公开(公告)号：US12059669B2

公开(公告)日：2024-08-13

申请号：US17438594

申请日：2020-03-13

Applicant: MITSUBISHI CHEMICAL UK LIMITED

Inventor： Adam Cullen

IPC: B01J21/00 ,  B01J6/00 ,  B01J21/06 ,  B01J21/08

CPC classification number: B01J21/063 ,  B01J6/001 ,  B01J21/08

Abstract: A catalyst including a modified silica support having a titanium modifier metal, and a catalytic metal on the modified silica support. A proportion of the modifier metal is present in the form of mononuclear titanium moieties or is derived from a mononuclear titanium cation source at the commencement of modification. The invention also discloses a corresponding modified silica support, a method of producing the catalyst or the modified silica support, and a process for preparing an ethylenically unsaturated acid or ester in the presence of the catalyst.

公开(公告)号：US20240116041A1

公开(公告)日：2024-04-11

申请号：US18389921

申请日：2023-12-20

Applicant: Alantum Europe GmbH ,  Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.

Inventor： Lars TORKUHL ,  Robin KOLVENBACH ,  JungSuk BAE ,  Andreas TILLMANN ,  Alexandra GERSTLE ,  Gunnar WALTHER ,  Tilo BÜTTNER ,  Hans-Dietrich BÖHM ,  Bernd KIEBACK ,  Thomas WEISSGÄRBER ,  Arne BODEN

IPC: B01J35/56 ,  B01J21/00 ,  B01J23/26 ,  B01J23/745 ,  B01J23/755 ,  B01J37/02 ,  B01J37/08 ,  B01J37/34

CPC classification number: B01J35/56 ,  B01J21/005 ,  B01J23/26 ,  B01J23/745 ,  B01J23/755 ,  B01J37/0217 ,  B01J37/0221 ,  B01J37/0225 ,  B01J37/08 ,  B01J37/344

Abstract: A method of manufacturing a catalyst material includes the steps of: providing a body having an open-porous foam structure and comprising at least a first metal or alloy; providing particles, each of which particles comprising at least a second metal or alloy; distributing the particles on the body; forming a structural connection between each of at least a subset of the particles and the body; and forming an oxide film on at least the subset of the particles and the body, wherein the oxide film has a catalytically active surface.

公开(公告)号：US20230398522A1

公开(公告)日：2023-12-14

申请号：US18250277

申请日：2021-11-24

Applicant: TOPSOE A/S

Inventor： Poul Erik HØJLUND NIELSEN ,  Niels Christian SCHJØDT ,  Susanne Lægsgaard JØRGENSEN ,  Uffe Vie MENTZEL ,  Matthias Josef BEIER ,  Henrik Junge MORTENSEN

IPC: B01J23/80 ,  B01J21/02 ,  B01J37/08 ,  B01J35/10 ,  B01J35/00 ,  B01J6/00 ,  B01J37/03 ,  B01J21/00 ,  C07C29/145

CPC classification number: B01J23/80 ,  B01J21/02 ,  B01J37/08 ,  B01J35/1033 ,  B01J35/1004 ,  B01J35/006 ,  B01J6/001 ,  B01J37/03 ,  B01J35/0026 ,  B01J21/005 ,  C07C29/145

Abstract: Process for the catalytic hydrogenation of organic carbonyl compounds containing at least one functional group belonging to the group of aldehydes, ketones, esters and carboxylic acids, whereby said at least one functional group is converted to an alcohol by contacting said carbonyl compound with hydrogen and a hydrogenation catalyst at elevated temperature and pressure as well as a catalyst therefore and a process for producing said catalyst.

公开(公告)号：US11701647B2

公开(公告)日：2023-07-18

申请号：US17034932

申请日：2020-09-28

Applicant: Hyundai Motor Company ,  Kia Motors Corporation ,  Research & Business Foundation Sungkyunkwan University

Inventor： Haeun Jeong ,  Jin Woo Choung ,  Kyung Soo Park ,  Jaehyeon Kwon ,  Ji Su Yu ,  Jong Wook Bae

IPC: B01J21/00 ,  B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J21/10 ,  B01J21/12 ,  B01J21/14 ,  B01J23/00 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/28 ,  B01J23/30 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/46 ,  B01J23/50 ,  B01J23/52 ,  B01J23/60 ,  B01J23/62 ,  B01J23/63 ,  B01J23/68 ,  B01J23/72 ,  B01J23/74 ,  B01J23/75 ,  B01J23/755 ,  B01J23/80 ,  B01J23/825 ,  B01J23/83 ,  B01J23/835 ,  B01J23/88 ,  B01J23/881 ,  B01J23/882 ,  B01J23/885 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J35/00 ,  B01J35/10 ,  C01B3/40 ,  B82Y30/00 ,  B82Y40/00

CPC classification number: B01J35/0013 ,  B01J23/755 ,  B01J35/006 ,  B01J35/1061 ,  C01B3/40 ,  B82Y30/00 ,  B82Y40/00

Abstract: Disclosed are a catalyst for preparing a synthetic gas through dry reforming, a method preparing the catalyst, and a method using the catalyst for preparing the synthetic gas. The catalyst may include: a support including regularly distributed mesopores; metal nanoparticles supported on the support; and a metal oxide coating layer coated on a surface of the support.

公开(公告)号：US11491471B2

公开(公告)日：2022-11-08

申请号：US16089012

申请日：2016-04-27

Applicant: University of Science and Technology of China

Inventor： Junling Lu ,  Lina Cao ,  Qi Yao ,  Si Chen ,  Huan Yan ,  Shiqiang Wei ,  Jinlong Yang

IPC: B01J23/89 ,  B01J23/38 ,  B01J37/02 ,  B01J21/18 ,  B01J21/06 ,  B01J21/10 ,  B01J23/74 ,  B01J23/10 ,  B01J21/00 ,  B01J37/00 ,  B01J21/04 ,  B01J21/08 ,  C01B3/58 ,  H01M8/0668

Abstract: This invention provides a preparation method of a catalyst for preferential oxidization of CO in a hydrogen-enriched atmosphere, and a catalyst product obtained from the method and its applications thereof. Particularly, in this invention, a wide-temperature catalyst for preferential oxidization of CO in a hydrogen-enriched atmosphere is obtained by depositing one or more of an iron oxide, cobalt oxide, and nickel oxide as a promoter onto the surface of a supported Pt-group noble metal catalyst precursor via chemical vapor deposition or atomic layer deposition. In the wide-temperature catalyst, the active noble metal component has a content of 0.1 to 10 wt %, and the promoter has a content of 0.1 to 10 wt % in terms of the metal element thereof. In the reaction of preferential oxidation of CO in a hydrogen-enriched atmosphere, the catalyst prepared by this invention can exhibit excellent catalytic performance and can achieve high conversion of CO with high selectivity in a wide temperature range of −80 to 200° C., for example. Also, the catalyst can remain stable for a long time even in a case where steam and CO2 are present in the hydrogen-enriched atmosphere.

公开(公告)号：US20220228520A1

公开(公告)日：2022-07-21

申请号：US17540741

申请日：2021-12-02

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Naoto NAGATA ,  Kazushi WAKAYAMA

IPC: F01N13/00 ,  F01N3/10 ,  F01N11/00 ,  B01D53/94 ,  B01J21/00 ,  B01J23/58 ,  B01J35/02 ,  B01J35/10

Abstract: An exhaust gas purification system of the present disclosure includes a first exhaust gas purification device that purifies exhaust gas discharged from an internal combustion engine and a second exhaust gas purification device that additionally purifies the exhaust gas purified by the first exhaust gas purification device, wherein the exhaust gas is exhaust gas with a gaseous composition in which an amount of reducing agents is in excess compared to a stoichiometric gaseous composition and a gaseous composition in which an amount of oxidants is in excess compared to the stoichiometric gaseous composition are alternately switched between, the first exhaust gas purification device includes a three-way catalyst, and the second exhaust gas purification device includes an exhaust gas purification catalyst containing spinel-type MgAlxFe2.00−xO4.00 supporting particles on which Rh is supported, where 0.00

公开(公告)号：US11365661B2

公开(公告)日：2022-06-21

申请号：US17081133

申请日：2020-10-27

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Naoto Nagata ,  Daisuke Shimoyama

IPC: F01N3/10 ,  F01N13/00 ,  B01J21/00

Abstract: There is provided an exhaust gas purification system that allows efficient purification of NOx present in exhaust gas emitted from an internal combustion engine. The exhaust gas purification system of the disclosure comprises a first exhaust gas purification device that purifies exhaust gas emitted from an internal combustion engine, wherein the atmosphere alternately switches between a reducing agent-excess atmosphere and an oxidizing agent-excess atmosphere with respect to the stoichiometric atmosphere, and a second exhaust gas purification device that further purifies the exhaust gas that has been purified by the first exhaust gas purification device, wherein the first exhaust gas purification device has a three-way catalyst, and the second exhaust gas purification device has an exhaust gas purifying catalyst that comprises an AMn2O4 spinel-type oxide support (A=Mg, Zn or Li) on which a precious metal is supported.

公开(公告)号：US11278869B2

公开(公告)日：2022-03-22

申请号：US16346291

申请日：2017-10-17

Applicant: HINDUSTAN PETROLEUM CORPORATION LIMITED

Inventor： Somanath Kukade ,  Pramod Kumar ,  Venkata Chalapathi Rao Peddy ,  Sriganesh Gandham

IPC: B01J21/00 ,  B01J21/12 ,  B01J29/08 ,  B01J29/42 ,  B01J29/70 ,  B01J37/00 ,  B01J37/02 ,  C10G11/05 ,  C10G11/18

Abstract: The instant disclosure provides a composition for fluid catalytic cracking of petroleum based feedstock into useful short chain olefins. The composition comprising: 76-86% of a non-zeolitic material; and 2-30% of at least one zeolite material, the percentage being based on weight of the catalyst composition, wherein one of the zeolites has been modified with 0.1-2.5 wt % metal. The said catalyst was found to be selective in enhancing the usable propylene gas content, while reducing the undesirable dry gas content of the cracked olefinic products. The present disclosure also provides a process for the preparation of the composition. The present disclosure also provides an apparatus (100) and process (200) for fluid catalytic cracking to obtain light olefins. The apparatus comprises a second riser (33) that includes a lower dense riser (2) and upper dilute riser (3). Further, the lower dense riser (2) has a diameter that is 1.1 to 2 times that of the upper dilute riser (3).

公开(公告)号：US11203010B2

公开(公告)日：2021-12-21

申请号：US16635586

申请日：2018-07-31

Applicant: PURDUE RESEARCH FOUNDATION

Inventor： Jeffrey T. Miller ,  Zhenwei Wu ,  Evan C. Wegener ,  Stephen Purdy ,  Nicole J. Libretto

IPC: C07C5/00 ,  B01J23/00 ,  B01J37/08 ,  B01J21/00 ,  B01J23/648 ,  B01J21/06 ,  B01J23/652 ,  B01J23/656 ,  B01J37/16 ,  C07C5/333 ,  B01J21/02 ,  B01J21/08

Abstract: A novel catalyst composition and its use in the dehydrogenation of alkanes to olefins. The catalyst comprises a Group VIII noble metal and a metal selected from the group consisting of manganese, vanadium, chromium, titanium, and combinations thereof, on a support. The Group VIII noble metal can be platinum, palladium, osmium, rhodium, rubidium, iridium, and combinations thereof. The support can be silicon dioxide, titanium dioxide, aluminum oxide, silica-alumina, cerium dioxide, zirconium dioxide, magnesium oxide, metal modified silica, silica-pillared clays, silica-pillared micas, metal oxide modified silica-pillared mica, silica-pillared tetrasilicic mica, silica-pillared taeniolite, zeolite, molecular sieve, and combinations thereof. The catalyst composition is an active and selective catalyst for the catalytic dehydrogenation of alkanes to olefins.

公开(公告)号：US20210316291A1

公开(公告)日：2021-10-14

申请号：US17261362

申请日：2019-07-16

Applicant: Alantum Europe GmbH ,  Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.

Inventor： Lars TORKUHL ,  Robin KOLVENBACH ,  JungSuk BAE ,  Andreas TILLMANN ,  Alexandra GERSTLE ,  Gunnar WALTHER ,  Tilo BÜTTNER ,  Hans-Dietrich BÖHM ,  Bernd KIEBACK ,  Thomas WEISSGÄRBER ,  Arne BODEN

IPC: B01J35/04 ,  B01J23/745 ,  B01J23/755 ,  B01J23/26 ,  B01J37/02 ,  B01J37/08 ,  B01J21/00 ,  B01J37/34

Abstract: A method of manufacturing a catalyst material includes the steps of: providing a body having an open-porous foam structure and comprising at least a first metal or alloy; providing particles, each of which particles comprising at least a second metal or alloy; distributing the particles on the body; forming a structural connection between each of at least a subset of the particles and the body; and forming an oxide film on at least the subset of the particles and the body, wherein the oxide film has a catalytically active surface.