亚硫酰基)的生产工艺

    公开(公告)号:US20130253147A1

    公开(公告)日:2013-09-26

    申请号:US13989714

    申请日:2011-10-18

    IPC分类号: C08G75/16

    CPC分类号: C08G75/16 C08G75/02

    摘要: A production process of a poly(arylene sulfide), including (a) a polymerization step of polymerizing at least one sulfur source selected from the group consisting of alkali metal sulfides and alkali metal hydrosulfides and a dihalo-aromatic compound in an organic amide solvent to form a polymer; (b) a separation step of separating the polymer from a liquid reaction mixture containing the polymer formed after the polymerization step; (c) a washing step of washing the polymer with at least one washing liquid selected from the group consisting of water, an organic solvent and a mixed solution of water and an organic solvent as desired; and (d) an aqueous oxidizing solution treatment step of treating the polymer by bringing the polymer into contact with an aqueous oxidizing solution.

    摘要翻译: 一种聚(亚芳基硫醚)的制造方法,包括(a)聚合步骤,将选自碱金属硫化物和碱金属氢硫化物中的至少一种硫源和二卤代芳族化合物在有机酰胺溶剂中聚合, 形成聚合物; (b)从含有聚合步骤后形成的聚合物的液体反应混合物分离聚合物的分离步骤; (c)洗涤步骤,根据需要用至少一种选自水,有机溶剂和水与有机溶剂的混合溶液的洗涤液洗涤聚合物; 和(d)通过使聚合物与氧化水溶液接触来处理聚合物的水性氧化溶液处理步骤。

    Process for Producing Poly(Arylene Sulfide), and Poly(Arylene Sulfide)
    3.
    发明申请
    Process for Producing Poly(Arylene Sulfide), and Poly(Arylene Sulfide) 有权
    生产聚(亚硫酰亚胺)和聚(亚硫酰亚胺)的方法

    公开(公告)号:US20130065054A1

    公开(公告)日:2013-03-14

    申请号:US13698600

    申请日:2011-04-21

    IPC分类号: C08G75/16

    摘要: Disclosed is a process for producing poly(arylene sulfide) which includes: a polymerization step of polymerizing a dihalogenated aromatic compound and at least one sulfur source selected from the group consisting of alkali metal sulfides and alkali metal hydrogen sulfides in an organic amide solvent, preferably in the presence of a phase separating agent; a separation step of separating a polymer from a reaction liquid containing a produced polymer after the polymerization step; a washing step of washing the polymer with a washing liquid that consists of water and/or an organic solvent; and a separated liquid treatment step of bringing both a separated liquid that has been recovered after the separation of the polymer in the separation step and a separated liquid containing a wash waste liquid that has been recovered after the separation of the polymer in the washing step into contact with an alkaline compound. Also disclosed is poly(arylene sulfide).

    摘要翻译: 公开了一种生产聚(亚芳基硫醚)的方法,其包括:在有机酰胺溶剂中聚合二卤代芳族化合物和至少一种选自碱金属硫化物和碱金属硫化氢的硫源的聚合步骤,优选 在相分离剂的存在下; 在聚合步骤之后从含有生成的聚合物的反应液中分离聚合物的分离步骤; 用由水和/或有机溶剂组成的洗涤液洗涤聚合物的洗涤步骤; 以及分离液体处理步骤,在分离步骤中分离聚合物之后已经回收的分离液体和在洗涤步骤中分离聚合物之后已经回收的含有洗涤废液的分离液体进入 与碱性化合物接触。 还公开了聚(亚芳基硫醚)。

    Process for producing poly(arylene sulfide), and poly(arylene sulfide) comprising contacting a wash liquid with an alkaline compound
    4.
    发明授权
    Process for producing poly(arylene sulfide), and poly(arylene sulfide) comprising contacting a wash liquid with an alkaline compound 有权
    包括使洗涤液与碱性化合物接触的制备聚(亚芳基硫醚)和聚(亚芳基硫醚)的方法

    公开(公告)号:US09068047B2

    公开(公告)日:2015-06-30

    申请号:US13698600

    申请日:2011-04-21

    IPC分类号: C08G75/02 C08G75/14

    摘要: Disclosed is a process for producing poly(arylene sulfide) which includes: a polymerization step of polymerizing a dihalogenated aromatic compound and at least one sulfur source selected from the group consisting of alkali metal sulfides and alkali metal hydrogen sulfides in an organic amide solvent, preferably in the presence of a phase separating agent; a separation step of separating a polymer from a reaction liquid containing a produced polymer after the polymerization step; a washing step of washing the polymer with a washing liquid that consists of water and/or an organic solvent; and a separated liquid treatment step of bringing both a separated liquid that has been recovered after the separation of the polymer in the separation step and a separated liquid containing a wash waste liquid that has been recovered after the separation of the polymer in the washing step into contact with an alkaline compound. Also disclosed is poly(arylene sulfide).

    摘要翻译: 公开了一种生产聚(亚芳基硫醚)的方法,其包括:在有机酰胺溶剂中聚合二卤代芳族化合物和至少一种选自碱金属硫化物和碱金属硫化氢的硫源的聚合步骤,优选 在相分离剂的存在下; 在聚合步骤之后从含有生成的聚合物的反应液中分离聚合物的分离步骤; 用由水和/或有机溶剂组成的洗涤液洗涤聚合物的洗涤步骤; 以及分离液体处理步骤,在分离步骤中分离聚合物之后已经回收的分离液体和在洗涤步骤中分离聚合物之后已经回收的含有洗涤废液的分离液体进入 与碱性化合物接触。 还公开了聚(亚芳基硫醚)。

    Longitudinal Solid-Liquid Countercurrent Contact Method, Method of Washing Solid Particles, Method of Manufacturing Poly(Arylene Sulfide) and Apparatus
    5.
    发明申请
    Longitudinal Solid-Liquid Countercurrent Contact Method, Method of Washing Solid Particles, Method of Manufacturing Poly(Arylene Sulfide) and Apparatus 审中-公开
    纵向固液反向接触法,固体颗粒洗涤方法,聚(亚硫酰基)制备方法及装置

    公开(公告)号:US20130068256A1

    公开(公告)日:2013-03-21

    申请号:US13699143

    申请日:2011-04-20

    IPC分类号: B08B3/04

    摘要: A longitudinal solid-liquid countercurrent contact method and apparatus are provided in which an aqueous slurry containing solid particles is supplied from an upper part and is caused to pass through a plurality of contact-processing chambers connected in a vertical direction while being caused to proceed downward, a contacting liquid is supplied from a lower part and is caused to pass through the plurality of contact-processing chambers connected in the vertical direction while being caused to proceed upward, and the aqueous slurry and the contacting liquid are caused to be continuously subjected to countercurrent contact, wherein the viscosity of a liquid phase in at least one of the contact-processing chambers is controlled, and especially the viscosity η1 of a liquid phase in a contact-processing chamber positioned at an uppermost part is controlled to fall within a range of 0.9≦η1/η0≦2.0 with respect to the reference viscosity η0 as the viscosity of a predetermined reference composition of a liquid phase at a predetermined temperature.

    摘要翻译: 提供了一种纵向固液逆流接触方法和装置,其中含有固体颗粒的含水浆料从上部供应并使其通过在垂直方向上连接的多个接触处理室,同时使其向下 从下部供给接触液体,使其在垂直方向上连续通过的多个接触处理室通过,同时使上述水性浆料和接触液体连续地进行 逆流接触,其中控制至少一个接触处理室中的液相的粘度,特别是控制位于最上部的接触处理室中的液相的粘度等于1 相对于参考粘度&eegr; 0作为p的粘度,范围为0.9≦̸&eegr; 1 / eegr; 0≦̸ 2.0 在预定温度下液相的重新确定的参考组合物。

    EXCAVATION MACHINE
    7.
    发明申请
    EXCAVATION MACHINE 有权
    挖掘机

    公开(公告)号:US20140084668A1

    公开(公告)日:2014-03-27

    申请号:US14112793

    申请日:2012-06-27

    IPC分类号: E21D9/11

    CPC分类号: E21D9/112

    摘要: An excavation machine having a cutter head with a large diameter while making it possible to excavate excavation objects such as hard bedrock etc. with high efficiency is provided. The excavation machine comprises an outer circumference cutter head 20 having a circular opening and being rotated and contacted to excavation objects and a small diameter cutter head 23 disposed in the opening and rotatable independently from the outer circumference cutter head. Rotation centers of the rotation disk and the rotation plate are gapped and the gap is shorter than a rotation radius of the small diameter cutter head.

    摘要翻译: 提供了具有大直径的切割头的挖掘机,同时能够高效率地挖掘诸如硬质基岩等挖掘对象。 挖掘机包括具有圆形开口并与挖掘物体旋转接触的外圆周切割头20和设置在开口中并与外周切割头独立旋转的小直径刀头23。 旋转盘和旋转板的旋转中心被间隙并且间隙比小直径刀头的旋转半径短。

    Spectral image acquiring apparatus
    8.
    发明授权
    Spectral image acquiring apparatus 有权
    光谱图像采集装置

    公开(公告)号:US08593631B2

    公开(公告)日:2013-11-26

    申请号:US13275572

    申请日:2011-10-18

    IPC分类号: G01J3/40 G01J3/45 G01B9/02

    摘要: A spectral image acquiring apparatus includes an optical filter on which light is incident; an image sensor including a two-dimensionally disposed pixel array for detecting the light via the optical filter; and a signal processing unit generating a difference-value image based on a detection signal from the image sensor. The optical filter includes a diffraction grating having a lattice pattern corresponding to one or more pixels on the image sensor. The signal processing unit calculates a difference value in an amount of received light between two adjacent pixels based on the detection signal from the image sensor, and generates the difference-value image based on the difference value. The difference value between the two adjacent pixels is varied depending on a difference in an interference point on the image sensor corresponding to a diffraction angle of the light that has passed through the diffraction grating.

    摘要翻译: 光谱图像获取装置包括光入射的滤光器; 图像传感器,包括用于经由滤光器检测光的二维布置的像素阵列; 以及信号处理单元,其基于来自图像传感器的检测信号生成差值图像。 光学滤波器包括具有对应于图像传感器上的一个或多个像素的格子图案的衍射光栅。 信号处理单元基于来自图像传感器的检测信号计算两个相邻像素之间的接收光量的差值,并基于差值生成差值图像。 两个相邻像素之间的差值取决于对应于已经通过衍射光栅的光的衍射角的图像传感器上的干涉点的差异。

    Liquid droplet recognition apparatus, raindrop recognition apparatus, and on-vehicle monitoring apparatus
    9.
    发明授权
    Liquid droplet recognition apparatus, raindrop recognition apparatus, and on-vehicle monitoring apparatus 有权
    液滴识别装置,雨滴识别装置和车载监视装置

    公开(公告)号:US08466960B2

    公开(公告)日:2013-06-18

    申请号:US12693864

    申请日:2010-01-26

    IPC分类号: H04N7/18

    摘要: Disclosed is a liquid droplet recognition apparatus for detecting liquid droplets attached to a front surface of a transparent member. The apparatus includes an image pickup apparatus that picks up a vertically polarized light image and a horizontally polarized light image at the front surface of the transparent member from a side of a rear surface of the transparent member; and a signal processing unit that determines whether the liquid droplets are attached to the front surface of the transparent member based on a polarized-light image ratio composed of the vertically polarized light image and the horizontally polarized light image picked up by the image pickup apparatus.

    摘要翻译: 公开了一种用于检测附着在透明构件前表面上的液滴的液滴识别装置。 该装置包括从透明构件的后表面侧在透明构件的前表面拾取垂直偏振光图像和水平偏振光图像的图像拾取装置; 以及信号处理单元,其基于由垂直偏振光图像和由图像拾取装置拾取的水平偏振光图像组成的偏振光图像比,确定液滴是否附着到透明构件的前表面。