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公开(公告)号：US20230053988A1
公开(公告)日：2023-02-23
申请号：US17966465
申请日：2022-10-14
申请人： GALATA CHEMICALS LLC
发明人： Peter FRENKEL , Chris TURNBULL , Larry B. SIMMONS
摘要： A composition comprising: (1) 0.1 to 84.0 wt % of a polymeric resin selected from PVC homopolymers, PVC copolymers, CPVC, PLA, SAN, ASA, CPE, EVA, ABS, MBS, polycarbonate, conventional acrylic ester polymers or mixtures thereof; and (2) 16.0 to 99.9 wt % of a polyacrylate resin/material (PAM) composition comprising a polymer (A) phase and a polymer (B) phase present in a ratio of polymer (A) phase/polymer (B) phase of 50/50 to 90/10, polymer (A), having a glass transition temperature Tg below −40° C., comprising 95.0 to 99.5 wt % of a first polymeric component (A1) of one or more mono-ethylenically unsaturated monomers selected from the group consisting of alkyl acrylates having an alkyl group containing from 1 to 8 carbons, and 0.5 to 5.0 wt % of a second polymeric component (A2) of one or more polyethylenically unsaturated monomers, where the double bonds can be of the same or differing reactivity; and polymer (B), having a glass transition temperature Tg above 85° C., comprising a first polymeric component (B1) of one or more monoethylenically unsaturated monomers selected from the group consisting of alkyl methacrylates having an alkyl group containing from 1 to 4 carbons, and optionally, 1.0 to 10.0 wt % of other monomers, based on the total weight of the (B1) component, selected from alkyl acrylates, vinylbenzene or substituted vinylbenzenes or mixtures thereof, and optionally a second polymeric component (B2) comprising 0.3 to 2.5 wt % based on the total weight of polymer (B) of one or more polyethylenically unsaturated monomers where the unsaturated bonds can be of the same or differing reactivity.
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公开(公告)号：US09580574B2
公开(公告)日：2017-02-28
申请号：US14443973
申请日：2012-12-12
申请人： Galata Chemicals LLC
发明人： Peter Frenkel
IPC分类号： A01N53/00 , C08K5/098 , C07D303/16 , C08K5/1515
CPC分类号： C08K5/1515 , A01N53/00 , C07D303/16 , C08K5/098
摘要： Bio-based biocide compositions containing epoxidized 2-ethylhexyl soyate and a solvent such as epoxidized soybean oil are disclosed. When incorporated into polymers such as PVC, preserved polymer compositions result. The invention also provides methods for preserving polymers, including incorporating these compositions into PVC in accordance with these methods.
摘要翻译： 公开了含有环氧化的2-乙基己基大豆油脂和溶剂如环氧化大豆油的生物基杀生物剂组合物。 当结合到聚合物如PVC中时，产生保留的聚合物组合物。 本发明还提供了保存聚合物的方法，包括根据这些方法将这些组合物并入PVC中。
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公开(公告)号：US09745450B2
公开(公告)日：2017-08-29
申请号：US15266379
申请日：2016-09-15
申请人： Galata Chemicals LLC
发明人： Peter Frenkel , Johannes Kaufhold
CPC分类号： C08K5/58 , C07F7/22 , C08K2201/014 , C08L27/06
摘要： A heat stabilizer composition comprising a) at least one mono-octyltin compound (n-Oc)Sn(T)3 having a purity greater than 85 wt %; and b) at least one di-methyltin compound (Me)2Sn(T)2 having a purity greater than 85 wt %.
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公开(公告)号：US09587088B2
公开(公告)日：2017-03-07
申请号：US14910627
申请日：2014-07-15
申请人： Galata Chemicals LLC
摘要： A stabilizer composition having low volatility and high efficiency comprising: (i.) 25.000% to 99.997% by weight of at least one dimethyltin compound of formula (CH3)2Sn(S(CH2)mCOOR1)2 wherein R1 is a linear, branched or cyclic C10-C20 alkyl group and m is 1 or 2, optionally containing unsaturations in the form of double or triple bonds; (ii.) 0.001% to 50.000% by weight of at least one mono-methyltin compound of formula CH3Sn(S(CH2)nCOOR2)3 wherein R2 is a linear, branched or cyclic C10-C20 alkyl group and n is 1 or 2, optionally containing unsaturations in the form of double or triple bonds; (iii.) 0.001% to 10.000% by weight of at least one tri-methyltin compound of formula (CH3)3Sn(S(CH2)pCOOR3) wherein R3 is a linear, branched or cyclic C10-C20 alkyl group and p is 1 or 2, optionally containing unsaturations in the form of double or triple bonds; and (iv.) 0.001% to 15.000% by weight of at least one thioester of formula HS(CH2)qCOOR4 wherein R4 is a linear, branched or cyclic C10-C20 alkyl group and q is 1 or 2, optionally containing unsaturations in the form of double or triple bonds.
摘要翻译： 具有低挥发性和高效率的稳定剂组合物，其包含：（i）25.000％至99.997％重量的至少一种式（CH3）2Sn（S（CH2）mCOOR1）2的二甲基锡化合物，其中R 1是直链，支链或 环状C 10 -C 20烷基，m为1或2，任选地含有双键或三键形式的不饱和键; （ii）0.001重量％至50.000重量％的至少一种式CH 3 Sn（S（CH 2）n COOR 2）的单甲基锡化合物，其中R 2是直链，支链或环状的C 10 -C 20烷基，n是1或2 ，任选地含有双键或三键形式的不饱和键; （iii）0.001重量％至10.000重量％的至少一种式（CH 3）3 N（S（CH 2）p COOR 3）的三甲基锡化合物，其中R 3是直链，支链或环状的C 10 -C 20烷基，p是1 或2，任选地含有双键或三键形式的不饱和键; 至少一种式HS（CH 2）q COOR 4的硫酯，其中R 4是直链，支链或环状的C 10 -C 20烷基，q是1或2，（iv）0.001％至15.000％ 双重或三重键的形式。
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公开(公告)号：US09346939B2
公开(公告)日：2016-05-24
申请号：US14463372
申请日：2014-08-19
申请人： Galata Chemicals LLC
IPC分类号： C08K5/1515 , C08K5/098 , C09K15/00 , C09K15/34
CPC分类号： C08K5/1515 , C08K5/098 , C09K15/34
摘要： A flexible compound comprising PVC or its co-polymers; greater than 10 to 200 parts by weight of at least one bio-based primary plasticizer comprising epoxidized fatty acid esters, wherein the fatty acids are derived from natural oils and animal fats, based on 100 parts by weight of PVC or its co-polymers; and 0.001 to 10 parts by weight of a mixed metal stabilizer comprising a zinc compound and at least one metal compound where the metal is selected from Li, Na, K, Mg, Ca, Sr, Ba, Cd, Al, La, Ce or rare earth metals, based on 100 parts by weight of PVC or its co-polymers, wherein an atomic ratio of metal/Zn for the mixed metal stabilizer is less than 1.0.
摘要翻译： 包含PVC或其共聚物的柔性化合物; 基于100重量份的PVC或其共聚物，大于10至200重量份的至少一种基于生物的主要增塑剂包含环氧化脂肪酸酯，其中所述脂肪酸衍生自天然油和动物脂肪; 和0.001至10重量份的包含锌化合物和至少一种金属化合物的混合金属稳定剂，其中金属选自Li，Na，K，Mg，Ca，Sr，Ba，Cd，Al，La，Ce或 稀土金属，基于100重量份的PVC或其共聚物，其中用于混合金属稳定剂的金属/ Zn的原子比小于1.0。
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公开(公告)号：US20100317874A1
公开(公告)日：2010-12-16
申请号：US12859427
申请日：2010-08-19
申请人： Michael G. Denoux , Ritchie Tregre , Garrett Mineo
发明人： Michael G. Denoux , Ritchie Tregre , Garrett Mineo
IPC分类号： C07D303/04
摘要： Disclosed is an oil composition wherein the oil contains measurable amounts of peroxide resulting from peroxidation, and also includes an effective amount of a peroxide-reducing phosphorous compound, preferably an alkyl/aryl substituted phosphite compound or phosphinic acid (H3PO2) and its derivatives.
摘要翻译： 公开了一种油组合物，其中油含有可测量的由过氧化产生的过氧化物，并且还包括有效量的过氧化物还原性磷化合物，优选烷基/芳基取代的亚磷酸酯化合物或次膦酸（H 3 PO 2）及其衍生物。
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公开(公告)号：US20210108064A1
公开(公告)日：2021-04-15
申请号：US16982085
申请日：2019-03-19
申请人： GALATA CHEMICALS LLC
发明人： Peter FRENKEL , Chris TURNBULL , Larry B. SIMMONS
摘要： A composition comprising: (1) 0.1 to 84.0 wt % of a polymeric resin selected from PVC homopolymers, PVC copolymers, CPVC, PLA, SAN, ASA, CPE, EVA, ABS, MBS, polycarbonate, conventional acrylic ester polymers or mixtures thereof; and (2) 16.0 to 99.9 wt % of a polyacrylate resin/material (PAM) composition comprising a polymer (A) phase and a polymer (B) phase present in a ratio of polymer (A) phase/polymer (B) phase of 50/50 to 90/10, polymer (A), having a glass transition temperature Tg below −40° C., comprising 95.0 to 99.5 wt % of a first polymeric component (A1) of one or more mono-ethylenically unsaturated monomers selected from the group consisting of alkyl acrylates having an alkyl group containing from 1 to 8 carbons, and 0.5 to 5.0 wt % of a second polymeric component (A2) of one or more polyethylenically unsaturated monomers, where the double bonds can be of the same or differing reactivity; and polymer (B), having a glass transition temperature Tg above 85° C., comprising a first polymeric component (B1) of one or more monoethylenically unsaturated monomers selected from the group consisting of alkyl methacrylates having an alkyl group containing from 1 to 4 carbons, and optionally, 1.0 to 10.0 wt % of other monomers, based on the total weight of the (B1) component, selected from alkyl acrylates, vinylbenzene or substituted vinylbenzenes or mixtures thereof, and optionally a second polymeric component (B2) comprising 0.3 to 2.5 wt % based on the total weight of polymer (B) of one or more polyethylenically unsaturated monomers where the unsaturated bonds can be of the same or differing reactivity.
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公开(公告)号：US08088937B2
公开(公告)日：2012-01-03
申请号：US12832701
申请日：2010-07-08
申请人： Edward Krainer , Peter Frenkel
发明人： Edward Krainer , Peter Frenkel
CPC分类号： C07F7/226
摘要： Disclosed herein are compounds of the formula: (R)x—Sn—(R′)4-x wherein: R is alkyl; R′ is a moiety selected from the group consisting of: w is 0 or 1; x is 1 or 2; y is 1, 2, 3, or 4; and Z is a linear, branched, cyclic, or aromatic hydrocarbon. These compounds are excellent stabilizers for halogen-containing resins, such as PVC.
摘要翻译： 本文公开的是下式的化合物：（R）x-Sn-（R'）4-x其中：R是烷基; R'是选自以下的部分：w为0或1; x为1或2; y为1,2,3或4; 并且Z是直链，支链，环状或芳族烃。 这些化合物是含卤树脂如PVC的优异的稳定剂。
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公开(公告)号：US07955525B2
公开(公告)日：2011-06-07
申请号：US12859427
申请日：2010-08-19
申请人： Michael G. Denoux , Ritchie Tregre , Garrett Mineo
发明人： Michael G. Denoux , Ritchie Tregre , Garrett Mineo
IPC分类号： C09K15/32 , C07F9/02 , C07D301/36 , C07D303/02
摘要： Disclosed is an oil composition wherein the oil contains measurable amounts of peroxide resulting from peroxidation, and also includes an effective amount of a peroxide-reducing phosphorous compound, preferably an alkyl/aryl substituted phosphite compound or phosphinic acid (H3PO2) and its derivatives.
摘要翻译： 公开了一种油组合物，其中油含有可测量的由过氧化产生的过氧化物，并且还包括有效量的过氧化物还原性磷化合物，优选烷基/芳基取代的亚磷酸酯化合物或次膦酸（H 3 PO 2）及其衍生物。
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公开(公告)号：US20100298589A1
公开(公告)日：2010-11-25
申请号：US12832701
申请日：2010-07-08
申请人： Edward Krainer , Peter Frenkel
发明人： Edward Krainer , Peter Frenkel
IPC分类号： C07F7/22
CPC分类号： C07F7/226
摘要： Disclosed herein are compounds of the formula: (R)x—Sn—(R′)4-x wherein: R is alkyl; R′ is a moiety selected from the group consisting of: w is 0 or 1; x is 1 or 2; y is 1, 2, 3, or 4; and Z is a linear, branched, cyclic, or aromatic hydrocarbon. These compounds are excellent stabilizers for halogen-containing resins, such as PVC.
摘要翻译： 本文公开的是下式的化合物：（R）x-Sn-（R'）4-x其中：R是烷基; R'是选自以下的部分：w为0或1; x为1或2; y为1,2,3或4; 并且Z是直链，支链，环状或芳族烃。 这些化合物是含卤树脂如PVC的优异的稳定剂。
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