-
公开(公告)号:US10174141B2
公开(公告)日:2019-01-08
申请号:US15307209
申请日:2015-04-29
申请人: China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
发明人: Shibo Wang , Junling Zhou , Dongbing Liu , Lei Zhang , Xinping Lv , Bingquan Mao , Zhenjie Liu , Xin Zhou , Changli Zhang , Baoquan Xing
IPC分类号: C08F110/02
摘要: The present invention provides a preparation method of a catalyst component for olefin polymerization, comprising firstly dissolving an anhydrous magnesium halide into a mixed solvent which comprises an oxygen-containing organic titanium compound, an organic epoxy compound, a hydroxy-containing compound, and an inert solvent, and does not comprise a phosphate compound, so as to form a magnesium halide solution; then mixing the magnesium halide solution with a halogen-containing compound to precipitate a solid, so as to obtain the catalyst component, wherein the halogen-containing compound comprises at least one selected from a group consisting of halogen and titanium-containing compounds, halogenated organic hydrocarbon compounds, acyl halide compounds, halogen and phosphorus-containing compounds, halogen and boron-containing compounds, halogenated organic aluminum compounds, and halogen and silicon-containing compounds. The catalyst component prepared by the present invention has better particle morphology, and a good hydrogen response, and thus is favorable to use of the catalyst in a slurry or gas polymerization process device.