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公开(公告)号：US06885547B2
公开(公告)日：2005-04-26
申请号：US10813332
申请日：2004-03-30
CPC分类号： H01G9/02
摘要： A dielectric oxide film-having anode foil and a cathode foil put opposite to each other via a separator therebetween are coiled up to construct a capacitor device. In this, the separator is coated with an electroconductive polymer formed through chemical oxidation polymerization of a polymerizing monomer in a solution that contains at least a non-transition metal-based oxidizing agent and an organic acid compound. Even when the electrolytic capacitor with the capacitor device is driven in a high-humidity atmosphere and a large amount of water penetrates into it, the capacitor is free from a trouble of dedoping, and therefore keeps its high voltage-proofness and leak current stability. The electrolytic capacitor is resistant to heat and its ESR is low in a high-frequency region.
摘要翻译： 具有通过隔膜间隔开的彼此相对的具有阳极箔和阴极箔的电介质氧化膜卷起来构成电容器装置。 在此，分离器涂覆有通过聚合单体在至少含有非过渡金属基氧化剂和有机酸化合物的溶液中进行化学氧化聚合形成的导电聚合物。 即使当电容器装置的电解电容器在高湿度气氛中被驱动并且大量的水渗入其中时，电容器也没有脱掺杂的问题，因此保持其高的电压和漏电流的稳定性。 电解电容器耐高温，其高频区域的ESR低。
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公开(公告)号：US07379289B2
公开(公告)日：2008-05-27
申请号：US10549119
申请日：2004-03-29
IPC分类号： H01G9/00
CPC分类号： H01G9/02 , H01G9/145 , H01G9/151 , Y10T29/41 , Y10T29/417
摘要： The present invention provides a highly conductive separator of which surface is coated with conductive polymer molecules, and provides an electrolytic capacitor having a low ESR characteristic using the separator. The conductive separator is formed by sticking the conductive polymer molecules to an insulating separator substrate by chemical oxidative polymerization, and the stuck amount of the conductive polymer molecules per basis weight of the separator substrate is set in the range of 3 to 30 g/m2. Conductive polymer molecules that are hardly de-doped can be formed in the electrolyte for driving by chemical oxidative polymerization, so that an electrolytic capacitor having high capacitance and low ESR can be obtained.
摘要翻译： 本发明提供了一种高导电性隔板，其表面涂覆有导电聚合物分子，并且使用隔膜提供具有低ESR特性的电解电容器。 通过化学氧化聚合将导电性聚合物分子粘合到绝缘隔板基板上形成导电性隔板，将隔膜基板的每单位面积重量的导电性聚合物分子的粘合量设定在3〜30g / SUP> 2 。 可以在用于通过化学氧化聚合驱动的电解质中形成几乎不被去掺杂的导电聚合物分子，从而可以获得具有高电容和低ESR的电解电容器。
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3.发明申请公开(公告)号：US20080316679A1
公开(公告)日：2008-12-25
申请号：US11662065
申请日：2005-09-06
申请人： Yukiyasu Sugihara , Keiko Hamada , Hiroyuki Matsuura , Shigetaka Furusawa , Hiroki Kusayanagi , Shinya Taguchi
发明人： Yukiyasu Sugihara , Keiko Hamada , Hiroyuki Matsuura , Shigetaka Furusawa , Hiroki Kusayanagi , Shinya Taguchi
IPC分类号： H01G9/004
摘要： It is provided the electrolytic solution for use in the electrolytic capacitor including a capacitor element and a casing containing said capacitor element, said capacitor element including a pair of electrodes, and a conductive separator (E) which is formed with a conductive polymer layer (F) containing a dopant agent (H) on its surface and is interposed between said pair of electrodes, said conductive separator (E) and said pair of electrodes being rolled up in an overlapped state with each other, and spaces between said pair of electrodes being impregnated with the electrolytic solution for electrolytic capacitor, wherein an acid component (D) and a base component (C) as electrolytic components to be contained in said electrolytic solution are at such a molar ratio that the acid component (D) is excessive. By use of said electrolytic solution for electrolytic capacitor, the increase in the ESR with the elapse of time in an electrolytic capacitor is suppressed.
摘要翻译： 提供了一种用于电解电容器的电解液，包括电容器元件和包含所述电容器元件的壳体，所述电容器元件包括一对电极，以及形成有导电聚合物层（F ），并且介于所述一对电极之间，所述导电性隔离物（E）和所述一对电极以重叠的状态卷起，所述一对电极之间的间隔为 浸渍在电解电容器用电解液中，其中作为所述电解液中含有的电解质成分的酸成分（D）和碱成分（C）的摩尔比为酸成分（D）过量。 通过使用上述电解电解电解液，电解电容器中ESR随时间的增加被抑制。
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4.发明授权Electrolytic solution for electrolytic capacitor, and electrolytic capacitor using the same 有权电解液用于电解电容器，电解电容器使用该电解电容器公开(公告)号：US07859828B2
公开(公告)日：2010-12-28
申请号：US11662065
申请日：2005-09-06
申请人： Yukiyasu Sugihara , Keiko Hamada , Hiroyuki Matsuura , Shigetaka Furusawa , Hiroki Kusayanagi , Shinya Taguchi
发明人： Yukiyasu Sugihara , Keiko Hamada , Hiroyuki Matsuura , Shigetaka Furusawa , Hiroki Kusayanagi , Shinya Taguchi
摘要： An electrolytic solution for use in an electrolytic capacitor including a capacitor element and a casing containing the capacitor element, the capacitor element including a pair of electrodes, and a conductive separator (E) which is formed with a conductive polymer layer (F) containing a dopant agent (H) on its surface and is interposed between the pair of electrodes, the conductive separator (E) and the pair of electrodes being rolled up in an overlapped state with each other, and spaces between the pair of electrodes being impregnated with the electrolytic solution, wherein an acid component (D) and a base component (C) as electrolytic components to be contained in the electrolytic solution are at such a molar ratio that the acid component (D) is excessive. By use of the electrolytic solution, increase in the ESR with the elapse of time in an electrolytic capacitor is suppressed.
摘要翻译： 一种用于电解电容器的电解液，包括电容器元件和容纳电容器元件的壳体，电容器元件包括一对电极，以及形成有导电性聚合物层（F）的导电性隔离物（E） 掺杂剂（H），并且被插入在一对电极之间，导电性隔离物（E）和一对电极以重叠的状态卷起，并且一对电极之间的间隔浸渍有 电解液，其中作为所述电解液中含有的电解质成分的酸成分（D）和碱成分（C）的摩尔比为酸成分（D）过量。 通过使用电解液，可以抑制电解电容器中随时间的增加而增加。
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5.发明授权Conductive composition precursor, conductive composition, solid electrolytic capacitor, and their manufacturing method 有权导电组合物前体，导电组合物，固体电解电容器及其制造方法公开(公告)号：US06602741B1
公开(公告)日：2003-08-05
申请号：US09660447
申请日：2000-09-12
申请人： Yasuo Kudoh , Kenji Akami , Hiroki Kusayanagi , Yasue Matsuya
发明人： Yasuo Kudoh , Kenji Akami , Hiroki Kusayanagi , Yasue Matsuya
IPC分类号： H01L2120
CPC分类号： H01G9/025 , H01B1/127 , H01B1/128 , H01G9/028 , H01G11/48 , H01G11/54 , H01G11/56 , Y02E60/13 , Y10T29/417
摘要： Method of manufacturing a conductive composition precursor prepared by dispersing or dissolving at least one additive having high dielectric layer repairing ability in conductive polymer solution, the conductive composition made by removing a medium or solvent from this composition precursor. The additive is at least one of “phosphoric acid or phosphoric acid ester compounds”, “phenol or phenol derivatives”, “nitrobenzene derivatives”, “alkyl naphthalene sulfonic acid anion”, “fluorocarbon surface active agent” and “fluorocarbon surface active agent and binder.”
摘要翻译： 通过将具有高介电层修复能力的至少一种添加剂分散或溶解在导电聚合物溶液中而制备导电组合物前体的方法，该导电组合物是通过从该组合物前体中除去介质或溶剂而制成的。 添加剂是“磷酸或磷酸酯化合物”，“苯酚或苯酚衍生物”，“硝基苯衍生物”，“烷基萘磺酸阴离子”，“碳氟表面活性剂”和“氟碳表面活性剂” 粘合剂“。
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6.发明授权Conductive composition precursor, conductive composition, solid electrolytic capacitor, and their manufacturing method 有权导电组合物前体，导电组合物，固体电解电容器及其制造方法公开(公告)号：US06793690B2
公开(公告)日：2004-09-21
申请号：US10337369
申请日：2003-01-07
申请人： Yasuo Kudoh , Kenji Akami , Hiroki Kusayanagi , Yasue Matsuya
发明人： Yasuo Kudoh , Kenji Akami , Hiroki Kusayanagi , Yasue Matsuya
IPC分类号： H01G900
CPC分类号： H01G9/025 , H01B1/127 , H01B1/128 , H01G9/028 , H01G11/48 , H01G11/54 , H01G11/56 , Y02E60/13 , Y10T29/417
摘要： Method of manufacturing a conductive composition precursor prepared by dispersing or dissolving at least one additive having high dielectric layer repairing ability in conductive polymer solution, the conductive composition made by removing a medium or solvent from this composition precursor. The additive is at least one of “phosphoric acid or phosphoric acid ester compounds”, “phenol or phenol derivatives”, “nitrobenzene derivatives”, “alkyl or naphthalene sulfonic acid anion”, “fluorocarbon surface active agent” and “fluorocarbon surface active agent and binder.”
摘要翻译： 通过将具有高介电层修复能力的至少一种添加剂分散或溶解在导电聚合物溶液中而制备导电组合物前体的方法，该导电组合物是通过从该组合物前体中除去介质或溶剂而制成的。 添加剂是“磷酸或磷酸酯化合物”，“苯酚或苯酚衍生物”，“硝基苯衍生物”，“烷基或萘磺酸阴离子”，“碳氟表面活性剂”和“氟碳表面活性剂” 和粘合剂“。
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公开(公告)号：US06375688B1
公开(公告)日：2002-04-23
申请号：US09390708
申请日：1999-09-07
申请人： Kenji Akami , Yasuo Kudo , Yasue Matsuya , Hiroki Kusayanagi
发明人： Kenji Akami , Yasuo Kudo , Yasue Matsuya , Hiroki Kusayanagi
IPC分类号： H01G900
CPC分类号： H01G9/0036 , H01G11/48 , H01G11/52 , H01G11/56 , Y02E60/13 , Y10T29/417
摘要： The invention includes the steps of preparing a mixed solution containing a polymerizable monomer, an oxidant, and a solvent; immersing a capacitor element in the mixed solution; and heating the capacitor element immediately over the boiling point of the solvent, after taking out the capacitor element from the mixed solution, in order to evaporate the solvent and form a conductive polymer layer on the capacitor element; the heating is carried out at a rate capable of generating a force able to tear open the conductive polymer. This method provides a capacitor having a high capacitance attainment ratio, an excellent dissipation factor, and a superior impedance characteristic.
摘要翻译： 本发明包括制备含有可聚合单体，氧化剂和溶剂的混合溶液的步骤; 将电容器元件浸入混合溶液中; 在从混合溶液中取出电容器元件之后，将电容器元件立即加热到溶剂的沸点之上，以蒸发溶剂并在电容器元件上形成导电聚合物层; 以能够产生能够撕开导电聚合物的力的速率进行加热。 该方法提供具有高电容获得率，优异的耗散因数和优异的阻抗特性的电容器。
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8.发明授权Conductive composition precursor, conductive composition, solid electrolytic capacitor, and their manufacturing method 有权导电组合物前体，导电组合物，固体电解电容器及其制造方法公开(公告)号：US06853540B2
公开(公告)日：2005-02-08
申请号：US10815803
申请日：2004-04-02
申请人： Yasuo Kudoh , Kenji Akami , Hiroki Kusayanagi , Yasue Matsuya
发明人： Yasuo Kudoh , Kenji Akami , Hiroki Kusayanagi , Yasue Matsuya
CPC分类号： H01G9/025 , H01B1/127 , H01B1/128 , H01G9/028 , H01G11/48 , H01G11/54 , H01G11/56 , Y02E60/13 , Y10T29/417
摘要： A solid electrolytic capacitor including a valve metal positive electrode, an anodized layer formed on a surface of the positive electrode, a conductive polymer-containing negative electrode conductive layer, and a coupling agent layer and a surface active agent layer placed between the anodized layer and the negative electrode conductive layer.
摘要翻译： 一种固体电解电容器，其包括阀金属正电极，阳极氧化层，形成在正极表面上，含导电聚合物的负电极导电层，耦合剂层和表面活性剂层，放置在阳极氧化层和 负极导电层。
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9.发明授权Photosensitive material for electrophotography and method for making the photosensitive material 失效用于电子照相的感光材料和用于制造感光材料的方法
公开(公告)号：US5389477A
公开(公告)日：1995-02-14
申请号：US942888
申请日：1992-09-10
CPC分类号： G03G5/0582 , G03G5/0514 , G03G5/0517 , G03G5/0567 , G03G5/0575 , G03G5/0696
摘要： A photosensitive material for electrophotography comprises a conductive support and a photosensitive layer formed on the conductive support, the photosensitive layer being made of X-type metal-free phthalocyanine, a resin binder, and an essential additive effective for improving electrophotographic or photosensitive characteristics or durability in repeated use wherein the X-type metal-free phthalocyanine is dispersed in the resin binder partly in a molecular state and partly in a particulate state. The essential additive includes electrolytically polymerized products, certain kinds of dyes, silane or polysilane compounds, hole and electron transport substances, titanyl or vanadyl phthalocyanine, electron acceptors, perylene compounds, amine derivatives, amino compounds, zinc oxide or the like.
摘要翻译： 用于电子照相的感光材料包括导电支撑体和形成在导电支撑体上的感光层，感光层由X型无金属酞菁制成，树脂粘合剂和有助于改善电子照相或感光特性或耐久性的必需添加剂 其中X型无金属酞菁分散在树脂粘合剂中，部分以分子状态部分处于颗粒状态。 必需添加剂包括电解聚合产物，某些种类的染料，硅烷或聚硅烷化合物，空穴和电子传输物质，氧钛或氧钒基酞菁，电子受体，苝化合物，胺衍生物，氨基化合物，氧化锌等。
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