公开(公告)号：US11773237B2

公开(公告)日：2023-10-03

申请号：US16954576

申请日：2018-12-14

申请人： MATSUMOTO YUSHI-SEIYAKU CO., LTD.

发明人： Takumi Ebe ,  Katsushi Miki

IPC分类号： C08K9/10 ,  B29C44/50 ,  B29C44/02 ,  C08J3/22 ,  C08J9/32 ,  C08K5/01 ,  C08L23/00 ,  B29K21/00 ,  B29K105/16 ,  B29L7/00

CPC分类号： C08K9/10 ,  B29C44/02 ,  B29C44/505 ,  C08J3/22 ,  C08J9/32 ,  C08K5/01 ,  C08L23/00 ,  B29K2021/003 ,  B29K2105/165 ,  B29L2007/002 ,  C08J2339/06

摘要： A resin composition containing heat-expandable microspheres including a thermoplastic resin shell and a thermally vaporizable blowing agent encapsulated therein and at least one base resin selected from rubbers, olefin resins and thermoplastic elastomers. The thermoplastic resin is a polymer of a polymerizable component containing N-substituted maleimide and a nitrile monomer containing methacrylonitrile. Also disclosed are molded articles manufactured by molding the resin composition.

公开(公告)号：US20210122888A1

公开(公告)日：2021-04-29

申请号：US16645307

申请日：2018-08-07

申请人： MATSUMOTO YUSHI-SEIYAKU CO., LTD.

发明人： Atsushi YABUMOTO ,  Kentaro SUZUKI ,  Takeyoshi NAKAYAMA

IPC分类号： C08J5/06 ,  C08J5/04 ,  D06M15/59

摘要： A sizing agent for matrix-resin-reinforcement fiber, a synthetic fiber strand sized therewith, and a fiber-reinforced composite material reinforced by the sized fiber strand. The sizing agent for reinforcement fiber contains a polyamide (A), a carbodiimide group-containing compound (B) and water (C), wherein the polyamide (A) has a melt viscosity ranging from 100 to 15,000 mP·s at 150° C. and the compound (B) has at least two carbodiimide groups per molecule. The polyamide (A) is preferably a water-soluble polyamide.

公开(公告)号：US20180056267A1

公开(公告)日：2018-03-01

申请号：US15554527

申请日：2016-02-19

申请人： MATSUMOTO YUSHI-SEIYAKU CO., LTD.

发明人： Satoshi KAWANAMI ,  Yoshitsugu SASAKI

IPC分类号： B01J13/18 ,  C08F2/44 ,  C09K3/00 ,  C08F2/18

CPC分类号： B01J13/18 ,  B01J13/185 ,  C08F2/18 ,  C08F2/20 ,  C08F2/44 ,  C08F214/08 ,  C08F220/14 ,  C08J9/0061 ,  C08J9/32 ,  C08J2203/22 ,  C08J2423/08 ,  C09K3/00 ,  C08F220/44 ,  C08F2222/1013

摘要： Heat-expandable microspheres having an expansion temperature which can be decreased by a simple means without changing the polymerizable monomer and its ratio and/or changing the blowing agent and its ratio, and applications thereof. The heat-expandable microspheres are composed of a thermoplastic resin shell and a core material encapsulated therein. The core material contains a thermally-vaporizable blowing agent which imparts a swelling degree of less than 5% as defined by the following formula (I) and a component (A) which imparts a swelling degree of 5 to 30% as defined by the following formula (I), wherein an amount of the component (A) ranges from 0.0001 to 30 parts by weight to 100 parts by weight of the blowing agent: Swelling degree (%)={(M2−M1)/M1}×100  (I) wherein M2 and M1 are as defined herein.

公开(公告)号：US09200384B2

公开(公告)日：2015-12-01

申请号：US14375346

申请日：2013-02-14

申请人： MATSUMOTO YUSHI-SEIYAKU CO., LTD.

发明人： Yoshio Hashimoto ,  Takeyoshi Nakayama ,  Jun Takaya ,  Mikio Nakagawa

IPC分类号： D01F9/24 ,  C08K5/5419 ,  C08K5/521 ,  D01F6/38 ,  D06M13/292 ,  D06M15/643 ,  D01F9/22

CPC分类号： D01F9/24 ,  C08K5/521 ,  C08K5/5419 ,  D01F6/38 ,  D01F9/22 ,  D06M13/292 ,  D06M15/643

摘要： An acrylic-fiber finish for carbon fiber production is prepared into a stable emulsion and applied to a carbon-fiber precursor to prevent gumming up of finish components in precursor production and carbon fiber fusing in baking process. The acrylic-fiber finish is used for carbon-fiber production and includes a modified silicone having a modifying group containing a nitrogen atom and an acidic phosphate ester represented by the following chemical formula (1). where R1 represents a C6-22 alkyl or alkenyl group, A represents a C2-4 alkylene group, and AO represents an oxyalkylene group, n represents a mole number of oxyalkylene group and is an integer ranging from 0 to 20, and each of a and b is an integer of 1 or 2 and meets the equation a+b=3.

摘要翻译： 将用于碳纤维生产的丙烯酸纤维整理剂制备成稳定的乳液并施加到碳纤维前体，以防止前体生产中的成品组分的上胶和烘烤过程中的碳纤维熔化。 丙烯酸纤维整理剂用于碳纤维生产，并且包括具有含氮原子的改性基团和由以下化学式（1）表示的酸性磷酸酯的改性硅氧烷。 其中R1表示C6-22烷基或烯基，A表示C2-4亚烷基，AO表示氧化烯基，n表示氧化烯基的摩尔数，为0〜20的整数， 并且b是1或2的整数，并满足等式a + b = 3。

公开(公告)号：US09126178B2

公开(公告)日：2015-09-08

申请号：US13321581

申请日：2010-05-21

申请人： Yu Kita ,  Katsushi Miki

发明人： Yu Kita ,  Katsushi Miki

IPC分类号： B32B15/02 ,  B05D1/02 ,  A61K9/14 ,  B01J13/20 ,  B01J13/18

CPC分类号： B01J13/20 ,  B01J13/185 ,  Y10T428/2989

摘要： Heat-expandable microspheres having high heat resistance and high solvent resistance, a production process thereof include a shell of a thermoplastic resin and a thermally vaporizable blowing agent being encapsulated therein. The thermoplastic resin includes a copolymer produced by polymerizing a polymerizable component containing a carboxyl-group-containing monomer. The surface of the heat-expandable microspheres is treated with an organic compound containing a metal of the Groups from 3 to 12 in the Periodic Table.

摘要翻译： 具有高耐热性和高耐溶剂性的热膨胀性微球，其制造方法包括热塑性树脂的壳体和可热汽化的发泡剂。 热塑性树脂包括通过聚合含有含羧基单体的可聚合组分制备的共聚物。 热可膨胀性微球体的表面用元素周期表中含有3〜12族金属的有机化合物进行处理。

公开(公告)号：US08329298B2

公开(公告)日：2012-12-11

申请号：US12067771

申请日：2006-10-04

申请人： Toshiaki Masuda ,  Kenichi Kitano ,  Katsushi Miki ,  Takeshi Inohara ,  Takayuki Aoki

发明人： Toshiaki Masuda ,  Kenichi Kitano ,  Katsushi Miki ,  Takeshi Inohara ,  Takayuki Aoki

IPC分类号： C08J9/16 ,  B32B15/02

CPC分类号： B01J13/14 ,  Y10T428/2982 ,  Y10T428/2984 ,  Y10T428/2985 ,  Y10T428/2987 ,  Y10T428/2998

摘要： A method that heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes, a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microsphres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.

摘要翻译： 热膨胀性微球的方法包括使用热塑性树脂的壳和封入其中的沸点不高于热塑性树脂的软化点的非氟发泡剂。 该方法包括：将含有可聚合组分的油性混合物，发泡剂和含有过氧化二碳酸酯的聚合引发剂在含水分散介质中分散以使包含在油性混合物中的可聚合组分聚合的步骤。 所得到的热膨胀微孔具有较不易于其理论值变薄的外壳，其外壳中含有最少量的树脂颗粒，并且具有优异的热膨胀性能。

公开(公告)号：US08206826B2

公开(公告)日：2012-06-26

申请号：US12594317

申请日：2008-05-14

申请人： Hiroki Naito ,  Satoshi Kawanami ,  Katsushi Miki ,  Ikuo Yosejima ,  Kenichi Kitano

发明人： Hiroki Naito ,  Satoshi Kawanami ,  Katsushi Miki ,  Ikuo Yosejima ,  Kenichi Kitano

IPC分类号： C08F2/44

CPC分类号： C08F2/44 ,  B01J13/14 ,  C08F2/20 ,  Y10T428/2982 ,  Y10T428/2985 ,  Y10T428/2987 ,  Y10T428/2989

摘要： A production method for heat-expandable microspheres, which have high expanding ratio and are thermally expanded into hollow particulates having excellent repeated-compression durability, and application thereof are provided. The method produces heat-expandable microspheres a shell of thermoplastic resin and a blowing agent being encapsulated therein and having a boiling point not higher than the softening point of the thermoplastic resin.

摘要翻译： 提供了具有高膨胀率并且热膨胀成具有优异的重复压缩耐久性的中空微粒的热膨胀性微球的制造方法及其应用。 该方法产生热膨胀性微球，将热塑性树脂的壳和发泡剂包封在其中，沸点不高于热塑性树脂的软化点。

公开(公告)号：US20120064347A1

公开(公告)日：2012-03-15

申请号：US13321581

申请日：2010-05-21

申请人： Yu Kita ,  Katsushi Miki

发明人： Yu Kita ,  Katsushi Miki

IPC分类号： B32B15/02 ,  B05D1/02 ,  B05D5/00 ,  B05D7/02

CPC分类号： B01J13/20 ,  B01J13/185 ,  Y10T428/2989

摘要： Heat-expandable microspheres having high heat resistance and high solvent resistance, a production process thereof include a shell of a thermoplastic resin and a thermally vaporizable blowing agent being encapsulated therein. The thermoplastic resin includes a copolymer produced by polymerizing a polymerizable component containing a carboxyl-group-containing monomer. The surface of the heat-expandable microspheres is treated with an organic compound containing a metal of the Groups from 3 to 12 in the Periodic Table.

摘要翻译： 具有高耐热性和高耐溶剂性的热膨胀性微球，其制造方法包括热塑性树脂的壳体和可热汽化的发泡剂。 热塑性树脂包括通过聚合含有含羧基单体的可聚合组分制备的共聚物。 热可膨胀性微球体的表面用元素周期表中含有3〜12族金属的有机化合物进行处理。

公开(公告)号：US08112980B2

公开(公告)日：2012-02-14

申请号：US12677253

申请日：2008-09-02

申请人： Shinichi Tatemoto ,  Tatsuo Harada ,  Kaori Kimoto

发明人： Shinichi Tatemoto ,  Tatsuo Harada ,  Kaori Kimoto

IPC分类号： D01H13/30

CPC分类号： D06M13/292 ,  D02G1/04 ,  D06M7/00 ,  D06M13/184 ,  D06M13/207 ,  D06M13/342 ,  D06M2200/40 ,  Y10T428/2933

摘要： A finish for synthetic filament yarn which decreases broken filaments and ends down in friction false-twist texturing includes 40 to 98 wt % of a polyether compound, and essentially comprises components (A) and (B); wherein the component (A) is at least one member selected from the group consisting of (A1) a C1-C10 fatty acid, (A2) a C1-C10 hydroxyfatty acid, (A3) a sarcosine derivative, and salts thereof, and the amount of the component (A) in the finish ranges from 0.05 to 5 wt %; and wherein the component (B) is an alkylphosphate salt and the amount of the component (B) in the finish ranges from 0.01 to 3 wt %.

摘要翻译： 合成长丝纱线的修整，其减少断裂的细丝并在摩擦假捻变形中终止，包括40至98重量％的聚醚化合物，并且基本上包含组分（A）和（B）; 其中组分（A）为选自（A1）C1-C10脂肪酸，（A2）C1-C10羟基脂肪酸，（A3）肌氨酸衍生物及其盐的至少一种，和 组分（A）的含量在0.05〜5重量％范围内; 并且其中组分（B）是烷基磷酸盐，并且组合物（B）的量在0.01至3重量％范围内。

公开(公告)号：US07857861B2

公开(公告)日：2010-12-28

申请号：US11672528

申请日：2007-02-08

申请人： Haruhiko Komeda ,  Setsuo Kita ,  Hidetoshi Kitaguchi ,  Kazuki Ito ,  Yoshiharu Fujimoto

发明人： Haruhiko Komeda ,  Setsuo Kita ,  Hidetoshi Kitaguchi ,  Kazuki Ito ,  Yoshiharu Fujimoto

IPC分类号： C11D3/00 ,  D06M15/423 ,  D06M13/127 ,  D01F9/22 ,  C08J7/12 ,  D06P1/673

CPC分类号： D06M13/332 ,  D06M13/217 ,  D06M13/292 ,  D06M13/342 ,  D06M13/46 ,  D06M13/467 ,  D06M15/647 ,  D06M2200/00

摘要： The hydrophilizing agent contains (a) a cationized compound of a (poly) amine, (b) an ester, (c) a dialkyl sulfosuccinate salt, (d) an alkylphosphate salt, (e) at least one glycine derivative selected from the group consisting of trialkyl glycine derivatives and (alkylamide alkyl) dialkyl glycine derivatives, and (f) a polyoxyalkylene-modified silicone; wherein the ratio of the component (a) ranges from 10 to 40 wt. %, the ratio of the component (b) ranges from 10 to 40 wt. %, the ratio of the component (c) ranges from 1 to 40 wt. %, the ratio of the component (d) ranges from 10 to 60 wt. %, the ratio of the component (e) ranges from 10 to 40 wt. %, and the ratio of the component (f) ranges from 1 to 20 wt. % of the hydrophilizing agent.

摘要翻译： 亲水剂包含（a）（多）胺阳离子化合物，（b）酯，（c）二烷基磺基琥珀酸盐，（d）烷基磷酸盐，（e）至少一种甘氨酸衍生物， 由三烷基甘氨酸衍生物和（烷基酰胺烷基）二烷基甘氨酸衍生物组成，和（f）聚氧化烯改性的硅氧烷; 其中组分（a）的比例为10至40wt。 ％，组分（b）的比例为10〜40重量％。 ％，成分（c）的比例为1〜40重量％。 ％，组分（d）的比例为10〜60重量％。 ％，组分（e）的比例为10〜40重量％。 ％，成分（f）的比例为1〜20重量％。 ％的亲水剂。