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公开(公告)号：US20230242466A1
公开(公告)日：2023-08-03
申请号：US18134219
申请日：2023-04-13
Applicant: DAIKIN INDUSTRIES, LTD.
Inventor： Yuusuke ETOU , Shingo NAKAMURA
IPC: C07C17/25 , C07C17/087 , C07C21/18 , C07C21/22
CPC classification number: C07C17/25 , C07C17/087 , C07C21/18 , C07C21/22
Abstract: A halogenated alkene compound and a fluorinated alkyne compound are obtained at a high conversion rate and high selectivity by employing any of the following methods (1) to (4):
(1) a halogenated butane compound represented by CX1X2X3CHX4CFHCX5X6X7, wherein X1, X2, X3, X4, X5, X6, and X7 are the same or different and each is a halogen atom, to a dehydrofluorination reaction;
(2) a halogenated butene compound represented by CX1X2X3CX4═CHCX5X6X7, wherein X1, X2, X3, X4, X5, X6, and X7 are as defined above, to a dehydrohalogenation reaction;
(3) a halogenated alkane compound represented by CHX8A1CHX9A2, wherein A1 and A2 are each a fluorine atom or a perfluoroalkyl group, and X8 and X9 are the same or different and each is a halogen atom, to a dehydrohalogenation reaction in the presence of a catalyst in a gas phase; and
(4) a halogenated alkene compound represented by CX8A1=CHA2, wherein A1, A2, and X8 are as defined above, to a dehydrohalogenation reaction in the presence of a catalyst.
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2.发明授权
公开(公告)号：US09752076B2
公开(公告)日：2017-09-05
申请号：US13505761
申请日：2010-10-06
Applicant: Christian Jasper , Elvira Montenegro , Detlef Pauluth , Volker Reiffenrath , Atsutaka Manabe
Inventor： Christian Jasper , Elvira Montenegro , Detlef Pauluth , Volker Reiffenrath , Atsutaka Manabe
IPC: C09K19/32 , C09K19/42 , C07C13/47 , C07C13/573 , C07C15/24 , C07C15/28 , C07C21/185 , C07C21/19 , C07C21/22 , C07C22/08
CPC classification number: C09K19/32 , C07C13/47 , C07C13/573 , C07C15/24 , C07C15/28 , C07C21/185 , C07C21/19 , C07C21/22 , C07C22/08 , C09K19/322 , C09K19/42 , C09K2219/11
Abstract: The present invention relates to compounds of the formula I where one or more of the radicals A1-5 denote a 1,4-naphthylene or 1,4- or 9,10-anthracenylene radical, and the other parameters are as defined in Claim 1. The invention additionally includes liquid-crystalline media which comprise the title compounds, and components for high-frequency technology which comprise these media, in particular phase shifters and microwave array antennae.
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公开(公告)号：US20160016988A1
公开(公告)日：2016-01-21
申请号：US14777267
申请日：2014-03-15
Inventor： John W. CRAN , Yinglin HAN , Faliang ZHANG
CPC classification number: C07J1/00 , C07C17/16 , C07C17/361 , C07C21/14 , C07C21/22 , C07C45/41 , C07C45/59 , C07C2601/10 , C07D317/72 , C07F7/0801 , C07F7/0805 , C07F7/0812 , C07F7/1804 , C07F9/5022 , C07F9/5059 , C07F9/5442 , C07F9/5456 , C07F9/65517 , C07J5/0053 , C07J15/005 , C07J61/00 , C07C47/20 , C07C49/647
Abstract: The present invention relates to the synthesis of ent-progesterone and intermediates thereof.
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公开(公告)号：US09169178B2
公开(公告)日：2015-10-27
申请号：US14429817
申请日：2013-09-16
Applicant: BROMINE COMPOUNDS LTD.
Inventor： Jakob Oren
Abstract: This invention provides a process for obtaining propargyl bromide in high yield from propargyl alcohol and phosphorus bromide, in the form of a stable composition with alkylbromide.
Abstract translation: 本发明提供以具有烷基溴的稳定组合物的形式从炔丙醇和溴化磷以高产率获得炔丙基溴的方法。
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公开(公告)号：US08703829B2
公开(公告)日：2014-04-22
申请号：US13478789
申请日：2012-05-23
Applicant: Gerald B. Hammond , Bo Xu , Paula J. Bates
Inventor： Gerald B. Hammond , Bo Xu , Paula J. Bates
IPC: A61K31/035 , A61K31/045
CPC classification number: C07C69/007 , C07C17/266 , C07C17/269 , C07C33/42 , C07C33/426 , C07C33/483 , C07C43/225 , C07C69/78 , C07C271/14 , C07C2601/02 , C07C2601/14 , C07D317/20 , C07C21/22
Abstract: The invention provides compounds of Formula (I): R1≡R2 (I) wherein R1 and R2 have any of the values or specific values defined herein, as well as compositions comprising such compounds and therapeutic methods comprising the administration of such compounds.
Abstract translation: 本发明提供了式（I）化合物：其中R 1和R 2具有本文定义的任何值或具体值的R 1 = R 2（I），以及包含这些化合物的组合物和包括施用这些化合物的治疗方法。
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公开(公告)号：US20110288349A1
公开(公告)日：2011-11-24
申请号：US13110992
申请日：2011-05-19
Applicant: Andrew Joseph Poss , David Nalewajek , Michael Van Der Puy , Haridasan K. Nair
Inventor： Andrew Joseph Poss , David Nalewajek , Michael Van Der Puy , Haridasan K. Nair
IPC: C07C17/278
CPC classification number: C07C21/18 , C07C17/206 , C07C17/25 , C07C17/278 , C07C17/354 , Y02P20/582 , C07C19/08 , C07C21/22 , C07C19/10
Abstract: The present invention provides a method for the preparation of suitable chlorofluorocarbon and hydrochlorofluorocarbon materials or chlorofluorocarbon and hydrochlorofluorocarbon alkene and alkyne intermediates which serve as useful feedstock for fluorination and reduction to cis-1,1,1,4,4,4-hexafluoro-2-butene. Also presented is a continuous process for the production of cis-1,1,1,4,4,4-hexafluoro-2-butene from the alkene and alkyne intermediates.
Abstract translation: 本发明提供了制备合适的氯氟烃和氢氯氟烃材料或氯氟烃和氢氯氟烃烯烃和炔烃中间体的方法，其用作氟化和还原成顺式-1,1,1,4,4,4-六氟-2 丁烯。 还提出了从烯烃和炔烃中间体生产顺式-1,1,1,4,4,4-六氟-2-丁烯的连续方法。
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公开(公告)号：US20110288346A1
公开(公告)日：2011-11-24
申请号：US13110979
申请日：2011-05-19
Applicant: Andrew Joseph Poss , David Nalewajek , Haridasan K. Nair , Michael Van Der Puy
Inventor： Andrew Joseph Poss , David Nalewajek , Haridasan K. Nair , Michael Van Der Puy
IPC: C07C17/354
CPC classification number: C07C17/278 , C07C17/04 , C07C17/206 , C07C17/23 , C07C17/25 , C07C17/354 , C07C19/10 , C07C21/22 , C07C21/18
Abstract: Disclosed is a process for preparing cis-1,1,1,4,4,4-hexafluoropropene comprising the steps of (a) reacting CCl4 with a compound having the formula CF3CX═CXH, where each X is independently halogen or hydrogen, to form a compound having the formula CF3CXClCXHCCl3; (b) fluorinating the compound formed in step (a) to form a compound having the formula CF3CXHCXHCF3; (c) converting the compound formed in step (b) by a reaction selected from the group consisting of dehydrohalogenation, dehalogenation and both reactions, to form a compound having the formula CF3C≡CCF3; and (d) catalytically reducing the compound formed in step (c) with hydrogen to form the compound having the formula:
Abstract translation: 公开了一种制备顺式-1,1,1,4,4,4-六氟丙烯的方法，包括以下步骤：（a）使CCl4与具有式CF 3 C X = C X H的化合物反应，其中每个X独立地为卤素或氢， 形成式CF3CXClCXHCCl3的化合物; （b）氟化步骤（a）中形成的化合物以形成具有式CF 3 C XHCXHCF 3的化合物; （c）通过选自脱卤化氢，脱卤和两种反应的反应转化步骤（b）中形成的化合物，以形成具有式CF 3C≡CCF3的化合物; 和（d）用氢气将步骤（c）中形成的化合物催化还原以形成具有下式的化合物：
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公开(公告)号：US07951981B2
公开(公告)日：2011-05-31
申请号：US12225529
申请日：2007-03-30
Applicant: Tatsuya Sugimoto
Inventor： Tatsuya Sugimoto
Abstract: A process for producing a perfluoroalkyne compound includes an addition reaction step of adding Cl2, Br2, or I2 to a compound shown by the formula (1) CH3C≡CR1 to obtain a compound shown by the formula (2) CH3CX2CX2R1, a fluorination reaction step of reacting the compound shown by the formula (2) with fluorine gas to obtain a compound shown by the formula (3) CF3CX2CX2R2, and a dehalogenation reaction step of contacting the compound shown by the formula (3) with a metal or an organometallic compound to obtain a perfluoroalkyne compound shown by the formula (4) CF3C≡CR2. According to the present invention, a perfluoroalkyne compound can be produced at high productivity and high yield using starting raw materials which are environmentally friendly and industrially available. In the above formulas, R1 represents a methyl group or an ethyl group, X represents Cl, Br, or I, and R2 represents a trifluoromethyl group or a pentafluoroethyl group.
Abstract translation: 一种全氟炔化合物的制造方法，包括向式（1）所示的化合物（CH 3C≡CR1）表示的化合物中加入Cl 2，Br 2或I 2的加成反应工序，得到式（2）所示的化合物，CH 3 C X 2 C X 2 R 1，氟化反应步骤 使式（2）所示的化合物与氟气反应，得到式（3）CF 3 C X 2 C X 2 R 2所示的化合物和使式（3）所示的化合物与金属或有机金属化合物接触的脱卤反应步骤 得到式（4）CF 3C≡CR2所示的全氟炔化合物。 根据本发明，可以以环保和工业上可获得的起始原料，以高生产率和高产率生产全氟炔化合物。 在上式中，R 1表示甲基或乙基，X表示Cl，Br或I，R 2表示三氟甲基或五氟乙基。
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公开(公告)号：US20100145112A1
公开(公告)日：2010-06-10
申请号：US12596321
申请日：2008-04-04
Applicant: Akira Ishihara , Yasuo Hibino
Inventor： Akira Ishihara , Yasuo Hibino
IPC: C07C21/18
Abstract: Disclosed is a method for producing 3,3,3-trifluoropropyne, which is characterized in that a base is reacted with (Z)-1-halogeno-3,3,3-trifluoropropene represented by formula [1]. It is possible by this production method to obtain 3,3,3-trifluoropropyne with high yield. Furthermore, since waste disposal is also easy, it is a production method that is industrially advantageous.
Abstract translation: 公开了3,3,3-三氟丙炔的制造方法，其特征在于使碱与式（1）所示的（Z）-1-卤代-3,3,3-三氟丙烯反应。 可以通过该制造方法以高收率得到3,3,3-三氟丙炔。 此外，由于废物处理也容易，因此是在工业上有利的生产方法。
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公开(公告)号：US07341764B2
公开(公告)日：2008-03-11
申请号：US10493225
申请日：2002-10-31
Applicant: Mitsuru Sugawara , Toshiro Yamada , Tatsuya Sugimoto , Kimiaki Tanaka
Inventor： Mitsuru Sugawara , Toshiro Yamada , Tatsuya Sugimoto , Kimiaki Tanaka
CPC classification number: C07C21/22 , C07C17/25 , C23C16/26 , C23C16/30 , C23F4/00 , H01L21/3065 , H01L21/31116
Abstract: A gas for plasma reaction comprising a chainlike perfluoroalkyne having 5 or 6 carbon atoms, preferably perfluoro-2-pentyne. This plasma reaction gas is suitable for dry etching for formation of a fine pattern, for plasma CVD for formation of a thin film, and for plasma ashing. The plasma reaction gas is synthesized by contacting a dihydrofluoroalkane compound or a monohydrofluoroalkene compound with a basic compound.
Abstract translation: 一种用于等离子体反应的气体，包括具有5或6个碳原子的链状全氟炔烃，优选全氟-2-戊炔。 这种等离子体反应气体适用于形成精细图案的干蚀刻，用于形成薄膜的等离子体CVD和等离子体灰化。 通过使二氢氟烷烃化合物或单氢氟烯烃化合物与碱性化合物接触来合成等离子体反应气体。
