公开(公告)号：US11912886B2

公开(公告)日：2024-02-27

申请号：US16964463

申请日：2020-01-30

Applicant: Colorado State University Research Foundation

Inventor： Ryan Michael Pearson ,  Matthew David Ryan ,  Garret Miyake

IPC: C09D133/10 ,  C09D155/00 ,  C09D7/61 ,  C09D7/41 ,  C09D4/00 ,  C09D5/00 ,  C09D175/14 ,  C09D181/02 ,  G02B1/00 ,  B29D11/00 ,  C08F299/04 ,  C09D153/00

CPC classification number: C09D155/005 ,  B29D11/00865 ,  C08F299/0485 ,  C09D4/00 ,  C09D5/002 ,  C09D7/41 ,  C09D7/61 ,  C09D133/10 ,  C09D153/00 ,  C09D175/14 ,  C09D181/02 ,  G02B1/005 ,  Y10T428/2848

Abstract: Polymer composite photonic crystal materials are disclosed as coatings and topcoats which have high reflection (>30%) in a specific range of the electromagnetic spectrum, such as ultraviolet (

公开(公告)号：US20150252157A1

公开(公告)日：2015-09-10

申请号：US14433202

申请日：2013-09-27

Applicant: DAI NIPPON PRINTING CO., LTD.

Inventor： Michihiro Ogura ,  Tomoki Murata ,  Yoshinobu Omori ,  Naonobu Yoshi ,  Mikiko Hojo ,  Masanori Sawada ,  Shigehiro Ueno ,  Shinsuke Nagino

IPC: C08J5/18 ,  C08K3/22 ,  C08K3/30 ,  C08K3/08

CPC classification number: C08J5/18 ,  B22F1/0022 ,  B22F7/04 ,  B22F2007/047 ,  C08F8/44 ,  C08F265/06 ,  C08F290/046 ,  C08F290/062 ,  C08K3/08 ,  C08K3/22 ,  C08K3/2279 ,  C08K3/30 ,  C08K2003/0806 ,  C08K2003/2227 ,  C08K2003/2231 ,  C08K2003/3009 ,  C08L55/005 ,  C09D155/005 ,  H01B1/22 ,  C08F220/34

Abstract: The present invention is to provide a metal particle dispersion which has low viscosity and excellent dispersibility and dispersion stability, and in which the precipitation of the metal particles is inhibited. Disclosed is a metal particle dispersion comprising metal particles, a dispersant and a solvent, wherein the metal particles contain one or more selected from the group consisting of gold, silver, copper, nickel, platinum, palladium, molybdenum, aluminum, antimony, tin, chromium, lanthanum, indium, gallium and germanium, and wherein the dispersant is a graft copolymer having at least one constitutional unit represented by the following general formula (I) and at least one constitutional unit represented by the following general formula (II), and in which at least part of nitrogen sites of the constitutional units represented by the general formula (I) each form a salt with at least one selected from the group consisting of a halogenated hydrocarbon, an acidic phosphorus compound represented by the following general formula (V), and a sulfonic acid compound represented by the following general formula (VI): (symbols shown in the general formulae (I), (II), (V) and (VI) are as described in the Description.)

Abstract translation: 本发明提供一种金属颗粒分散体，其具有低粘度和优异的分散性和分散稳定性，并且其中金属颗粒的沉淀被抑制。 公开了包含金属颗粒，分散剂和溶剂的金属颗粒分散体，其中金属颗粒含有选自金，银，铜，镍，铂，钯，钼，铝，锑，锡， 铬，镧，铟，镓和锗，并且其中所述分散剂是具有至少一个由以下通式（I）表示的结构单元和至少一个由以下通式（II）表示的结构单元的接枝共聚物，以及 其中由通式（I）表示的结构单元的至少一部分氮位与各自与选自卤代烃，由以下通式表示的酸性磷化合物（V ）和由以下通式（VI）表示的磺酸化合物：（通式（I），（II），（V）和（VI）中所示的符号如上所述） 在说明中。）

公开(公告)号：US20100068386A1

公开(公告)日：2010-03-18

申请号：US12441727

申请日：2007-10-01

Applicant: Shinya Kanbe ,  Takayuki Maki ,  Yousuke Asai ,  Morikatsu Matsunaga ,  Yoshio Mori

Inventor： Shinya Kanbe ,  Takayuki Maki ,  Yousuke Asai ,  Morikatsu Matsunaga ,  Yoshio Mori

IPC: C09D11/10 ,  B05D5/00

CPC classification number: B41M7/0054 ,  B41M5/5254 ,  B41M5/529 ,  C08F290/068 ,  C09D11/322 ,  C09D11/54 ,  C09D155/005

Abstract: The object of the invention is to provide an aqueous coating agent which I applied onto a recording medium in the ink-jet system to form a film excellent in scratch resistance, water resistance and gloss on the surface of an image, and an aqueous coating solution containing this aqueous coating agent. The means for solving is an aqueous coating agent for pigment ink-jet, which is characterized by comprising a graft copolymer that has a silicone-based side chain, and an ethylenically unsaturated carboxylic acid-containing monomer as an essential constituent in a main chain, and has an acid value in the range from 40 to 200 mg-KOH/g (solid) and a weight-average molecular weight in the range from 5,000 to 30,000; and an aqueous coating solution for pigment ink-jet comprising the aqueous coating agent which is characterized in that the aqueous coating solution is charged into a tank different from a tank for pigment ink, and is ejected and applied onto a recorded material from a nozzle different from a nozzle for pigment ink in ink-jet system.

Abstract translation: 本发明的目的是提供一种在喷墨系统中施加到记录介质上以形成图像表面上的耐刮擦性，耐水性和光泽优异的水性涂料，以及水性涂布溶液 含有该水性涂料。 用于解决的方法是用于颜料喷墨的水性涂料，其特征在于包含具有硅酮侧链的接枝共聚物和在主链中作为必需成分的含烯属不饱和羧酸的单体， 并且具有在40至200mg-KOH / g（固体）范围内的酸值和5,000至30,000的重均分子量; 以及含有水性涂布剂的颜料喷墨用水性涂布液，其特征在于，将所述水性涂布液装入与颜料墨水用容器不同的槽中，并将其从不同的喷嘴喷射到记录材料上 从喷墨系统中的颜料墨水喷嘴。

公开(公告)号：US06794475B1

公开(公告)日：2004-09-21

申请号：US09609077

申请日：2000-06-30

Applicant: Julie Vaughn Bialke ,  John B. Canady ,  Shui-Jen Raymond Hsu ,  Alexander V. Lubnin ,  William F. Masler, III ,  Beth A. Valentino

Inventor： Julie Vaughn Bialke ,  John B. Canady ,  Shui-Jen Raymond Hsu ,  Alexander V. Lubnin ,  William F. Masler, III ,  Beth A. Valentino

IPC: C08F22068

CPC classification number: C09D155/005 ,  C08F290/062

Abstract: This invention relates to latex polymers and blends of such latex polymers used to produce articles having superior electrostatic dissipative properties. The polymers and blends comprise one or more (1) polymers, in latex, or dispersion form, of (a) at least one reactive macromer of at least one alkylene oxide having at least one functional group capable of free-radical transformation, (b) optionally, at least one ethylenically unsaturated monomer having at least one carboxylic acid group, and (c) optionally, one or more free radically polymerizable comonomers, and (2) one or more other polymer latexes or dispersions of such polymers as natural rubber, conjugated-diene-containing polymers, hydrogenated styrene-butadiene triblock copolymers, chlorosulfonated polyethylenes, ethylene copolymers, acrylic and/or methacrylic ester copolymers, vinyl chloride copolymers, vinylidene chloride copolymers, polyisobutylenes, polyurethanes, polyureas, and poly-urethane-urea)s.

Abstract translation: 本发明涉及用于制备具有优异的静电耗散性能的物品的胶乳聚合物和这种胶乳聚合物的共混物。 聚合物和共混物包含一种或多种（1）聚合物，胶乳或分散体形式，（a）至少一种至少一种具有至少一个能够进行自由基转化的官能团的环氧烷的反应性大分子单体，（b ）任选的至少一种具有至少一个羧酸基团的烯键式不饱和单体，和（c）任选的一种或多种可自由基聚合的共聚单体，和（2）一种或多种其它聚合物胶乳或天然橡胶， 含共轭二烯的聚合物，氢化苯乙烯 - 丁二烯三嵌段共聚物，氯磺化聚乙烯，乙烯共聚物，丙烯酸和/或甲基丙烯酸酯共聚物，氯乙烯共聚物，偏二氯乙烯共聚物，聚异丁烯，聚氨酯，聚脲和聚氨酯脲） 。

公开(公告)号：US5856408A

公开(公告)日：1999-01-05

申请号：US803581

申请日：1997-02-20

Applicant: Yoshiaki Matsukura ,  Atsuhiro Sakai ,  Hitoshi Taniguchi ,  Yoshiaki Kawamura

Inventor： Yoshiaki Matsukura ,  Atsuhiro Sakai ,  Hitoshi Taniguchi ,  Yoshiaki Kawamura

IPC: C08F290/04 ,  C08L55/00 ,  C09D155/00 ,  C08F285/00

CPC classification number: C09D155/005 ,  C08F290/046 ,  C08L55/005

Abstract: Provided are aqueous paints with which paint films which have excellent paint film properties such as water resistance and resistance to chemical attack, and excellent finished appearance are obtained, and which have excellent painting operability and storage stability. The invention further provides water dispersible acrylic based graft copolymers, aqueous paints incorporating same and a method to make such paints, wherein an unsaturated bond-containing acrylic based copolymer (a) obtained by reacting an acrylic based copolymer (a1) of acid value 35-120 mg.KOH/gram, hydroxy group value 50-150 mg.KOH/gram, glass transition temperature -20.degree.-+50.degree. C. and number average molecular weight 4500-9000 and an unsaturated monomer mixture (a2), which has functional groups which can react with hydroxy groups, in a mol ratio of a2/a1=0.4-1.5, and a monomer composition (b) compounded in such a way that the acid value is not more than 15 and the hydroxy group value is 50-150 are reacted in the proportions by weight of a/b=10/90-60/40 to produce the claimed water dispersible acrylic based graft copolymer.

Abstract translation: 本发明提供了具有耐水性，耐化学腐蚀性等优异的涂膜特性，外观优异的油漆膜的水性涂料，其涂装操作性和贮存稳定性优异。 本发明还提供了水分散性丙烯酸系接枝共聚物，含有它的水性涂料和制造这种涂料的方法，其中通过使酸值为35〜35的丙烯酸系共聚物（a1） 120mgKOH /克，羟基值50-150mg.KOH /克，玻璃化转变温度-20℃〜50℃，数均分子量4500-9000，不饱和单体混合物（a2），其具有 可以以a2 / a1 = 0.4-1.5的摩尔比与羟基反应的官能团和单体组合物（b）以使酸值不超过15并且羟基值为50的方式复合 -150以a / b = 10 / 90-60 / 40的重量比反应，以产生要求保护的水分散性丙烯酸基接枝共聚物。

公开(公告)号：US5530070A

公开(公告)日：1996-06-25

申请号：US519837

申请日：1995-08-25

Applicant: Joseph A. Antonelli ,  Lee A. E. Becton ,  Brian P. Devlin ,  Christopher Scopazzi

Inventor： Joseph A. Antonelli ,  Lee A. E. Becton ,  Brian P. Devlin ,  Christopher Scopazzi

IPC: C08F2/38 ,  C08F8/40 ,  C08F290/04 ,  C09D5/00 ,  C09D7/12 ,  C09D17/00 ,  C09D155/00 ,  C08F265/04 ,  C08F265/06 ,  C08F283/10

CPC classification number: C08F290/04 ,  C09D155/005

Abstract: A graft copolymer dispersant (binder) having a weight average molecular weight of about 5,000-100,000 wherein: (1) the graft copolymer has a polymeric backbone formed by polymerizing ethylenically unsaturated monomers; (2) the graft copolymer has macromonomer side chains attached to the backbone at a single terminal point that have weight average molecular weights of about 1,000-30,000 and are formed from by polymerizing ethylenically unsaturated monomers in the presence of a cobalt chain transfer agent. The graft copolymer further contains about 2 to 70% by weight, based on the weight of the graft copolymer, of polymerized constituents having a phosphate moiety or phosphoric acid moleties that are polymerized into the backbone, the side chains, or both. The graft copolymer is neutralized with an inorganic base or an amine.

Abstract translation: 一种重均分子量约5,000-100,000的接枝共聚物分散剂（粘合剂），其中：（1）接枝共聚物具有通过聚合烯属不饱和单体形成的聚合物主链; （2）接枝共聚物具有在单末点连接主链的大分子单体侧链，其重均分子量约为1,000-3,000，并且由在钴链转移剂存在下聚合烯属不饱和单体形成。 基于接枝共聚物的重量，接枝共聚物还含有约2-70重量％的聚合成主链，侧链或二者的磷酸酯部分或磷酸汽车的聚合成分。 用无机碱或胺中和接枝共聚物。

公开(公告)号：US5502113A

公开(公告)日：1996-03-26

申请号：US294002

申请日：1994-08-22

Applicant: Joseph A. Antonelli ,  Lee A. E. Becton ,  Brian P. Devlin ,  Christopher Scopazzi

Inventor： Joseph A. Antonelli ,  Lee A. E. Becton ,  Brian P. Devlin ,  Christopher Scopazzi

IPC: C08F2/38 ,  C08F8/40 ,  C08F290/04 ,  C09D5/00 ,  C09D7/12 ,  C09D17/00 ,  C09D155/00 ,  C08L33/08 ,  C08L33/12 ,  C08L33/14 ,  C08L63/10

CPC classification number: C08F290/04 ,  C09D155/005

Abstract: A pigment dispersion useful for forming aqueous coating compositions containing metallic flake pigment, an aqueous carrier and a graft copolymer dispersant (binder);wherein the graft copolymer has a weight average molecular weight of about 5,000-100,000 and comprises a polymeric backbone and macromonomer side chains attached to the backbone wherein(1) the polymeric backbone is formed of polymerized ethylenically unsaturated monomers and(2) the side chains are macromonomers that are attached to the backbone at a single terminal point and formed from polymerized ethylenically unsaturated monomers that are polymerized in the presence of a cobalt chain transfer agent have a weight average molecular weight of about 1,000-30,000;wherein the graft copolymer contains about 2 to 70% by weight, based on the weight of the graft copolymer, of polymerized constituents having a phosphate moiety and phosphoric acid moieties that are polymerized into the backbone, the side chains or both and the polymer is neutralized with an inorganic base or an amine; andthe metallic flake pigment is present in a binder to pigment weight ratio of least 10/100;coating compositions containing the novel dispersion, the graft copolymer and the process for making the graft copolymer and pigment dispersions are part of the invention.

Abstract translation: 用于形成含有金属薄片颜料，水性载体和接枝共聚物分散剂（粘合剂）的水性涂料组合物的颜料分散体; 其中所述接枝共聚物的重均分子量为约5,000-100,000，并且包含连接于主链的聚合物主链和大分子单体侧链，其中（1）聚合物主链由聚合的烯属不饱和单体形成，和（2）侧链是 在单链末端附着于骨架并由在钴链转移剂存在下聚合的聚合的烯键式不饱和单体形成的大分子单体的重均分子量为约1,000-3,000; 其中所述接枝共聚物含有约2-70重量％，基于接枝共聚物的重量，聚合成聚磷酸酯部分的聚合组分和聚合成骨架的磷酸部分，侧链或两者，聚合物被中和 与无机碱或胺反应; 并且金属薄片颜料以粘合剂存在至颜料重量比至少为10/100; 包含新型分散体，接枝共聚物和制备接枝共聚物和颜料分散体的方法的涂料组合物是本发明的一部分。

公开(公告)号：US5436279A

公开(公告)日：1995-07-25

申请号：US189971

申请日：1994-02-01

Applicant: Ulrich Grundke ,  Klaus-Peter Liebetanz ,  Achim Hansen ,  Jurgen Zehrfeld ,  Rainer Scharre ,  Werner Peters

Inventor： Ulrich Grundke ,  Klaus-Peter Liebetanz ,  Achim Hansen ,  Jurgen Zehrfeld ,  Rainer Scharre ,  Werner Peters

IPC: C08F2/50 ,  C08F290/00 ,  C08F299/02 ,  C08F299/06 ,  C08G18/58 ,  C08G18/81 ,  C08J7/04 ,  C08L63/10 ,  C09D4/00 ,  C09D155/00 ,  C09D163/10 ,  C09D175/00 ,  C09D175/14 ,  G03F7/038 ,  H05K3/28 ,  C08K3/18 ,  C08K3/36

CPC classification number: G03F7/0388 ,  C08F299/028 ,  C08F299/065 ,  C08G18/581 ,  C08G18/8175 ,  C08L63/10 ,  C09D155/005 ,  H05K3/287

Abstract: A coating material crosslinkable by radiation comprising a) an olefinic unsaturated ester of an epoxy novolac resin, b) a binder formed by reaction of an epoxy compound having more than one epoxide group per molecule with at least one carboxylic acid in a molar ratio of epoxy groups per carboxyl group of 1:0.5 to 0.9 and subsequent reaction of the resulting reaction product with at least one unsaturated isocyanate ester formed by reaction of a compound with at least two isocyanate groups with a member of the group consisting of hydroxyl containing acrylic acid, methacrylic acid and cyanacrylic acid esters, c) at least one latent hardener, d) at least one photoinitiator e) 80-120% by weight of fillers and (f) additives, adjuvants and solvents and protective films formed with them.

Abstract translation: 可通过辐射交联的涂料，其包含：a）环氧酚醛清漆树脂的烯属不饱和酯，b）通过每分子具有多于一个环氧基团的环氧化合物与至少一种羧酸以环氧树脂的摩尔比反应形成的粘合剂 每个羧基的基团为1：0.5至0.9，随后将所得反应产物与至少一种不饱和异氰酸酯进行反应，所述不饱和异氰酸酯通过化合物与至少两个异氰酸酯基团反应形成，所述不饱和异氰酸酯酯与由含羟基的丙烯酸， 甲基丙烯酸和氰基丙烯酸酯，c）至少一种潜在硬化剂，d）至少一种光引发剂e）80-120重量％的填料和（f）添加剂，助剂和溶剂以及与它们形成的保护膜。

公开(公告)号：US5147946A

公开(公告)日：1992-09-15

申请号：US667140

申请日：1991-03-11

Applicant: Kou-Chang Liu

Inventor： Kou-Chang Liu

IPC: C08F290/06 ,  C09D155/00

CPC classification number: C09D155/005 ,  C08F290/068

Abstract: This invention relates to a copolymeric film forming and release coating comprising as active monomeric components between about 15 and about 40 weight percent of a cyclic polyvinyl compound of the formula: ##STR1## and between about 60 and about 85 weight % of a hydroxy containing vinyl ether siloxane of the formula ##STR2## wherein A is a saturated or unsaturated cyclic moiety having a 5 to 8 membered ring; n has a value of from 3 to 8; X and X' are each individually oxygen, sulfur, or NR where R is hydrogen or lower alkyl; B is alkylene having from 2 to 20 carbon atoms or a C.sub.2 to C.sub.3 alkoxylated derivatives thereof; R.sub.1 and R.sub.2 are lower alkyl; t has a value of from 1 to 100; ##STR3## where Y is alkylene or alkylenephenylene optionally substituted with fluorine; m has a value of from 1 to 10; U is halo or loweralkyl; v has a value of from 0 to 4; M is --CH.sub.2 -- or ##STR4## q has a value of from 0 to 20; Z is C.sub.2 to C.sub.3 alkylene; r has a value of from 0 to 20; D is alkylene or alkylenephenylene and R.sub.3 is the same as T or is C.sub.1 to C.sub.20 alkyl. The invention also relates to the use of the above copolymers and to the copolymerizable composition.

Abstract translation: 本发明涉及一种共聚物成膜和释放涂层，其包含作为活性单体组分的约15至约40重量％的下式的环状聚乙烯基化合物：＆lt; IMAGE＆gt;和约60-约85重量％的含羟基的乙烯基 醚式硅氧烷，其中A是具有5至8元环的饱和或不饱和环状部分; n的值为3到8; X和X'分别是氧，硫或NR，其中R是氢或低级烷基; B是具有2至20个碳原子的亚烷基或其C2-C3烷氧基化衍生物; R1和R2是低级烷基; t的值为1到100; T是CH 2 CHO（YO）mCH 2 CH（OH）CH 2 O + TR＆lt; IMAGE＆gt;其中Y是任选被氟取代的亚烷基或亚烷基亚苯基; m的值为1〜10; U是卤素或低级烷基; v的值为0到4; M是-CH2-或 q具有0至20的值; Z是C 2至C 3亚烷基; r的值为0〜20; D是亚烷基或亚烷基亚苯基，R3与T相同或是C1-C20烷基。 本发明还涉及上述共聚物和可共聚组合物的用途。

公开(公告)号：US4673718A

公开(公告)日：1987-06-16

申请号：US816485

申请日：1986-01-06

Applicant: Rose A. Ryntz ,  Kenneth R. Kurple

Inventor： Rose A. Ryntz ,  Kenneth R. Kurple

IPC: C08F290/06 ,  C08F290/14 ,  C08G18/46 ,  C08G18/63 ,  C09D155/00 ,  C08F283/00

CPC classification number: C08G18/635 ,  C08F290/068 ,  C08F290/148 ,  C08G18/4692 ,  C09D155/005

Abstract: Hydroxy functional polysiloxane graft copolymers are provided. The copolymer is crosslinkable by hydroxy-reactive crosslinking agent and, in particular, is suitable for use in thermosetting coating compositions adapted to form a flexible cured coating over a variety of substrates, such as metal and plastic. The copolymer has a number average molecular weight between about 1000 and about 15,000, has a hydroxyl number between about 30 and about 300, and is the reaction product of carbon-carbon double bond-reactive monoethylenically unsaturated monomer with hydroxy functional carbon-carbon double bond-bearing branched polysiloxane macromer. The macromer is the reaction product of (i) epoxy monomer having the formula: ##STR1## with (ii) hydroxy functional polysiloxane reactant containing 0-10 urethane linkages per molecule.