摘要:
The invention relates to an arrangement and a method for the controlled discharge of an energy store using redox shuttle additives and to the use of redox shuttle additives for the controlled discharge of an energy store. The energy store arrangement comprises a storage container with a redox shuttle additive which is dispensed into the electrolytes of the energy store upon triggering a dispensing device such that the energy store is partly or completely discharged, wherein the redox shuttle additive is oxidized on the cathode and reduced on the anode. The redox shuttle additive has a redox potential which is less than or equal to the potential of the partially or completely discharged cathode and greater than or equal to the potential of the partially or completely discharged anode.
摘要:
A fuel cell assembly comprises a fuel cell stack (160) with at least one fuel cell (10), and a pump (50). Each fuel cell (10) includes a first gas chamber, an electrolyte chamber, and a second gas chamber, and two electrodes separating the electrolyte chamber from the gas chambers. The pump (50) is arranged to reduce the pressure of an electrolyte (40) in the electrolyte chamber to a negative pressure. This negative pressure may be adjusted in accordance with the electrical output of the fuel cell stack (160).
摘要:
According to one embodiment of the present invention, the method for controlling the pump speed of a redox flow battery for transferring an electrolyte stored in an electrolyte tank to a cell stack comprises the steps of: measuring the input power and/or the output power of the redox flow battery; measuring the charging power and/or the discharging power of the redox flow battery; calculating the power loss of the redox flow battery by using the difference between the input power and the charging power, or the difference between the output power and the discharging power; and adjusting the pump speed according to the power loss.
摘要:
One embodiment provides a method for predicting maintenance of a redox flow battery, the method including: receiving, from a plurality of sensors, data regarding characteristics of the redox flow battery; weighting, using a processor, each of the characteristics to form an estimated state parameter for the redox flow battery; and determining, using the processor, a maintenance action for the redox flow battery using the estimated state parameter. Other aspects are described and claimed.
摘要:
The present disclosure relates to an electrochemical cell comprising a fuel electrode for oxidizing a fuel, an oxidant electrode for reducing an oxidant, and an ionically conductive medium for conducting ions between the fuel and oxidant electrodes to support electrochemical reactions at the fuel and oxidant electrodes. The ionically conductive medium comprises at least one active additive for enhancing (controlling the rate, overpotential and/or the reaction sites for) at least one electrochemical reaction within the cell. The cell further comprises an additive medium in contact with the ionically conductive medium and containing the at least one active additive capable of corroding or dissolving in the ionically conductive medium. The additive medium and/or casing is configured to release the active additive to the ionically conductive medium as a concentration of the active additive in the ionically conductive medium is depleted during operation of the cell.
摘要:
A flow battery system and method are provided. The flow battery system includes first and second storage tanks initially respectively storing first and second electrolyte and a battery stack that includes a half-cell configured to charge and/or discharge a positive or negative liquid electrolyte provided from the first and second storage tanks. Electrolytes returned from the battery stack are returned with a higher SOC when the selected mode indicates a charging mode and electrolytes are returned from the battery stack with a lower SOC when the selected mode indicates a discharging mode. The flow battery system and method control a defined sequence for a selected mode of one of charging or discharging of the first and second electrolytes to charge or discharge the first electrolyte before charging or discharging the second electrolyte, based on the selected mode.
摘要:
The present invention relates to a process for operating a fuel cell, especially for operating a fuel cell in which the electrolyte responsible for the proton conduction is volatile.By means of the process according to the invention, better operation of such a fuel cell is possible, and they exhibit an improved lifetime.
摘要:
An anaerobic aluminum-water electrochemical cell that includes: a plurality of electrode stacks, each electrode stack featuring an aluminum or aluminum alloy anode, and at least one cathode configured to be electrically coupled to the anode; one or more physical separators between each electrode stack adjacent to the cathode; a housing configured to hold the electrode stacks, an electrolyte, and the physical separators; a water injection port, in the housing, configured to introduce water into the housing. The electrochemical cell also includes an amount of hydroxide base sufficient to form an electrolyte having a hydroxide base concentration of at least 0.05 M to at most 3 M when water is introduced between the anode and at least one cathode of the electrochemical cell. The aluminum or aluminum alloy of the anode is substantially free of titanium and boron.
摘要:
A flow battery having stable electrochemical performance is provided. The flow battery includes a separator disposed between a positive electrode and a negative electrode, a first flow plate to distribute a positive electrolyte to the positive electrode, and a second flow plate to distribute a negative electrolyte to the negative electrode. A material of at least one of the positive and negative electrodes is treated such that a surface area of the material when treated is greater than a surface area of the material when untreated. When the positive and negative electrolytes include vanadium ions, a concentration of vanadium in the positive electrolyte is different from a concentration of vanadium in the negative electrolyte to mitigate crossover-induced capacity fade.
摘要:
A method for measuring an electrolyte balance of a redox flow battery may include: charging the redox flow battery by applying a current to a stack; measuring temperatures of an anode electrolyte solution and a cathode electrolyte solution while the redox flow battery is charged; calculating a temperature change rate of the anode electrolyte solution over time and a temperature change rate of the cathode electrolyte solution over time; deciding a first change time corresponding to an inflection point of the temperature change rate of the anode electrolyte solution over time and a second change time corresponding to an inflection point of the temperature change rate of the cathode electrolyte solution over time; and calculating an average electrolyte oxidation number of the redox flow battery, using the first change time, the second change time, an oxidation number of the anode electrolyte and an oxidation number of the cathode electrolyte.