摘要:
This invention relates to a catalyst for hydrorefining and/or hydroconversion of hydrocarbon-containing feedstocks that contain compounds whose boiling point is higher than 520null C. and that contain sulfur and possibly metals, as well as its use in hydrorefining and/or hydroconversion processes of heavy feedstocks. A petroleum residue of atmospheric distillation (RA) or of vacuum distillation (RSV) or a deasphalted oil (DAO) are representative feedstocks of the feedstocks treated within the scope of this invention.
摘要:
A catalyst characterized by its ability to hydrotreat a charge hydrocarbon feed containing components boiling above 1000null F., and sediment-formers, sulfur, metals, asphaltenes, carbon residue, and nitrogen is prepared by mulling a porous alumina support with a salt of a Group VIII metal oxide and with a salt of a Group VI-B metal oxide in the presence of an acid to provide a mixture, by extruding the mixture to form an extrudate, by drying the extrudate and by subjecting the dried extrudate to hydrothermal calcination to provide the catalyst.
摘要:
A guard catalyst, comprising an alumina support and molybdenum and/or tungsten and nickel and/or cobalt supported on the alumina support, wherein the total ammonia integral adsorption heat of said alumina support does not exceed 25 J/g, the percentage taken up by the ammonia integral adsorption heat of the ammonia differential adsorption heat greater than 100 kJ/mol does not exceed 10% of the total ammonia integral adsorption heat. Compared to the catalysts of the prior art, the guard catalyst has higher catalytic activity, less coke deposit, lower reduction rate of pore volume, better stability of activity, and higher strength.
摘要:
There are disclosed are a method for producing at least one compound selected from a carbonyl compound and a hydroxy adduct compound by an oxidative cleavage or addition reaction of an olefinic double bond of an olefin compound, which contains reacting an olefin compound with hydrogen peroxide, utilizing as a catalyst, at least one member selected from (a) tungsten, (b) molybdenum, or (c) a tungsten or molybdenum metal compound containing (ia) tungsten or (ib) molybdenum and (ii) an element of Group IIIb, IVb, Vb or VIb excluding oxygen, and a catalyst composition
摘要:
A catalyst contains at least one group VIII element and at least molybdenum and/or tungsten, said elements being present at least in part in the catalyst in the dry state in the form of at least one heteropolyanion with formula MxAB6O24H6C(3-2x), tH2O; MxAB6O24H6C(4-2x), tH2O; MxA2B10O38H4C(6-2x), tH2O; MxA2B10O38H4C(8-2x), tH2O; or MxA2B10O38H4C(7-2x), tH2O, in which M is cobalt and/or nickel and/or iron and/or copper and/or zinc, A is one or two elements from group VIII of the periodic table, B is molybdenum and/or tungsten and C is an Hnull ion and/or a (NR1R2R3R4)null type ammonium ion, in which R1, R2, R3 and R4, which may be identical or different, correspond either to a hydrogen atom or to an alkyl group and/or caesium and/or potassium and/or sodium, t is a number between 0 and 15 and x takes a value in the range 0 to 4 depending on the formula.
摘要翻译:催化剂含有至少一种VIII族元素和至少钼和/或钨,所述元素至少部分地以至少一种具有式MxAB6O24H6C(3-2x)的杂多阴离子的形式存在于干燥状态的催化剂中, tH2O; MxAB6O24H6C(4-2x),tH2O; MxA2B10O38H4C(6-2x),tH2O; MxA2B10O38H4C(8-2x),tH2O; 或MxA2B10O38H4C(7-2x),tH2O,其中M是钴和/或镍和/或铁和/或铜和/或锌,A是元素周期表第Ⅷ族中的一种或两种元素,B是钼和 /或钨,C是H +离子和/或(NR 1 R 2 R 3 R 4)+型铵离子,其中可以相同或不同的R 1,R 2,R 3和R 4对应于氢原子或 烷基和/或铯和/或钾和/或钠,t是0至15之间的数,x取值取决于式中的0至4。
摘要:
The invention relates to a process for removing sulfur containing compounds such as H2S and COS from a gas stream, comprising contacting the gas stream with an absorbent in a fluidized bed, which absorbent is based on at least one oxide of a first metal selected from the group consisting of Mn, Fe, Co, Ni, Cu and Zn, in combination with at least one oxide of a second metal selected from the group consisting of Cr, Mo and W on a carrier selected from the group consisting of Al2O3, TiO2, or ZrO2 or mixtures thereof, said absorbent being in the form of particles.
摘要翻译:本发明涉及一种从气流中除去含硫化合物如H 2 S和COS的方法,包括使气流与流化床中的吸收剂接触,该吸收剂基于选自以下的第一种金属的至少一种氧化物: 由Mn,Fe,Co,Ni,Cu和Zn组成的组,与选自由Al 2 O 3,TiO 2,Al 2 O 3,Al 2 O 3组成的组的载体中的至少一种选自Cr,Mo和W的第二金属的氧化物组合, 或ZrO 2或其混合物,所述吸收剂为颗粒形式。