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    Alcohol Oxidation Catalyst and Method of Synthesizing the Same
    3.
    发明申请
    Alcohol Oxidation Catalyst and Method of Synthesizing the Same 审中-公开
    醇氧化催化剂及其合成方法

    公开(公告)号：US20070232838A1

    公开(公告)日：2007-10-04

    申请号：US11570756

    申请日：2005-06-24

    Applicant: Yoshiharu Iwabuchi ,  Masatoshi Shibuya ,  Masaki Tomizawa

    Inventor： Yoshiharu Iwabuchi ,  Masatoshi Shibuya ,  Masaki Tomizawa

    IPC: C07D487/00 ,  B01J31/02 ,  C07C29/00

    CPC classification number: C07D471/08 ,  B01J31/006 ,  B01J31/0235 ,  B01J31/0237 ,  B01J2231/70 ,  C07C45/29

    Abstract: An organic oxidation catalyst for alcohols which is environmentally less harmful and with which efficient oxidation can be conducted. The oxidation catalyst for alcohols is a 1-alkyl-2-azadamantan-N-oxyl which has a nitroxyl group incorporated in the adamantane skeleton and was synthesized from as a base material a bicyclic compound obtained by the Grob-type ring-opening reaction of 1,3-adamantanediol. Due to the nitroxyl group on the adamantane skeleton, the α-position hydrogen is stabilized based on Bredt's rule and the stability of the oxoammonium group generated by the oxidation thereof is ensured. Compared to TEMPO, which is a conventional oxidation catalyst, this catalyst is reduced in steric hindrance and is usable in a wide range of reaction fields. Because of this, not only a primary alcohol but a secondary alcohol having a sterically complicated structure, which has been difficult to oxidize with TEMPO, can be oxidized at a high efficiency.

    Abstract translation: 用于醇的有机氧化催化剂，其对环境无害且能够进行有效的氧化。 醇的氧化催化剂是在金刚烷骨架中具有硝酰基的1-烷基-2-氮杂金刚烷-N-氧基，其作为基材通过由Grob型开环反应获得的双环化合物合成， 1,3-金刚烷二醇 由于金刚烷骨架上的硝酰基，基于Bredt规则使α位氢稳定，并且确保了通过其氧化产生的氧代铵基团的稳定性。 与作为常规氧化催化剂的TEMPO相比，该催化剂的空间位阻减小，可用于广泛的反应领域。 因此，不仅可以高效地氧化难以用TEMPO氧化的伯醇和具有空间复杂结构的仲醇。

    Ionic liquids and their use
    4.
    发明授权
    Ionic liquids and their use 有权
    离子液体及其用途

    公开(公告)号：US07196221B2

    公开(公告)日：2007-03-27

    申请号：US10381059

    申请日：2001-09-26

    Applicant: Andrew P. Abbott ,  David L. Davies ,  Glen Capper ,  Raymond K. Rasheed ,  Vasuki Tambyrajah

    Inventor： Andrew P. Abbott ,  David L. Davies ,  Glen Capper ,  Raymond K. Rasheed ,  Vasuki Tambyrajah

    IPC: C07C211/00

    CPC classification number: B01J31/0284 ,  B01J31/006 ,  B01J31/0279 ,  B01J31/26 ,  B01J2231/125 ,  B01J2231/326 ,  C07B37/12 ,  C07C45/69 ,  C07C211/63 ,  C07C215/90 ,  C07C2601/16 ,  C07C2602/42 ,  C07C2602/44 ,  C25D3/02 ,  C25D3/665 ,  C25F3/20 ,  C25F3/24 ,  H01M6/164 ,  H01M6/166 ,  H01M10/36 ,  C07C47/42 ,  C07C49/543 ,  C07C49/553 ,  C07C47/445

    Abstract: Ionic compounds having a freezing point of no more than 50° C., formed by the reaction of at least one amine salt of the formula R1R2R3R4N+X− (I) with at least one hydrated salt, which is a chloride, nitrate, sulphate or acetate of Li, Mg, Ca, Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb, Bi, La or Ce; wherein R1, R2 and R3 are each independently a C1 to C5 alkyl or a C6 to C10 cycloalkyl group, or wherein R2 and R3 taken together represent a C4 to C10 alkylene group, thereby forming with the N atom of formula (I) a 5 to 11 membered heterocyclic ring, and wherein R4 is hydrogen, or phenyl, or C1 to C12 alkyl or cycloalkyl group, optionally substituted with at least one group selected from OH, Cl, Br, F, I, phenyl, NH2, CN, NO2, COOR5, CHO, COR5 and OR5, wherein R5 is a C1 to C10 alkyl or cycloalkyl group, and X− is an anion capable of being complexed by the said hydrated salt. The compounds are useful as solvents, electrolytes, and catalysts, and have particular application in solvents/electrolytes for metal plating and electropolishing processes, in particular in chromium plating.

    Abstract translation: 通过使至少一种下式的胺盐反应形成冰点不超过50℃的离子化合物：R 1， 具有至少一种水合盐，其是氯化物，硝酸盐，硫酸盐（III），其中R 1，R 2，R 3，R 4， 或Li，Mg，Ca，Cr，Mn，Fe，Co，Ni，Cu，Zn，Cd，Pb，Bi，La或Ce的乙酸盐; 其中R 1，R 2和R 3各自独立地为C 1至C 5， / C 1 -C 6烷基或C 6〜C 10环烷基，或其中R 2和R 3取代 一起代表C 10亚烷基的C 4+，从而与式（I）的N原子形成5至11元杂环，并且其中R“ 4是氢或苯基或C 1至C 12烷基或环烷基，任选被至少一个选自OH，Cl，Br ，F，I，苯基，NH 2，CN，NO 2，COOR 5，CHO，COR 5， 和OR 5，其中R 5是C 1至C 10烷基或环烷基的C 1至C 10， SUP> - 是能够被所述水合盐络合的阴离子。 该化合物可用作溶剂，电解质和催化剂，并且特别适用于用于金属电镀和电解抛光方法的溶剂/电解质，特别是在镀铬中。

    Process for producing epoxide compound
    5.
    发明授权
    Process for producing epoxide compound 失效
    环氧化合物的制备方法

    公开(公告)号：US07074947B2

    公开(公告)日：2006-07-11

    申请号：US10501956

    申请日：2003-01-31

    Applicant: Masaji Hirota ,  Koji Hagiya

    Inventor： Masaji Hirota ,  Koji Hagiya

    IPC: C07D301/12 ,  B01J31/06

    CPC classification number: B01J31/34 ,  B01J23/28 ,  B01J23/30 ,  B01J27/16 ,  B01J27/22 ,  B01J31/006 ,  B01J31/0237 ,  B01J31/0244 ,  B01J2231/72 ,  C07D301/12

    Abstract: A process for producing an epoxide compound, characterized by reacting an olefin compound with hydrogen peroxide in the presence of: a metal oxide catalyst obtained by reacting hydrogen peroxide with at least one member selected from the group consisting of tungsten metal, molybdenum metal, compounds of tungsten and a Group IIIb, IVb, Vb, or VIb element, tungstic acid and salts thereof, compounds of molybdenum and a Group IIIb, IVb, Vb, or VIb element, and molybodic acid and salts thereof; at least one member selected from the group consisting of tertiary amine compounds, tertiary amine oxide compounds, nitrogenous aromatic compounds, and nitrogenous aromatic N-oxide compounds; and a phosphoric acid compound.

    Abstract translation: 一种制备环氧化合物的方法，其特征在于使烯烃化合物与过氧化氢在以下存在下反应：金属氧化物催化剂，其通过使过氧化氢与至少一种选自钨金属，钼金属， 钨和IIIb，IVb，Vb或VIb族元素，钨酸及其盐，钼和IIIb，IVb，Vb或VIb族元素的化合物，以及钼酸及其盐; 选自叔胺化合物，叔胺氧化物化合物，含氮芳族化合物和含氮芳族N-氧化物化合物中的至少一种; 和磷酸化合物。

    Process for producing expoxide compound
    7.
    发明申请
    Process for producing expoxide compound 失效
    过氧化物生产工艺

    公开(公告)号：US20050020841A1

    公开(公告)日：2005-01-27

    申请号：US10501956

    申请日：2003-01-31

    Applicant: Masaji Hirota ,  Koji Hagiya

    Inventor： Masaji Hirota ,  Koji Hagiya

    IPC: B01J23/28 ,  B01J23/30 ,  B01J27/16 ,  B01J27/22 ,  B01J31/02 ,  B01J31/34 ,  C07D301/12

    CPC classification number: B01J31/34 ,  B01J23/28 ,  B01J23/30 ,  B01J27/16 ,  B01J27/22 ,  B01J31/006 ,  B01J31/0237 ,  B01J31/0244 ,  B01J2231/72 ,  C07D301/12

    Abstract: A process for producing an epoxide compound, characterized by reacting an olefin compound with hydrogen peroxide in the presence of: a metal oxide catalyst obtained by reacting hydrogen peroxide with at least one member selected from the group consisting of tungsten metal, molybdenum metal, compounds of tungsten and a Group IIIb, IVb, Vb, or VIb element, tungstic acid and salts thereof, compounds of molybdenum and a Group IIIb, IVb, Vb, or VIb element, and molybodic acid and salts thereof; at least one member selected from the group consisting of tertiary amine compounds, tertiary amine oxide compounds, nitrogenous aromatic compounds, and nitrogenous aromatic N-oxide compounds; and a phosphoric acid compound.

    Abstract translation: 一种制备环氧化合物的方法，其特征在于使烯烃化合物与过氧化氢在以下存在下反应：金属氧化物催化剂，其通过使过氧化氢与至少一种选自钨金属，钼金属， 钨和IIIb，IVb，Vb或VIb族元素，钨酸及其盐，钼和IIIb，IVb，Vb或VIb族元素的化合物，以及钼酸及其盐; 选自叔胺化合物，叔胺氧化物化合物，含氮芳族化合物和含氮芳族N-氧化物化合物中的至少一种; 和磷酸化合物。

    Metal ligand containing bleaching compositions
    10.
    发明授权
    Metal ligand containing bleaching compositions 有权
    含有漂白组合物的金属配体

    公开(公告)号：US06241779B1

    公开(公告)日：2001-06-05

    申请号：US09564419

    申请日：2000-05-04

    Applicant: Terrence J. Collins ,  Colin P. Horwitz

    Inventor： Terrence J. Collins ,  Colin P. Horwitz

    IPC: D06L302

    CPC classification number: C07D257/10 ,  B01J31/006 ,  B01J31/184 ,  B01J2231/70 ,  B01J2531/72 ,  B01J2531/842 ,  C11D3/3932 ,  D21C9/1036

    Abstract: The invention provides a novel composition and method for removing or reducing levels of recalcitrant constituents from an effluent, such as lignin chromophores, AOX species, such as chlorinated phenols, dioxins, dibenzofurans, biphenyls, and high molecular weight material produced in the pulp and paper bleaching operations which includes using a composition comprised of (a) an amount of a source of an oxidant effective for oxidizing and thereby reducing the levels of such constituents and (b) an oxidatively stable oxidant activator having the structure wherein Y1, Y3 and Y4 each represent a bridging group having zero, one, two or three carbon containing nodes for substitution, and Y2 is a bridging group having at least one carbon containing node for substitution, each said node containing a C(R), C(R1)(R2), or a C(R)2 unit and each R substituent is the same or different from the remaining R substituents; M is a transition metal with oxidation states of I, II, III, IV, V, VI, VII or VIII or selected from Groups 3, 4, 5, 6, 7, 8, 9, 10 and 11 of the Periodic Table of the Elements; and Q is any counterion which would balance the charge of the compound on a stoichiometric basis.

    Abstract translation: 本发明提供了用于从流出物如木质素发色团，AOX物质如氯化酚，二恶英，二苯并呋喃，联苯和在纸浆和纸中产生的高分子量材料中去除或降低顽固成分的水平的新型组合物和方法 漂白操作包括使用包含（a）一定量的氧化剂源的氧化剂量，从而降低这些成分的含量的组合物，和（b）具有Y1，Y3和Y4的结构的氧化稳定的氧化剂活化剂各自表示 具有0,1或2个或3个含碳的节点用于取代的桥连基团，Y2是具有至少一个含碳节点进行取代的桥连基团，每个所述节点含有C（R），C（R 1）（R 2） ，或C（R）2单元，并且每个R取代基与其余R取代基相同或不同; M是具有I，II，III，IV，V，VI，VII或VIII氧化态或选自元素周期表第3,4,5,6,7,8,9,10和11族的过渡金属 元素; 而Q是以化学计量为基础平衡化合物的电荷的任何抗衡离子。

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