摘要:
A method of using select Schiff base compounds for chemical agent detoxification. The method including applying a compound to the contaminated substrate. The compound includes an imine having at least one Schiff base nitrogen and an alkyl substituent or an aryl substituent having an electron acceptor. The at least one Schiff base nitrogen is spaced away from the electron acceptor by a distance ranging from about 200 pm to about 1000 pm. The substrate and the compound are dried. The at least one Schiff base nitrogen of the compound promotes a nucleophilic attack on an electrophilic site of the toxic chemical agent.
摘要:
A method of using select Schiff base compounds for chemical agent detoxification. The method including applying a compound to the contaminated substrate. The compound includes an imine having at least one Schiff base nitrogen and an alkyl substituent or an aryl substituent having an electron acceptor. The at least one Schiff base nitrogen is spaced away from the electron acceptor by a distance ranging from about 200 pm to about 1000 pm. The substrate and the compound are dried. The at least one Schiff base nitrogen of the compound promotes a nucleophilic attack on an electrophilic site of the toxic chemical agent.
摘要:
The object of the invention is a functional protective material, especially with the function of protecting against chemical and/or biological poisons and/or noxious materials, such as combat agents, wherein the functional protective material comprises a multilayer construction. The multilayer construction has a two-dimensional backing material, especially a textile backing material and a membrane, which is assigned to the backing material and, in particular, is connected therewith. The membrane is provided with a reactive finish, especially with a component having catalytic activity preferably with respect to chemical and/or biological poisons and/or noxious matter. The adsorption filter material is suitable particularly for use in ABC protection objects (such as ABC protective clothing).
摘要:
A two step process for the destruction of a precursor material using a steam plasma in a three zone reactor wherein the precursor material is hydrolyzed as a first step in the high temperature zone of the reactor, followed by a second step of medium temperature oxidation of the reactant stream in the combustion zone of the reactor where combustion oxygen or air is injected and immediate quenching of the resulting gas stream to avoid the formation of unwanted by-products. A related apparatus includes a non transferred direct current steam plasma torch, an externally cooled three zone steam plasma reactor means for introducing the precursor material into the plasma plume of the plasma torch, means for introducing the combustion air or oxygen into the combustion zone, means for exiting the reactant mixture from the reactor and means for quenching the reactant mixture located at the exit end of the reactor.
摘要:
A method for the treatment of waste by plasma treating the waste to destroy the hazardous organic components and to yield a slag and an off-gas by plasma treating the waste in the presence of added oxygen gas in a transferred-arc plasma treatment unit, followed by directing off-gas from the plasma treatment unit to a thermal oxidizer combustion chamber.
摘要:
The present application relates to methods for the reduction of halogenated hydrocarbons using compounds of Formula (I): wherein the reduction of the halogenated compounds is carried out, for example, under ambient conditions without the need for a transition metal containing co-factor. The present application also relates to methods of recovering precious metals using compounds of Formula (I) that are absorbed onto a support material.
摘要:
This document provides methods, systems, and devices for inducing a decomposition reaction by directing x-rays towards a location including a particular compound. The x-rays can have an irradiation energy that corresponds to a bond distance of a bond in the particular compound in order to break that bond and induce a decomposition of that particular compound. In some cases, the particular compound is a hazardous substance or part of a hazardous substance. In some cases, the particular compound is delivered to a desired location in an organism and x-rays induce a decomposition reaction that creates a therapeutic substance (e.g., a toxin that kills cancer cells) in the location of the organism. In some cases, the particular compound decomposes to produce a reactant in a reactor apparatus (e.g., fuel cell or semiconductor fabricator).
摘要:
A process for the conversion of organic halide compounds, including refrigerant fluids, is provided. The process includes contacting the organic halide compound with an additive hydrogen donor at a reaction temperature, to produce a product stream that includes a hydrogen halide and carbon oxide.
摘要:
A method for dehalogenation detoxication of halogenated aromatic and/or cyclic compounds, based on the fact that at least one halogenated aromatic and/or cyclic compound is heated on a support matrix in a closed system at a temperature of 200 to 500° C. in the presence of copper in metallic form and/or in the form of copper compounds, a hydrogen donor, carbon and at least one additional reducing substance, capable of reducing cupric and cuprous ions to elemental copper at the above temperature.
摘要:
A process and apparatus are described for converting a feed that is substantially comprised of halogenated materials, and especially byproduct and waste chlorinated hydrocarbons as are produced from a variety of chemical manufacturing processes, to one or more higher value products via a partial oxidation reforming reaction step. These products can be in the form of a useful or salable acid product and/or a product synthesis gas comprised of carbon monoxide and hydrogen, or the reaction product including the same hydrogen halide, carbon monoxide and hydrogen components can be employed as a feed in the synthesis of a different useful or salable product.