Synthesis of cyclic organic compounds and metallocenes

    公开(公告)号:US11377461B2

    公开(公告)日:2022-07-05

    申请号:US17156786

    申请日:2021-01-25

    IPC分类号: C07F17/00

    摘要: A method comprising synthesizing a cyclic organic compound via reaction of an unsubstituted or substituted cycloheptene with an unsubstituted or substituted acrylic acid in the presence of phosphoric and/or sulfonic acid reagent to make the cyclic organic compound. Also, a method of synthesizing a ligand for a transition metal, and a related substituted ligand-metal complex and catalyst, from the unsubstituted or substituted cycloheptene and unsubstituted or substituted acrylic acid. Also, the cyclic organic compound, ligand, and substituted ligand-metal complex and catalyst synthesized thereby. Also a method of polymerizing an olefin with the catalyst to give a polyolefin, and the polyolefin made thereby.

    BIMODAL POLYETHYLENE COPOLYMER COMPOSITION AND PIPE MADE THEREOF

    公开(公告)号:US20210380737A1

    公开(公告)日:2021-12-09

    申请号:US17276912

    申请日:2019-09-10

    IPC分类号: C08F210/16 C08F4/659 F16L9/12

    摘要: A bimodal ethylene-co-1-hexene copolymer composition consisting of a higher molecular weight component and a lower molecular weight component and, when in melted form at 190 degrees Celsius, is characterized by a melt property performance defined by a combination of melt index (5 kg), melt strength, and, optionally, shear thinning properties, and, when in solid form, is characterized by a slow crack growth property performance defined by a combination of strain hardening modulus and accelerated full-notch creep test performance. A pipe consisting of the bimodal ethylene-co-1-hexene copolymer composition. A method of synthesizing the bimodal ethylene-co-1-hexene copolymer composition. A method of making the pipe. A manufactured article, which is not a pipe, comprising the bimodal ethylene-co-1-hexene copolymer composition.

    UNIMODAL POLYETHYLENE COPOLYMER AND FILM THEREOF

    公开(公告)号:US20210261703A1

    公开(公告)日:2021-08-26

    申请号:US17261605

    申请日:2019-07-29

    IPC分类号: C08F210/16 C08J5/18

    摘要: A unimodal ethylene-co-1-hexene copolymer that, when in melted form at 190 degrees Celsius, is characterized by a unique melt property space defined by combination of melt elasticity and complex viscosity ratio (shear thinning) properties. A blown film consisting essentially of the unimodal ethylene-co-1-hexene copolymer. A method of synthesizing the unimodal ethylene-co-1-hexene copolymer. A method of making the blown film. A manufactured article comprising the unimodal ethylene-co-1-hexene copolymer.