Abstract:
A composite polyimide separator and a preparation method thereof, and a secondary battery are described. The preparation method of the composite polyimide separator comprises: providing a porous polyamic acid film; subjecting a diamine aqueous solution and an acyl chloride organic solution to an interfacial polymerization reaction on a surface of the porous polyamic acid film to obtain a composite polyamic acid separator; and placing the composite polyamic acid separator in vapor of an imidization reagent for imidization treatment to obtain the composite polyimide separator. In the present application, by controlling the parameters of the interfacial polymerization reaction, a composite polyamic acid separator with a dense surface, a loose bottom, and an adjustable surface pore size can be obtained.
Abstract:
A process comprises polymerizing an olefin monomer in a loop reactor in the presence of a catalyst and a diluent, and producing a slurry comprising solid particulate olefin polymer and diluent. The Biot number is maintained at or below about 3.0 within the loop reactor during the polymerizing process. The slurry in the loop reactor forms a slurry film having a film coefficient along an inner surface of the reactor wall, and the film coefficient is less than about 500 BTU·hr−1·ft−2·° F.−1.
Abstract:
Provided is a method of forming a polymer, comprising (a) providing a reaction mixture comprising (i) one or more vinyl monomers, (ii) one or more pH-sensitive inhibition systems, (iii) one or more initiators, and (iv) water; (b) establishing conditions in said reaction mixture such that a free radical polymerization of said vinyl monomer occurs at a location, and (c) after steps (a) and (b) and prior to completion of said free radical polymerization, changing the pH of said reaction mixture to increase the rate of generation of said free radical polymerization at the location of said free radical polymerization.
Abstract:
A method for producing a polymer, which contains: bringing a monomer containing a vinyl bond into contact with a compressive fluid and melting or dissolving the monomer containing a vinyl bond, followed by carrying out addition polymerization of the monomer containing a vinyl bond in the presence of an initiator.
Abstract:
A polyethylene resin having a multimodal molecular weight distribution comprising at least two polyethylene fractions A and B, fraction A being substantially free of comonomer and having a lower weight average molecular weight and a higher density than fraction B, each fraction prepared in different reactors of two reactors connected in series in the presence of a Ziegler-Natta catalyst system, the polyethylene resin having a density of from 0.950 to 0.965 g/cm3 and a melt index MI2 of from 0.5 to 5 g/10 min.
Abstract:
The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.
Abstract:
Techniques are provided for producing polymer particles of a size just slightly larger than the size of polymer fines. The technique may prevent or limit the occurrence of reactor fouls associated with large polymer particles. The technique also may provide a greater weight percentage of solids in the reactor. The desired polymer particle size may be achieved by employing a catalyst having particles of a size determined based on the expected catalyst productivity. In certain embodiments, the catalyst particle size may be determined based on the expected catalyst productivity, the polymer particle density, the catalyst particle density, and/or the polymer particle size.
Abstract:
The present disclosure relates to methods for the hydroaminoalkylation of an olefin. Such methods can comprise reacting the olefin with a secondary amine in the presence of a catalyst of Formula (I). The present disclosure also relates to catalysts which can be useful in such methods. LxM(R1)y(I)
Abstract:
A process for polymerising alpha-olefin monomers in a loop reactor comprising the steps of introducing a main feed stream (2) comprising at least one alpha-olefin monomer into the loop reactor (1); introducing a polymerisation catalyst into the loop reactor (1); polymerising the at least one alpha-olefin monomer in the presence of the polymerisation catalyst in the loop reactor (1) to produce a slurry comprising polyolefin particles; withdrawing an outlet stream (4) comprising at least a portion of the slurry from the loop reactor (1); adding a first feed stream (9) comprising the at least one alpha-olefin monomer and/or hydrogen to the outlet stream (4) to form a concentrator inlet stream (8); introducing the concentrator inlet stream (8) into a concentrator (5); withdrawing from the concentrator (5) an overflow stream (6) comprising the polyolefin particles, wherein the concentration of the polyolefin particles in the overflow stream (6) is smaller than in the concentrator inlet stream (8); withdrawing from the concentrator (5) a bottom outlet stream (12) comprising the polyolefin particles, wherein the concentration of the polyolefin particles in the bottom outlet stream (12) is greater than in the concentrator inlet stream (8); returning the overflow stream (6) into the loop reactor (1) in an area different from that from which the outlet stream (4) is withdrawn.
Abstract:
A process for the preparation of polyethylene by polymerizing in a slurry ethylene and optionally one or more C3 to C10 alpha-olefins in a reactor system comprising a polymerization reactor and one or more first heat exchangers located outside the polymerization reactor where the slurry in the polymerization reactor is cooled by withdrawing slurry from the polymerization reactor, cooling the slurry in the one or more first heat exchangers and returning the cooled slurry to the polymerization reactor, wherein the one or more first heat exchangers are cooled by a first coolant having a temperature of 29° C. or higher.