公开(公告)号：US06541068B1

公开(公告)日：2003-04-01

申请号：US09601395

申请日：2000-09-12

Applicant: Leonid Semenovich Galbraikh ,  Nina Sergeevna Zubkova ,  Nataliya Grigorievna Butylkina ,  Alexandr Alexandrovich Berlin ,  Nikolai Alexandrovich Khalturinsky

Inventor： Leonid Semenovich Galbraikh ,  Nina Sergeevna Zubkova ,  Nataliya Grigorievna Butylkina ,  Alexandr Alexandrovich Berlin ,  Nikolai Alexandrovich Khalturinsky

IPC: D06M13364

CPC classification number: C09D161/28 ,  D06M13/425 ,  D06M13/447 ,  D06M15/423 ,  D06M15/432 ,  D06M15/643 ,  D06M15/6436 ,  D06M15/693 ,  D06M2200/30

Abstract: A process is proposed for the fireproofing treatment of textile materials by impregnating them initially with a melamine-formaldehyde resin or organosilicon substances, and then with a solution of a complex compound of the ammonia salt of amidoalkylphosphonic acid with ammonium chloride. Materials treated in accordance with the invention have reduced combustibility and low toxicity of the gases given off during combustion.

Abstract translation: 提出了一种通过先用三聚氰胺 - 甲醛树脂或有机硅物质浸渍纺织材料进行防火处理的方法，然后用酰氨基烷基膦酸的氨盐与氯化铵的络合物的溶液进行浸渍。 根据本发明处理的材料在燃烧期间释放的气体的可燃性和低毒性降低。

公开(公告)号：US5320785A

公开(公告)日：1994-06-14

申请号：US736679

申请日：1991-07-26

Applicant: Salman Dermeik

Inventor： Salman Dermeik

IPC: C07F9/38 ,  C09K21/12 ,  D06M13/02 ,  D06M13/184 ,  D06M13/188 ,  D06M13/192 ,  D06M13/203 ,  D06M13/244 ,  D06M13/322 ,  D06M13/35 ,  D06M13/355 ,  D06M13/358 ,  D06M13/402 ,  D06M13/432 ,  D06M13/447 ,  D06M15/432 ,  D06M101/00 ,  D06M101/02 ,  D06M101/06 ,  D06M101/08 ,  C09K21/10 ,  D06M13/00

CPC classification number: D06M13/192 ,  D06M13/447 ,  D06M15/432

Abstract: The permanence of the flame-resistant finish of fibre materials, in particular those based on cellulose, is improved if a phosphono compound which contains an N-methylol group. is used together with an organic carboxylic acid as the finishing agent. If oxalic acid in particular is used as the carboxylic acid, the finished fibre material can be stored in a damp environment for a prolonged period of time without intermediate washing being necessary. The tendency of the finish to hydrolyse in a damp atmosphere is reduced by using the organic carboxylic acid instead of a mineral acid.

Abstract translation: 如果含有N-羟甲基的膦酰基化合物，纤维材料的阻燃整理剂，特别是基于纤维素的耐火漆的耐久性得到改善。 与有机羧酸一起用作整理剂。 如果特别使用草酸作为羧酸，则成品纤维材料可以在潮湿环境中长时间储存​​，而不需要中间洗涤。 通过使用有机羧酸代替无机酸，降低了在潮湿气氛中水解的趋势。

公开(公告)号：US4063883A

公开(公告)日：1977-12-20

申请号：US604489

申请日：1975-08-14

Applicant: Johann Hupfl ,  Manfred Czermak ,  Helmut Teichmann ,  Josef Paul

Inventor： Johann Hupfl ,  Manfred Czermak ,  Helmut Teichmann ,  Josef Paul

IPC: C08K3/32 ,  C08K5/00 ,  D01F2/10 ,  D01F11/02 ,  D06M11/68 ,  D06M11/70 ,  D06M13/285 ,  D06M13/292 ,  D06M13/44 ,  D06M15/431 ,  D06M15/432 ,  D06M15/673 ,  D01F2/08

CPC classification number: D06M15/673 ,  C08K3/32 ,  C08K5/0066 ,  C08K5/49 ,  D01F2/10 ,  D06M11/68 ,  D06M11/70 ,  D06M13/285 ,  D06M13/292 ,  D06M15/431 ,  D06M15/432

Abstract: Manufacture of flame-retardant regenerated cellulose fibres by adding one or more flame-retardant phosphorus comounds to viscose, extruding the viscose-containing mixture thus obtained into a spinning bath, stretching and after treating the resulting filaments or staple fibres. The flame-retardant fibres are made by using as the flame-retardant agent a combination of compounds of the general formula:PN.sub.x O.sub.yin which x stands for a number between 0.09 and 1.7 and y stands for a number between 1.2 and 0, preferably approaching zero as the values of x increase towards 1.7 (component A), with compounds which are selected from phosphoric acid alkylesters, preferably halogen-containing phosphoric acid alkylesters; cyclophosphazenes, polyphosphazenes; tetrakis-(oxymethyl)-phosphonium chloride or hydroxide or its condensation products with ammonia, oxymethylamine, urea or other amines or amides, vinyl compounds containing halogen, phosphonitrogen or phosphorus; and tris-(1-aziridinyl)-phosphine oxide or N-(oxymethyl)-3-phosphonopropionamide, if desired in further combination with a condensation resin (component B).

Abstract translation: 通过向粘胶加入一种或多种阻燃磷化合物制造阻燃再生纤维素纤维，将由此获得的含粘胶混合物挤出到纺丝浴中，拉伸和处理所得到的长丝或短纤维。 阻燃纤维是通过使用以下通式的化合物作为阻燃剂来制备的：

公开(公告)号：US3647734A

公开(公告)日：1972-03-07

申请号：US3647734D

申请日：1970-03-26

Applicant: LOWENSTEIN & SONS M

Inventor： HARDWICKE JAMES E ,  SCHEFFLER BERNARD ,  WEISZ HERMAN S

IPC: D06M15/432 ,  C08G51/24 ,  C08G37/32

CPC classification number: D06M15/432

Abstract: A COMPOSITION FOR RENDERING COLLULOSIC MATERIAL FLAME RETARTDANT IS PREPARED BY MAINTAINING THE INTERMEDIATE REACTION PROUCT 3-(DI-ISOPROPYLPHOSPHONO) PROPRIONAMIDE IN AQUEOUS SOLUTION BELOW ITS MELTING POINT FOR METHYLOLATION WITH FORMALDEHYDE TO FORM THE N-HYDROXYMETHYL DERIVATIVE, AND THEN FORMULATING THIS DERIVATIVE WITH AN AQUEOUS METHYOLMELAMINE RESIN SOLUTION AND AN ACID CATALYST FOR PAD-DRY-CURE APPLICATION TO THE CELLULOSIC MATERIAL. CELLULOSIC MATERIAL TREATED WITH THE RESULTING COMPOSITION IS RENDERED SELF-EXTINGUISHING AND RETANS THIS CHARACTERISTIC AFTER FIFTY WASHINGS.

公开(公告)号：US4370442A

公开(公告)日：1983-01-25

申请号：US214017

申请日：1980-12-05

Applicant: Glenn A. Pearson

Inventor： Glenn A. Pearson

IPC: C08G12/40 ,  D06M15/432 ,  C08L61/20

CPC classification number: D06M15/432 ,  C08G12/40

Abstract: A method of preparing an aqueous resinous system, and the resinous system produced by the method is described wherein about 75-100 parts of an aldehyde such as formaldehyde, about 100-125 parts of phosphoric acid, about 15-25 parts of an alkanolamine such as triethanolamine, about 30-50 parts of urea, and about 20-40 parts of melamine, based on 100-200 parts of water, are reacted to provide an aqueous resinous solution which will cure at room temperature or upon application of heat, permitting its use as a flexible, pliable, waterproof, nonburning coating, especially for textiles and paper containing materials. The solution may be applied by impregnation or as a coating to the fabric or an underlayer to the fabric. In a special embodiment, there is provided a method for providing fire retardancy to a textile fabric applied over an underlayer such as muslin, by applying a fire retardant solution to the underlayer. There is also provided a fire retardant spray solution.

Abstract translation: 描述了一种制备水性树脂体系的方法和通过该方法制备的树脂体系，其中约75-100份醛如甲醛，约100-125份磷酸，约15-25份链烷醇胺如 作为三乙醇胺，约30-50份尿素和约20-40份三聚氰胺（基于100-200份水）反应，以提供在室温或加热下固化的水性树脂溶液，允许 其用作柔性，柔韧，防水，不燃涂层，特别适用于纺织和含纸材料。 溶液可以通过浸渍或作为涂层施加到织物或底层到织物上。 在一个特殊的实施方案中，提供了一种通过将阻燃溶液施加到底层上来为施加在诸如细棉布的底层上的织物提供阻燃性的方法。 还提供了阻燃喷雾溶液。

公开(公告)号：US4280812A

公开(公告)日：1981-07-28

申请号：US132594

申请日：1980-03-21

Applicant: Darrell J. Donaldson ,  Robert J. Harper, Jr.

Inventor： Darrell J. Donaldson ,  Robert J. Harper, Jr.

IPC: D06M11/82 ,  D06M15/432 ,  D06M1/00

CPC classification number: D06M15/432 ,  D06M11/82

Abstract: Smolder resistance is imparted to cotton and cotton-containing fabrics by applying a certain boron-nitrogen-phosphorus system to the fabric, employing conventional equipment. An inorganic boron compound is placed in solution with a phosphorus-containing compound, then a nitrogen-containing compound is added. The aqueous mixture is applied using conventional textile equipment, dried, and cured by standard methods.

Abstract translation: 使用常规设备，通过向织物施加一定的硼 - 氮 - 磷体系，对棉和含棉织物施加锑阻力。 将无机硼化合物与含磷化合物一起放入溶液中，然后加入含氮化合物。 使用常规纺织设备施加含水混合物，干燥并通过标准方法固化。

公开(公告)号：US4028053A

公开(公告)日：1977-06-07

申请号：US550295

申请日：1975-02-18

Applicant: Marshall W. Duke

Inventor： Marshall W. Duke

IPC: D06M15/432 ,  D06M1/00

CPC classification number: D06M15/432 ,  Y10S428/921

Abstract: A process for rendering cellulose and cellulose containing fabrics fire resistant by first impregnating the fibers with a solution of an aminoplast resin, an acid and an effective amount of a dialkyl phosphono methylol alkylamide to produce fire retardancy in the resulting fabric having the formula ##STR1## wherein R is lower alkyl having 1 to 6 carbon atoms and x is an integer from 1 to 3 and polymerizing the resin while the fibers are wet and swollen. The fabric is then cured, washed and dried. The fabric obtained from this process possesses high fire-retardancy values, soft hand, and tensile values similar to that of the untreated fabric.

Abstract translation: 通过首先用氨基塑料树脂，酸和有效量的二烷基膦酰羟甲基烷基酰胺浸渍纤维来使纤维素和含纤维素的织物呈现耐火性的方法，以在具有下式的所得织物中产生阻燃性： （I）其中R是具有1至6个碳原子的低级烷基，x是1至3的整数，并且在纤维湿润和溶胀时使树脂聚合。 然后将织物固化，洗涤和干燥。 从该方法获得的织物具有与未处理织物相似的高阻燃性值，柔软的手感和拉伸值。

公开(公告)号：US3832227A

公开(公告)日：1974-08-27

申请号：US29397372

申请日：1972-10-02

Applicant: STAUFFER CHEMICAL CO

Inventor： WEIL E ,  FEARING R

IPC: C07F9/6521 ,  C08G12/40 ,  C08G59/40 ,  D06M13/288 ,  D06M15/432 ,  C09D5/18

CPC classification number: C08G59/4071 ,  C07F9/65217 ,  C08G12/40 ,  D06M13/288 ,  D06M15/432

Abstract: A PROCESS FOR THE FLAMEPROOFING OF TEXTILES BY TREATING THE TEXTILE WITH A NOVEL CLASS OF TRIAZINYLAMINOALKYL PHOSPHONATES AND THE CROSSLINKING OF THE PHOSPHONATES TO YIELD A FIRE RETARDANT FINISHED FOR THE TEXTILE IS DISCLOSED. THESE TRIAZINYLAMINOALKYL PHOSPHONATES ARE FOUND TO BE LOW IN COST AND OF MINIMAL TOXICITY AND THEIR USE OF THE FLAMEPROOFING OF TEXTILES PROVIDES HIGHLY DURABLE FINISHES.

公开(公告)号：US3746572A

公开(公告)日：1973-07-17

申请号：US3746572D

申请日：1971-02-23

Applicant: STAUFFER CHEMICAL CO

Inventor： WEIL E ,  FEARING R ,  EISENBERG B

IPC: D06M15/432 ,  C09D5/18

CPC classification number: D06M15/432 ,  Y10S428/921 ,  Y10T442/268

Abstract: THE PRESENT INVENTION A PROCESS FOR FLAME RETARDING TEXTILES WHICH COMPRISES: (1) APPLYING TO A TEXTILE AN AQUEOUS SOLUTION CONSISTING OF (A) A PHOSPHONATE HAVING AT LEAST ONE CARBON-BONDED PRIMARY ALCOHOL GROUP, (B) DIMETHYLOLDIHYDROXYETHYLENE UREA, AND (C) A CURING CATALYST; AND (2) CURING THE PHOSPHONATE AND UREA ON THE TEXTILE AND THEREBY RENDERING THE TEXTILE FLAME RETARDANT.

公开(公告)号：US20170152379A1

公开(公告)日：2017-06-01

申请号：US15320519

申请日：2015-06-10

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Michael D. Kelly

IPC: C08L61/24 ,  D06M15/432 ,  D04H1/587 ,  D04H1/64 ,  C08F220/18 ,  D04H1/4218

CPC classification number: C08L61/24 ,  C08F2/001 ,  C08F2/24 ,  C08F2/26 ,  C08F30/02 ,  C08F36/20 ,  C08F220/18 ,  C08F290/00 ,  C08F2220/1825 ,  C08L43/02 ,  C08L61/06 ,  C08L2201/52 ,  C08L2201/54 ,  C09J161/24 ,  D04H1/4218 ,  D04H1/587 ,  D04H1/64 ,  D06M15/432 ,  D10B2101/06 ,  C08F212/08 ,  C08F220/06 ,  C08F212/14 ,  C08F2230/085

Abstract: The present invention provides polymer modified aqueous urea formaldehyde resin (UF resin) binder compositions useful in making a treated glass mat, e.g., for roofing shingles, wherein the polymer modifier is an multistage aqueous emulsion acorn copolymer comprising one protuberant polymer stage containing phosphorous acid groups and one or more other polymer stage comprising an addition copolymer incompatible with the protuberant polymer stage, wherein the multistage aqueous emulsion copolymer has a measured Tg of from −60 to 25° C., or, preferably from 31 30 to 12° C. and, further wherein the weight ratio of the total of monomers used to make the one or more other polymer stage to the total amount of monomers used to make the protuberant polymer stage ranges from 3:1 to 50:1, or, preferably, from 3:1 to 30:1 or, more preferably, from 3:1 to 20:1, or, even more preferably, from 8:1 to 12:1.