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公开(公告)号：US07199074B2
公开(公告)日：2007-04-03
申请号：US11140287
申请日：2005-05-27
CPC分类号： B01J31/16 , B01J31/146 , B01J31/1805 , B01J31/182 , B01J31/183 , B01J31/2208 , B01J31/2243 , B01J31/2291 , B01J31/2404 , B01J2231/005 , B01J2231/12 , B01J2531/001 , B01J2531/0241 , B01J2531/0252 , B01J2531/0291 , B01J2531/16 , B01J2531/62 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C08F4/639 , C08F4/7052 , C08F10/00 , C08F12/08 , C08F112/08 , C08F210/02 , C08F210/14 , C08F2410/03 , C08F4/695 , C08F220/14 , C08F2500/03 , C08F232/00 , C08F2500/25 , C08F212/08 , C08F4/60048 , C08F4/7006 , C08F4/7016 , C08F4/69103 , C08F4/60189 , C08F4/69112
摘要： A catalytic composition, including a cationic metal-pair complex, is disclosed, along with a method for its preparation. A method for the polymerization of ethylenically unsaturated monomers using the catalytic composition, and the addition polymers produced thereby are also disclosed.
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2.发明授权Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers 有权催化组合物及其制备和用于从烯属不饱和单体制备聚合物的用途公开(公告)号：US07172986B2
公开(公告)日：2007-02-06
申请号：US11139874
申请日：2005-05-27
CPC分类号： B01J31/2291 , B01J31/146 , B01J31/16 , B01J31/1805 , B01J31/1815 , B01J31/183 , B01J31/2208 , B01J31/2404 , B01J2231/005 , B01J2231/12 , B01J2531/001 , B01J2531/0291 , B01J2531/16 , B01J2531/62 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07F11/005 , C07F15/006 , C07F15/0066 , C07F15/02 , C07F15/025 , C07F15/06 , C07F15/065 , C08F10/00 , C08F20/12 , C08F32/08 , C08F112/08 , C08F120/14 , C08F132/08 , C08F210/02 , C08F212/08 , C08F220/12 , C08F220/14 , C08F232/00 , C08F232/08 , C08F2410/03 , C08F4/6912 , C08F220/18 , C08F2500/03 , C08F4/7042 , C08F4/7044 , C08F2500/25
摘要： A catalytic composition, including a cationic metal-pair complex, is disclosed, along with a method for its preparation. A method for the polymerization of ethylenically unsaturated monomers using the catalytic composition, and the addition polymers produced thereby are also disclosed.
摘要翻译： 公开了包括阳离子金属对络合物的催化组合物及其制备方法。 还公开了使用催化组合物聚合烯键式不饱和单体的方法和由其制备的加成聚合物。
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3.发明授权Catalyst and method having selectivity to isobutyraldehyde via catalyst induction 有权通过催化剂诱导对异丁醛具有选择性的催化剂和方法公开(公告)号：US08921608B2
公开(公告)日：2014-12-30
申请号：US13837694
申请日：2013-03-15
CPC分类号： C07C45/505 , B01J31/183 , B01J31/189 , B01J31/2404 , B01J31/2447 , B01J2231/321 , B01J2531/0205 , B01J2531/025 , B01J2531/0291 , B01J2531/22 , B01J2531/822 , C07C45/50 , C07C47/02
摘要： Industrially relevant product selectivities and reaction rates are obtained from rhodium catalyzed hydroformylation of propylene via the use of a novel induction period in which the supramolecular ligand assembly, the rhodium precatalyst and an initial substrate are allowed to form a hydroformylation catalyst that is more selective toward branched aldehydes. Upon heating this incubated mixture and addition of propylene, iso-butyraldehyde is obtained in higher concentrations and rates that are otherwise unattainable.
摘要翻译： 通过使用新的诱导期，从铑催化的丙烯加氢甲酰化获得工业相关的产物选择性和反应速率，其中超分子配体组合，铑预催化剂和初始底物被允许形成对分支更具选择性的加氢甲酰化催化剂 醛。 加热该温育混合物并加入丙烯后，以更高的浓度和速率获得异丁醛，否则无法实现。
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公开(公告)号：US20090326226A1
公开(公告)日：2009-12-31
申请号：US12237154
申请日：2008-09-24
申请人： Christoph Jakel , Martin Volland , Thomas Mackewitz , Rocco Paciello , Bernhard Breit , Wolfgang Seiche , Martine Weis , Christoph Waloch
发明人： Christoph Jakel , Martin Volland , Thomas Mackewitz , Rocco Paciello , Bernhard Breit , Wolfgang Seiche , Martine Weis , Christoph Waloch
IPC分类号： C07F9/28
CPC分类号： B01J31/18 , B01J31/182 , B01J31/1865 , B01J31/189 , B01J31/2273 , B01J31/2409 , B01J31/2452 , B01J31/2495 , B01J2231/32 , B01J2231/321 , B01J2231/323 , B01J2231/325 , B01J2231/326 , B01J2231/341 , B01J2231/342 , B01J2231/44 , B01J2231/52 , B01J2231/543 , B01J2231/645 , B01J2531/0266 , B01J2531/0291 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/847 , C07B53/00 , C07F9/58 , C07F9/65719
摘要： The present invention relates to a process for asymmetric synthesis in the presence of a chiral catalyst comprising at least one complex of a metal of transition group VIII with ligands capable of dimerization via noncovalent bonds, such catalysts and their use.
摘要翻译： 本发明涉及在手性催化剂存在下不对称合成的方法，其包含至少一个过渡基团VIII的金属与能够通过非共价键二聚的配体的复合物，以及它们的用途。
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公开(公告)号：US20070073092A1
公开(公告)日：2007-03-29
申请号：US10580322
申请日：2004-11-24
申请人： Christoph Jäkel , Martin Volland , Thomas Mackewitz , Rocco Paciello , Bernhard Breit , Wolfgang Seiche , Martine Weis , Christoph Waloch
发明人： Christoph Jäkel , Martin Volland , Thomas Mackewitz , Rocco Paciello , Bernhard Breit , Wolfgang Seiche , Martine Weis , Christoph Waloch
CPC分类号： B01J31/18 , B01J31/182 , B01J31/1865 , B01J31/189 , B01J31/2273 , B01J31/2409 , B01J31/2452 , B01J31/2495 , B01J2231/32 , B01J2231/321 , B01J2231/323 , B01J2231/325 , B01J2231/326 , B01J2231/341 , B01J2231/342 , B01J2231/44 , B01J2231/52 , B01J2231/543 , B01J2231/645 , B01J2531/0266 , B01J2531/0291 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/847 , C07B53/00 , C07F9/58 , C07F9/65719
摘要： The present invention relates to a process for asymmetric synthesis in the presence of a chiral catalyst comprising at least one complex of a metal of transition group VIII with ligands capable of dimerization via noncovalent bonds, such catalysts and their use.
摘要翻译： 本发明涉及在手性催化剂存在下不对称合成的方法，其包含至少一个过渡基团VIII的金属与能够通过非共价键二聚的配体的复合物，以及它们的用途。
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6.发明申请CATALYST AND METHOD HAVING SELECTIVITY TO ISOBUTYRALDEHYDE VIA CATALYST INDUCTION 有权具有通过催化剂诱导的异丁酸选择性的催化剂和方法公开(公告)号：US20130324713A1
公开(公告)日：2013-12-05
申请号：US13837694
申请日：2013-03-15
CPC分类号： C07C45/505 , B01J31/183 , B01J31/189 , B01J31/2404 , B01J31/2447 , B01J2231/321 , B01J2531/0205 , B01J2531/025 , B01J2531/0291 , B01J2531/22 , B01J2531/822 , C07C45/50 , C07C47/02
摘要： Industrially relevant product selectivities and reaction rates are obtained from rhodium catalyzed hydroformylation of propylene via the use of a novel induction period in which the supramolecular ligand assembly, the rhodium precatalyst and an initial substrate are allowed to form a hydroformylation catalyst that is more selective toward branched aldehydes. Upon heating this incubated mixture and addition of propylene, iso-butyraldehyde is obtained in higher concentrations and rates that are otherwise unattainable.
摘要翻译： 通过使用新的诱导期，从铑催化的丙烯加氢甲酰化获得工业相关的产物选择性和反应速率，其中超分子配体组合，铑预催化剂和初始底物被允许形成对分支更具选择性的加氢甲酰化催化剂 醛。 加热该温育混合物并加入丙烯后，以更高的浓度和速率获得异丁醛，否则无法实现。
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公开(公告)号：US07696349B2
公开(公告)日：2010-04-13
申请号：US12237154
申请日：2008-09-24
申请人： Christoph Jäkel , Martin Volland , Thomas Mackewitz , Rocco Paciello , Bernhard Breit , Wolfgang Seiche , Martine Weis , Christoph Waloch
发明人： Christoph Jäkel , Martin Volland , Thomas Mackewitz , Rocco Paciello , Bernhard Breit , Wolfgang Seiche , Martine Weis , Christoph Waloch
IPC分类号： C07F9/80
CPC分类号： B01J31/18 , B01J31/182 , B01J31/1865 , B01J31/189 , B01J31/2273 , B01J31/2409 , B01J31/2452 , B01J31/2495 , B01J2231/32 , B01J2231/321 , B01J2231/323 , B01J2231/325 , B01J2231/326 , B01J2231/341 , B01J2231/342 , B01J2231/44 , B01J2231/52 , B01J2231/543 , B01J2231/645 , B01J2531/0266 , B01J2531/0291 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/847 , C07B53/00 , C07F9/58 , C07F9/65719
摘要： The present invention relates to a process for asymmetric synthesis in the presence of a chiral catalyst comprising at least one complex of a metal of transition group VIII with ligands capable of dimerization via noncovalent bonds, such catalysts and their use.
摘要翻译： 本发明涉及在手性催化剂存在下不对称合成的方法，其包含至少一个过渡基团VIII的金属与能够通过非共价键二聚的配体的复合物，以及它们的用途。
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公开(公告)号：US20050277569A1
公开(公告)日：2005-12-15
申请号：US11139874
申请日：2005-05-27
申请人： Brian Goodall , Jennifer Petoff , Han Shen
发明人： Brian Goodall , Jennifer Petoff , Han Shen
IPC分类号： B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , C07F11/00 , C07F15/00 , C07F15/02 , C07F15/04 , C07F15/06 , C07F19/00 , C08F4/70 , C08F10/00 , C08F20/12 , C08F32/08 , C08F112/08 , C08F120/14 , C08F132/08 , C08F210/02 , C08F212/08 , C08F220/12 , C08F220/14 , C08F232/08 , C11D17/00
CPC分类号： B01J31/2291 , B01J31/146 , B01J31/16 , B01J31/1805 , B01J31/1815 , B01J31/183 , B01J31/2208 , B01J31/2404 , B01J2231/005 , B01J2231/12 , B01J2531/001 , B01J2531/0291 , B01J2531/16 , B01J2531/62 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07F11/005 , C07F15/006 , C07F15/0066 , C07F15/02 , C07F15/025 , C07F15/06 , C07F15/065 , C08F10/00 , C08F20/12 , C08F32/08 , C08F112/08 , C08F120/14 , C08F132/08 , C08F210/02 , C08F212/08 , C08F220/12 , C08F220/14 , C08F232/00 , C08F232/08 , C08F2410/03 , C08F4/6912 , C08F220/18 , C08F2500/03 , C08F4/7042 , C08F4/7044 , C08F2500/25
摘要： A catalytic composition, including a cationic metal-pair complex, is disclosed, along with a method for its preparation. A method for the polymerization of ethylenically unsaturated monomers using the catalytic composition, and the addition polymers produced thereby are also disclosed.
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公开(公告)号：US08216968B2
公开(公告)日：2012-07-10
申请号：US10557706
申请日：2004-05-24
申请人： Joost Nicolaas Hendrik Reek , Ruifang Chen , Paul Clemens Jozef Kamer , Vincent Friso Slagt , Petrus Wilhelmus Nicholas Maria Van Leeuwen
发明人： Joost Nicolaas Hendrik Reek , Ruifang Chen , Paul Clemens Jozef Kamer , Vincent Friso Slagt , Petrus Wilhelmus Nicholas Maria Van Leeuwen
IPC分类号： C07F19/00
CPC分类号： B01J31/2495 , B01J31/069 , B01J31/1608 , B01J31/1633 , B01J31/165 , B01J31/183 , B01J31/189 , B01J31/2409 , B01J2219/00497 , B01J2219/00605 , B01J2219/00612 , B01J2219/00626 , B01J2219/00628 , B01J2219/00738 , B01J2231/12 , B01J2231/321 , B01J2231/342 , B01J2231/348 , B01J2231/4205 , B01J2231/44 , B01J2231/46 , B01J2231/52 , B01J2231/543 , B01J2231/645 , B01J2531/025 , B01J2531/0291 , B01J2531/26 , B01J2531/822 , B01J2531/824 , B01J2540/68 , C07C45/50 , C07C45/72 , C07C67/293 , C07C67/303 , C07F15/006 , C07F15/0066 , C07F15/0073 , C07F15/008 , Y02P20/588 , C07C47/228 , C07C69/007 , C07C69/34 , C07C69/157
摘要： The invention relates to a coordination complex system comprising a ligand having at least two donor moieties, which are complexed to at least a metal selected from a transition metal and lanthanide, characterized in that the ligand comprises at least two building blocks, each having at least one functional group and at least one donor moiety, wherein one building block is non-covalently bonded through its functional group to a complementary functional group of another building block or of a template, wherein the template comprises at least one other functional group that is noncovalently bonded to a complementary functional group of another building block, and wherein all building blockemplate-building block structures are the same when the template contains more than two functional groups.
摘要翻译： 本发明涉及一种配位络合物体系，其包含具有至少两个供体部分的配体，其与至少一种选自过渡金属和镧系元素的金属络合，其特征在于该配体包含至少两个构建块， 一个官能团和至少一个供体部分，其中一个结构单元通过其官能团非共价键合到另一个结构单元或模板的互补官能团，其中该模板包含非共价的至少一个其它官能团 键合到另一构建块的互补官能团，并且其中当模板包含多于两个官能团时，所有建筑模板构建块结构相同。
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公开(公告)号：US07790932B1
公开(公告)日：2010-09-07
申请号：US12653878
申请日：2009-12-21
CPC分类号： C07C29/141 , B01J31/189 , B01J31/2409 , B01J31/2452 , B01J2231/321 , B01J2531/0291 , B01J2531/822 , C07C45/50 , C07C31/207 , C07C47/19
摘要： A catalyst, useful for the hydroformylation of allyl alcohol, is described. The catalyst comprises a rhodium complex and a 6-bis(3,5-dialkylphenyl)phosphino-N-pivaloyl-2-aminopyridine or a 3-bis(3,5-dialkylphenyl)phosphino-2H-isoquinolin-1-one. The invention also includes a process for the production of 4-hydroxybutyraldehyde comprising reacting allyl alcohol with a mixture of carbon monoxide and hydrogen in the presence of a solvent and the catalyst. The process gives a high ratio of the linear product 4-hydroxybutyraldehyde to the branched co-product 3-hydroxy-2-methylpropionaldehyde.
摘要翻译： 描述了可用于烯丙醇加氢甲酰化的催化剂。 催化剂包含铑络合物和6-双（3,5-二烷基苯基）膦基-N-新戊酰基-2-氨基吡啶或3-双（3,5-二烷基苯基）膦基-2H-异喹啉-1-酮。 本发明还包括一种生产4-羟基丁醛的方法，包括在溶剂和催化剂存在下使烯丙醇与一氧化碳和氢气的混合物反应。 该方法给出线性产物4-羟基丁醛与支链副产物3-羟基-2-甲基丙醛的高比例。
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