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公开(公告)号:US09283495B2
公开(公告)日:2016-03-15
申请号:US13787296
申请日:2013-03-06
申请人: DIONEX CORPORATION
CPC分类号: B01D15/363 , B01D15/361 , B01D15/367 , G01N30/96 , G01N2030/965
摘要: An apparatus for capillary ion chromatography comprising a suppressor comprising flow-through ion exchange packing in a housing and capillary tubing formed of a permselective ion exchange membrane, and at least partially disposed in said ion exchange packing. Also, a recycle conduit for aqueous liquid from the detector to the packing. Further, the capillary tubing may have weakly acidic or weakly basic functional groups. Also, a method for using the apparatus.
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公开(公告)号:US20120228227A1
公开(公告)日:2012-09-13
申请号:US13479119
申请日:2012-05-23
IPC分类号: B01D15/20
CPC分类号: B01D15/363 , B01D15/361 , B01D15/367 , G01N30/96 , G01N2030/965
摘要: An apparatus for capillary ion chromatography comprising a suppressor comprising flow-through ion exchange packing in a housing and capillary tubing formed of a permselective ion exchange membrane, and at least partially disposed in said ion exchange packing. Also, a recycle conduit for aqueous liquid from the detector to the packing. Further, the capillary tubing may have weakly acidic or weakly basic functional groups. Also, a method for using the apparatus.
摘要翻译: 一种用于毛细管离子色谱的装置,包括抑制器,该抑制器包括在壳体中的流通离子交换填料和由选择性选择性离子交换膜形成的毛细管,并且至少部分地设置在所述离子交换填料中。 另外,从检测器到包装的水性液体循环管道。 此外,毛细管可具有弱酸性或弱碱性官能团。 另外,使用该装置的方法。
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公开(公告)号:US20120141328A1
公开(公告)日:2012-06-07
申请号:US13368663
申请日:2012-02-08
CPC分类号: G01N30/96 , B01D15/367 , B01D61/48 , Y10T436/25
摘要: A non-electrolytic method and apparatus for treating an aqueous sample stream including analyte ions and matrix ions of opposite charge, for pretreatment or suppression. The apparatus includes an ion exchange membrane capable of passing only ions of opposite charge to the analyte ions, a sample stream flow channel, a first aqueous stream ion receiving flow channel adjacent one side of the sample stream flow channel and separated therefrom by the first ion exchange membrane, and stationary flow-through ion exchange packing disposed in the sample stream flow channel. The ion receiving channel has an ion exchange capacity for the matrix ions less than about 25% of the ion exchange capacity for the matrix ions.
摘要翻译: 一种用于处理包含分析物离子和相反电荷的基质离子的水样品流的非电解方法和装置,用于预处理或抑制。 该装置包括能够仅将相反电荷的离子通过到分析物离子的离子交换膜,样品流流动通道,邻近样品流流动通道的一侧的第一含水流离子接收流动通道,并由第一离子 交换膜和设置在样品流流动通道中的固定流通离子交换填料。 离子接收通道对于基质离子的离子交换容量小于基质离子的离子交换容量的约25%。
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公开(公告)号:US20150306518A1
公开(公告)日:2015-10-29
申请号:US14260095
申请日:2014-04-23
申请人: DIONEX CORPORATION
发明人: Kannan Srinivasan
CPC分类号: B01D15/367 , B01D15/361 , B01D61/44 , C25F1/00 , C25F7/00 , G01N30/28 , G01N30/96 , G01N2030/965
摘要: An electrolytic device comprising a housing includes at least first and second adjacent liquid flow-through channels. A bather impermeable to ion flow and to bulk liquid flow is disposed between the first and second channels. A first electrode assembly is disposed adjacent to one end of the channels and a second electrode assembly is disposed adjacent the other end of the channels.Also, a contaminant removal method using the above electrolytic device. A first aqueous stream including contaminants flows through the first channel while passing a current between the first and second electrode assemblies to remove contaminants. Effluent from the first channel flows, with or without further treatment, through the second channel while passing current between said first and second electrode assemblies to remove further contaminants.
摘要翻译: 包括壳体的电解装置包括至少第一和第二相邻的液体流通通道。 在第一和第二通道之间设置有不可透过离子流和散装液体流动的浴衣。 第一电极组件邻近通道的一端设置,并且第二电极组件邻近通道的另一端设置。 另外,使用上述电解装置的污染物去除方法。 包含污染物的第一含水流在第一和第二电极组件之间通过电流同时流过第一通道以除去污染物。 来自第一通道的流出物在有或没有进一步处理的情况下通过第二通道流动,同时在所述第一和第二电极组件之间通过电流以除去更多的污染物。
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公开(公告)号:US08636963B2
公开(公告)日:2014-01-28
申请号:US13368663
申请日:2012-02-08
IPC分类号: G01N30/84
CPC分类号: G01N30/96 , B01D15/367 , B01D61/48 , Y10T436/25
摘要: A non-electrolytic method and apparatus for treating an aqueous sample stream including analyte ions and matrix ions of opposite charge, for pretreatment or suppression. The apparatus includes an ion exchange membrane capable of passing only ions of opposite charge to the analyte ions, a sample stream flow channel, a first aqueous stream ion receiving flow channel adjacent one side of the sample stream flow channel and separated therefrom by the first ion exchange membrane, and stationary flow-through ion exchange packing disposed in the sample stream flow channel. The ion receiving channel has an ion exchange capacity for the matrix ions less than about 25% of the ion exchange capacity for the matrix ions.
摘要翻译: 一种用于处理包含分析物离子和相反电荷的基质离子的水样品流的非电解方法和装置,用于预处理或抑制。 该装置包括能够仅将相反电荷的离子通过到分析物离子的离子交换膜,样品流流动通道,邻近样品流流动通道的一侧的第一含水流离子接收流动通道,并由第一离子 交换膜和设置在样品流流动通道中的固定流通离子交换填料。 离子接收通道对于基质离子的离子交换容量小于基质离子的离子交换容量的约25%。
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公开(公告)号:US20130180922A1
公开(公告)日:2013-07-18
申请号:US13787296
申请日:2013-03-06
IPC分类号: B01D15/36
CPC分类号: B01D15/363 , B01D15/361 , B01D15/367 , G01N30/96 , G01N2030/965
摘要: An apparatus for capillary ion chromatography comprising a suppressor comprising flow-through ion exchange packing in a housing and capillary tubing formed of a permselective ion exchange membrane, and at least partially disposed in said ion exchange packing. Also, a recycle conduit for aqueous liquid from the detector to the packing. Further, the capillary tubing may have weakly acidic or weakly basic functional groups. Also, a method for using the apparatus.
摘要翻译: 一种用于毛细管离子色谱的装置,其包括抑制器,该抑制器包括在壳体中的流通离子交换填料和由选择性选择性离子交换膜形成的毛细管,并且至少部分地设置在所述离子交换填料中。 另外,从检测器到包装的水性液体循环管道。 此外,毛细管可具有弱酸性或弱碱性官能团。 另外,使用该装置的方法。
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公开(公告)号:US08415168B2
公开(公告)日:2013-04-09
申请号:US13479119
申请日:2012-05-23
IPC分类号: G01N30/84
CPC分类号: B01D15/363 , B01D15/361 , B01D15/367 , G01N30/96 , G01N2030/965
摘要: An apparatus for capillary ion chromatography comprising a suppressor comprising flow-through ion exchange packing in a housing and capillary tubing formed of a permselective ion exchange membrane, and at least partially disposed in said ion exchange packing. Also, a recycle conduit for aqueous liquid from the detector to the packing. Further, the capillary tubing may have weakly acidic or weakly basic functional groups. Also, a method for using the apparatus.
摘要翻译: 一种用于毛细管离子色谱的装置,包括抑制器,该抑制器包括在壳体中的流通离子交换填料和由选择性选择性离子交换膜形成的毛细管,并且至少部分地设置在所述离子交换填料中。 另外,从检测器到包装的水性液体循环管道。 此外,毛细管可具有弱酸性或弱碱性官能团。 另外,使用该装置的方法。
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公开(公告)号:US20040214344A1
公开(公告)日:2004-10-28
申请号:US10421608
申请日:2003-04-23
IPC分类号: G01N001/00
CPC分类号: G01N30/96 , B01D15/16 , B01D15/367 , G01N30/02 , G01N30/34 , B01D15/361 , G01N30/44
摘要: A method and apparatus is provided for generating a high purity eluant suitable for use in chromatography. The high purity eluant may be generated by providing water and a first stationary phase comprising exchangeable cations. Electrolysis ions are generated by the electrolysis of water. The electrolysis ions are selected from the group consisting of hydronium ions and hydroxide ions. The hydronium ions are passed through the first stationary phase so that the hydronium ions replace the cations in the first stationary phase. Thereafter, a source of desired ions is combined with the cations to form a high purity eluant containing the desired ions.
摘要翻译: 提供了一种产生适用于色谱法的高纯度洗脱液的方法和装置。 可以通过提供水和包含可交换阳离子的第一固定相来产生高纯度洗脱剂。 电解离子是通过水的电解产生的。 电解离子选自水合氢离子和氢氧根离子。 水合氢离子通过第一固定相,使得水合氢离子代替第一固定相中的阳离子。 此后,将所需离子源与阳离子组合以形成含有所需离子的高纯度洗脱液。
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9.
公开(公告)号:US20170199167A1
公开(公告)日:2017-07-13
申请号:US15377833
申请日:2016-12-13
IPC分类号: G01N30/96 , B01D15/36 , G01N27/447
CPC分类号: G01N30/96 , B01D15/24 , B01D15/363 , B01D15/367 , G01N27/44756 , G01N2030/965
摘要: A permeative amine/acid introduction device (PAID) is placed after a conventional KOH eluent suppressed conductometric anion chromatography (SCAC) system. The PAID converts the suppressed eluites from the acid form to the corresponding salt. For example, when the analytes are acids, they are converted to the corresponding ammonium salt (NR2H+HX→NR2H2++X−) and allows very weak acids HX (pKa≧7.0) that cannot normally be detected by SCAC to be measured by a second conductivity detector following the PAID. Permeative reagent introduction is dilutionless, can be operated without pumps and provides good mixing with low band dispersion (as small as 30 μL). An exemplary amine is diethylamine (DEA), which was chosen as the amine source due to its low pKb value (pKb 3.0), high vapor pressure, and low toxicity and low odor.
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公开(公告)号:US20150111305A1
公开(公告)日:2015-04-23
申请号:US14057864
申请日:2013-10-18
申请人: DIONEX CORPORATION
发明人: Kannan SRINIVASAN , Sheetal BHARDWAJ , Rong LIN
IPC分类号: G01N30/96
CPC分类号: G01N30/96 , B01D15/367 , B01D61/44 , G01N2030/645 , G01N2030/965
摘要: An electrolytic device comprising: a central sample flow channel, first and second regenerant flow channels, first and second charged barriers disposed between said sample flow channel and first and second regenerant flow channels, and pairs of oppositely charged, spaced electrodes disposed in the regenerant flow channels. Also, electrolytic devices with a different electrode configuration are described. Also, methods of using the devices, e.g., for suppression in an ion chromatography system are described.
摘要翻译: 一种电解装置,包括:中央样品流动通道,第一和第二再生剂流动通道,设置在所述样品流动通道与第一和第二再生剂流动通道之间的第一和第二带电屏障,以及设置在再生剂流中的成对相对带电的间隔开的电极 频道 另外,还描述了具有不同电极结构的电解装置。 此外,描述了使用该装置的方法,例如用于离子色谱系统中的抑制。
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