METHOD FOR PRODUCING HEXAFLUOROACETONE OR HYDRATE THEREOF
    1.
    发明申请
    METHOD FOR PRODUCING HEXAFLUOROACETONE OR HYDRATE THEREOF 有权
    生产十六烷酮或其水合物的方法

    公开(公告)号:US20140121416A1

    公开(公告)日:2014-05-01

    申请号:US14124085

    申请日:2012-05-10

    IPC分类号: C07C45/59

    摘要: Hexafluoroacetone or a hydrate thereof is produced with a high yield by subjecting a 1-fluoro-4,4-bis(trifluoromethyl)-2,3,5-trioxolanyl ether compound represented by the general formula: wherein R is an alkyl group having 1 to 8 carbon atoms, an aryl group, or a benzyl group, which has been obtained by ozone oxidation of a heptafluoroisobutenyl ether compound, to a reduction reaction in the presence of a reducing agent selected from dialkyl sulfide containing an alkyl group having 3 or 4 carbon atoms, diaryl sulfide, diaryl disulfide, and diaralkyl sulfide.

    摘要翻译: 通过使通式(1)表示的1-氟-4,4-双(三氟甲基)-2,3,5-三氧杂环戊烷基醚化合物,其中R为具有1个 至8个碳原子,通过七氟异丁烯基醚化合物的臭氧氧化获得的芳基或苄基在还原剂存在下还原反应,所述还原反应选自含有3或4个烷基的二烷基硫化物 碳原子,二芳基硫醚,二芳基二硫化物和二烷基硫化物。

    Method for producing hexafluoroacetone or hydrate thereof
    2.
    发明授权
    Method for producing hexafluoroacetone or hydrate thereof 有权
    六氟丙酮或其水合物的制备方法

    公开(公告)号:US08853462B2

    公开(公告)日:2014-10-07

    申请号:US14124085

    申请日:2012-05-10

    IPC分类号: C07C45/59 C07C45/40 C07C29/00

    摘要: Hexafluoroacetone or a hydrate thereof is produced with a high yield by subjecting a 1-fluoro-4,4-bis(trifluoromethyl)-2,3,5-trioxolanyl ether compound represented by the general formula: wherein R is an alkyl group having 1 to 8 carbon atoms, an aryl group, or a benzyl group, which has been obtained by ozone oxidation of a heptafluoroisobutenyl ether compound, to a reduction reaction in the presence of a reducing agent selected from dialkyl sulfide containing an alkyl group having 3 or 4 carbon atoms, diaryl sulfide, diaryl disulfide, and diaralkyl sulfide.

    摘要翻译: 通过使通式(1)表示的1-氟-4,4-双(三氟甲基)-2,3,5-三氧杂环戊烷基醚化合物,其中R为具有1个 至8个碳原子,通过七氟异丁烯基醚化合物的臭氧氧化获得的芳基或苄基在还原剂存在下还原反应,所述还原反应选自含有3或4个烷基的二烷基硫化物 碳原子,二芳基硫醚,二芳基二硫化物和二烷基硫化物。

    Developer replenishing device and developer container for use therewith
    4.
    发明授权
    Developer replenishing device and developer container for use therewith 失效
    显影剂补充装置和显影剂容器用于此

    公开(公告)号:US5627631A

    公开(公告)日:1997-05-06

    申请号:US587966

    申请日:1996-01-17

    IPC分类号: G03G15/08

    摘要: A developer replenishing device for replenishing a developing device with a developer, and a developer container for use therewith. The developer container, or toner bottle, has a mouth portion at one end thereof which is smaller in diameter than a hollow cylindrical main body. At the end of the bottle provided with the mouth, a shoulder has the inner periphery thereof partly raised to the edge of the mouth portion to form a raised portion for scooping up a toner. In addition, a part of the inner periphery of the circumferential wall of the bottle which is contiguous with the raised portion is also raised toward the axis of the bottle about which the bottle is rotatable, thereby forming another raised portion. When the bottle is mounted to a bottle holder, which is included in the replenishing device, substantially horizontally with the mouth portion oriented sideways, the bottle is rotated to raise the toner from the bottom of the main body to the mouth portion. As a result, the toner is discharged to the outside via the mouth portion smoothly.

    摘要翻译: 用于用显影剂补充显影装置的显影剂补充装置和与其一起使用的显影剂容器。 显影剂容器或调色剂瓶在其一端具有直径小于中空圆柱形主体的口部。 在设置有口部的瓶子的端部,肩部的内周部分地部分地升高到嘴部的边缘,以形成用于舀取调色剂的凸起部分。 此外,与凸起部分邻接的瓶的圆周壁的内周的一部分也朝向瓶可旋转的瓶的轴线升高,从而形成另一个凸起部分。 当瓶子被安装到包括在补充装置中的瓶保持器时,基本上水平地使口部侧向取向,瓶子被旋转以将调色剂从主体的底部升高到嘴部。 结果,调色剂通过口部平滑地排出到外部。

    Process for producing 2,2,3,3-tetrafluorooxetane
    6.
    发明申请
    Process for producing 2,2,3,3-tetrafluorooxetane 失效
    制备2,2,3,3-四氟氧杂环丁烷的方法

    公开(公告)号:US20070191617A1

    公开(公告)日:2007-08-16

    申请号:US10589418

    申请日:2005-02-10

    IPC分类号: C07D305/04

    CPC分类号: C07D305/08

    摘要: In the production of 2,2,3,3-tetrafluorooxetane by reaction of tetrafluoroethylene with a compound of formaldehyde generation source in anhydrous hydrogen fluoride, the reaction is carried out in the presence of polyfluoroalkylcarboxylic acid or polyfluoroalkyl ester thereof, represented by the following general formula RfCOORf′ (where Rf is a polyfluoroalkyl group having 1-5 carbon atoms, and Rf′ is a hydrogen atom or a polyfluoroalkyl group having 1-5 carbon atoms), preferably CF3COOH, CF3COOCH2CF2CF3, or CF3COOCH2CF3, whereby a high reaction yield can be attained.

    摘要翻译: 在通过四氟乙烯与无水氟化氢中的甲醛生成源的化合物的反应制备2,2,3,3-四氟氧杂环丁烷的情况下,反应在多氟烷基羧酸或其多氟烷基酯的存在下进行,由以下通式 式RfCOORf'(其中Rf是具有1-5个碳原子的多氟烷基,Rf'是氢原子或具有1-5个碳原子的多氟烷基),优选CF 3 COOH,CF 3, CO 2 3 CO 2 CH 2 CO 2 CH 3或CO 3 CO 2 CH 2, CF 3 N 3,由此可以获得高的反应产率。

    Process for producing polyfluoroalkyl ester of unsaturated carboxylic acid
    7.
    发明申请
    Process for producing polyfluoroalkyl ester of unsaturated carboxylic acid 有权
    制备不饱和羧酸多氟烷基酯的方法

    公开(公告)号:US20060025625A1

    公开(公告)日:2006-02-02

    申请号:US11191398

    申请日:2005-07-28

    IPC分类号: C07C69/52

    摘要: A polyfluoroalkyl ester of unsaturated carboxylic acid is produced in high yield in a more simple reactor and with much more reduction in the waste than the conventional process based on esterification reaction by subjecting a polyfluoroalkanol represented by the following general formula: Rf-R—OH , where Rf is a polyfluoroalkyl group having 1-6 carbon atoms and R is an alkylene group having 1-6 carbon atoms, and an unsaturated carboxylic acid to dehydration reaction in a fluorine-containing solvent in the presence of an acid catalyst and a polymerization inhibitor.

    摘要翻译: 不饱和羧酸的多氟烷基酯在更简单的反应器中以高产率生产,与通过使由以下通式表示的多氟烷醇进行酯化反应相比,废弃物的还原性大大降低: 公式描述=“在线公式”end =“lead”?> Rf-R-OH <?in-line-formula description =“In-line Formulas”end =“tail”?>,其中Rf是多氟烷基 具有1-6个碳原子,R是具有1-6个碳原子的亚烷基,在酸催化剂和聚合抑制剂的存在下,在含氟溶剂中进行不饱和羧酸脱水反应。

    Developer replenishing device and developer container for use therewith
    8.
    发明授权
    Developer replenishing device and developer container for use therewith 有权
    显影剂补充装置和显影剂容器用于此

    公开(公告)号:US06289195B1

    公开(公告)日:2001-09-11

    申请号:US09549510

    申请日:2000-04-14

    IPC分类号: G03G1508

    摘要: A developer replenishing device for replenishing a developing device with a developer, and a developer container for use therewith. The developer container, or toner bottle, has a mouth portion at one end thereof which is smaller in diameter than a hollow cylindrical main body. At the end of the bottle provided with the mouth portion, a shoulder has the inner periphery thereof partly raised to the edge of the mouth portion to form a raised portion for scooping up a toner. In addition, a part of the inner periphery of the circumferental wall of the bottle, which is contiguous with the raised portion, is also raised toward the axis of the bottle, about which the bottle is rotatable, thereby forming another raised portion. When the bottle is mounted on a bottle holder, which is included in the replienishing device, substantially horizontally with the mouth portion oriented sideways, the bottle is rotated to raise the toner from the bottom of the main body to the mouth portion. As a result, the toner is discharged to the outside via the mouth portion smoothly.

    摘要翻译: 用于用显影剂补充显影装置的显影剂补充装置和与其一起使用的显影剂容器。 显影剂容器或调色剂瓶在其一端具有直径小于中空圆柱形主体的口部。 在设置有口部的瓶的端部,肩部的内周部分地向嘴部的边缘升高,以形成用于舀起调色剂的凸起部分。 此外,与凸起部分相邻的瓶子的外周壁的内周的一部分也朝向瓶子的轴线升高,瓶子可旋转,从而形成另一个凸起部分。 当瓶子被安装在包括在复制装置中的瓶保持器上时,基本上水平地将口部侧向取向,使瓶子旋转以将调色剂从主体的底部升高到嘴部。 结果,调色剂通过口部平滑地排出到外部。