公开(公告)号：US20250051157A1

公开(公告)日：2025-02-13

申请号：US18718092

申请日：2022-12-14

Applicant: BASF SE

Inventor： Elias Christopher FREI ,  Michael KRAEMER ,  Virginie LANVER ,  Nils BOTTKE

IPC: C01B3/04 ,  B01J21/04 ,  B01J23/755 ,  B01J23/78 ,  B01J23/89 ,  C01B3/38

Abstract: The present invention relates to a specific process for the reforming of ammonia, wherein the process comprises (i) providing a reactor containing a catalyst comprising a metal M1 selected from the group consisting of Ni, Co, or Ni and Co; (ii) preparing a feed gas stream comprising NH3; (iii) feeding the feed gas stream prepared in (ii) into the reactor provided in (i) and contacting the feed gas stream with the catalyst, wherein contacting is performed at a pressure of 1 to 50 bara, and at a temperature of 400 to 1,100° C.; (iv) removing an effluent gas stream from the reactor, the effluent gas stream comprising H2 and N2.

公开(公告)号：US20250025865A1

公开(公告)日：2025-01-23

申请号：US18572292

申请日：2022-06-21

Applicant: TOHOKU UNIVERSITY

Inventor： Ryota SAKAMOTO ,  Ryu ABE ,  Jingyan GUAN ,  Hajime SUZUKI

IPC: B01J31/16 ,  B01J23/02 ,  B01J23/78 ,  B01J35/39 ,  C01B3/04

Abstract: The cocatalyst for hydrogen generation is a cocatalyst for hydrogen generation to be combined with a semiconductor catalyst that is excited by light and includes a metal-organic framework having a molecular structure represented by the following formula (1). In the formula (1), M is at least one selected from Ni, Co, Fe, Cu, Zn, Pd, Pt, Au, and Ir, L1 to L4 are each independently at least one selected from S, Se, Te, NH, and O, C1 and C2 are carbon atoms forming a first aromatic group, and C3 and C4 are carbon atoms forming a second aromatic group.

公开(公告)号：US20240278225A1

公开(公告)日：2024-08-22

申请号：US18568559

申请日：2022-05-11

Applicant: LINDE GMBH ,  BASF SE

Inventor： Nicole SCHÖDEL ,  Stephanie NEUENDORF ,  Axel BEHRENS ,  Wibke KORN ,  Sonja SCHULTE ,  Stefan HOFFMANN ,  Marcelo Daniel KAUFMAN RECHULSKI ,  Virginie LANVER ,  Stefan DIETRICH ,  Nils BOTTKE ,  Christiane KURETSCHKA ,  Hamideh AHI ,  Manuel Frederik GENTZEN ,  Michael KRAMER

IPC: B01J37/10 ,  B01J21/04 ,  B01J23/78 ,  B01J23/83 ,  B01J37/18 ,  C01B3/40

CPC classification number: B01J37/10 ,  B01J21/04 ,  B01J23/78 ,  B01J23/83 ,  B01J37/18 ,  C01B3/40 ,  C01B2203/0238 ,  C01B2203/1052 ,  C01B2203/1082

Abstract: The invention relates to a method for activating a catalyst for catalytic reforming that is particularly carried out with carbon dioxide being reacted, and according to which an activation gas that contains steam and hydrogen is passed over the catalyst to be activated at an activation temperature during an activation period. The activation gas comprises 10 to 30 mol-% steam, 40 to 60 mol-% hydrogen and 20 to 40 mol-% one or more inert gases.

公开(公告)号：US11980868B2

公开(公告)日：2024-05-14

申请号：US17820012

申请日：2022-08-16

Applicant: Johnson Matthey Public Limited Company

Inventor： Silvia Alcove Clave ,  Kevin Doura ,  Joseph Fedeyko

IPC: B01J21/02 ,  B01D53/86 ,  B01J21/10 ,  B01J23/00 ,  B01J23/02 ,  B01J23/10 ,  B01J23/34 ,  B01J23/72 ,  B01J23/78 ,  B01J23/83 ,  B01J23/88 ,  B01J23/889 ,  F24F8/167 ,  F24F8/95

CPC classification number: B01J23/002 ,  B01D53/864 ,  B01D53/8687 ,  B01J21/02 ,  B01J23/72 ,  B01J23/78 ,  B01J23/83 ,  B01J23/8892 ,  F24F8/167 ,  F24F8/95 ,  B01D2255/40 ,  B01D2257/502 ,  B01D2257/708 ,  B01D2258/06 ,  B01D2259/4508 ,  B01J2523/17 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/72

Abstract: The present invention relates to a method for the treatment of an exhaust gas comprising carbon monoxide (CO) and/or one or more volatile organic compounds (VOCs) using a PGM-free catalyst article comprising a mixed oxide of Mn, Cu, Mg, Al and La. The present invention also relates to an HVAC system comprising a PGM-free catalyst article.

公开(公告)号：US20240139718A1

公开(公告)日：2024-05-02

申请号：US18410777

申请日：2024-01-11

Applicant: INDUSTRY FOUNDATION OF CHONNAM NATIONAL UNIVERSITY

Inventor： Chang Hyun KO ,  Ji Yoon Jeon ,  Jeong Woo Yun ,  Eun Gyong Park

IPC: B01J23/78 ,  B01J23/00 ,  B01J37/04 ,  B01J37/08 ,  C01B3/40

CPC classification number: B01J23/78 ,  B01J23/002 ,  B01J37/04 ,  B01J37/088 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0261 ,  C01B2203/1058 ,  C01B2203/1241

Abstract: The present invention is a perovskite metal oxide catalyst substituted with metal ions for reducing carbon deposition, a method for producing the same, and a process for performing a methane reforming reaction using this catalyst. The catalyst is produced in which Ni in ionic form is substituted at a portion of the Ti site of SrTiO3, MgTiO3, CaTiO3, or BaTiO3, which is a multi-component metal oxide having a perovskite structure. Then, various methane reforming reactions (steam-methane reforming, dry reforming of methane, catalytic partial oxidation of methane) may be efficiently and economically performed using this catalyst. The nickel-substituted perovskite metal oxide catalyst has a structure in which Ni2+ is substituted in the perovskite lattice structure. Thus, the metal oxide catalyst has advantages in that carbon deposition thereon does not occur, and thus, the catalyst has a high catalytic stability and may be used for a long time.

公开(公告)号：US20230381751A1

公开(公告)日：2023-11-30

申请号：US18248775

申请日：2021-10-13

Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION ,  SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC

Inventor： Lei SONG ,  Changxi MIAO ,  Min ZHU ,  Chunling WEI ,  Yongfan XU

IPC: B01J23/83 ,  B01J23/78 ,  B01J37/04 ,  B01J37/00 ,  B01J37/08 ,  B01J23/888 ,  B01J23/00 ,  B01J23/745

CPC classification number: B01J23/83 ,  B01J23/78 ,  B01J37/04 ,  B01J23/745 ,  B01J37/08 ,  B01J23/888 ,  B01J23/002 ,  B01J37/0018

Abstract: An iron-potassium-cerium-based composite oxide catalyst, its preparation and application thereof are provided. The catalyst has metal elements Fe, K and Ce, as well as a metal element M that is at least one selected from the group consisting of Group IIA metal elements, Group VIB metal elements other than Cr and Group IVA metal elements. The catalyst has a total alkali content of 0.32-0.46 mmol/g, and a strong alkali content of 0.061-0.082 mmol/g. When used for dehydrogenation of alkyl aromatics, the catalyst shows high selectivity, high catalytic activity and high stability, provides less by-products, and has the characteristics of low material consumption and low power consumption, even at a low dehydrogenation temperature and an ultralow steam-to-oil ratio.

公开(公告)号：US11806700B2

公开(公告)日：2023-11-07

申请号：US17944623

申请日：2022-09-14

Applicant: Saudi Arabian Oil Company ,  King Abdullah University of Science and Technology

Inventor： Jorge Gascon ,  Salvador Sayas ,  Natalia Morlanes ,  Sai Katikaneni ,  Aadesh Harale ,  Bandar Solami

IPC: B01J23/10 ,  B01J23/78 ,  B01J37/03 ,  B01J35/02 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  C01B3/04

CPC classification number: B01J37/031 ,  B01J23/10 ,  B01J23/78 ,  B01J35/023 ,  B01J37/009 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/06 ,  B01J37/088 ,  C01B3/047

Abstract: A method for ammonia decomposition to produce hydrogen, the method comprising the steps of introducing an ammonia stream to a reactor, wherein the ammonia stream comprises ammonia, wherein the reactor comprises a cobalt-based catalyst, the cobalt-based catalyst comprising 15 wt % and 70 wt % of cobalt, 5 wt % and 45 wt % of cerium, and 0.4 wt % and 0.5 wt % barium, wherein a remainder of weight of the cobalt-based catalyst is oxygen; contacting the ammonia in the ammonia stream with the cobalt-based catalyst, wherein the cobalt-based catalyst is operable to catalyze an ammonia decomposition reaction; catalyzing the ammonia decomposition reaction to cause the ammonia decomposition in the presence of the cobalt-based catalyst to produce hydrogen; and withdrawing a product stream from the reactor, the product stream comprising hydrogen.

公开(公告)号：US11642661B2

公开(公告)日：2023-05-09

申请号：US17093849

申请日：2020-11-10

Applicant: Murata Manufacturing Co., Ltd.

Inventor： Satoshi Kuretake ,  Kentaro Ishihara ,  Nario Sugahara

IPC: B01J23/889 ,  A61L9/03 ,  B01D53/86 ,  B01J23/00 ,  B01J23/34 ,  B01J23/68 ,  B01J23/78 ,  B01J35/10 ,  C01G45/12 ,  C01G51/00 ,  C01G53/00 ,  B01J21/06 ,  B01J35/04 ,  B01D53/94 ,  B01J21/04 ,  B01J35/02 ,  B01J37/00 ,  B01J21/16

CPC classification number: B01J23/8892 ,  A61L9/03 ,  B01D53/865 ,  B01D53/8668 ,  B01D53/8687 ,  B01D53/8696 ,  B01D53/94 ,  B01J21/04 ,  B01J21/066 ,  B01J23/002 ,  B01J23/34 ,  B01J23/688 ,  B01J23/78 ,  B01J35/026 ,  B01J35/04 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  C01G45/125 ,  C01G45/1207 ,  C01G51/66 ,  C01G53/66 ,  B01D2255/104 ,  B01D2255/2042 ,  B01D2255/2047 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2073 ,  B01D2255/2092 ,  B01D2255/2094 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/20792 ,  B01D2255/402 ,  B01D2255/9202 ,  B01D2255/9207 ,  B01D2257/7027 ,  B01D2258/01 ,  B01D2258/02 ,  B01J21/16 ,  B01J37/009 ,  C01P2002/34 ,  C01P2002/50 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16

Abstract: A supported catalyst for decomposing an organic substance that includes a support and a catalyst particle supported on the support. The catalyst particle contains a perovskite-type composite oxide represented by AxByMzOw, where the A contains at least one selected from Ba and Sr, the B contains Zr, the M is at least one selected from Mn, Co, Ni and Fe, y+z=1, x≥0.995, z≤0.4, and w is a positive value satisfying electrical neutrality. A film thickness of a catalyst-supporting film supported on the support and containing the catalyst particle is 5 μm or more, or a supported amount as determined by normalizing a mass of the catalyst particle supported on the support by a volume of the support is 45 g/L or more.

公开(公告)号：US20230095488A1

公开(公告)日：2023-03-30

申请号：US17795892

申请日：2021-01-29

Applicant: BASF SE

Inventor： Marcelo Daniel KAUFMAN RECHULSKI ,  Christiane KURETSCHKA ,  Sandra MAGNUS ,  Sabine BORCHERS ,  Juergen AMANN

IPC: B01J23/78 ,  C01B3/40 ,  B01J6/00 ,  B01J37/04 ,  B01J37/00

Abstract: The present invention relates to a process for preparing a molding comprising a mixed oxide comprising O, Mg, and Ni, the process comprising: —(i) mixing water, a Mg source, a Ni source, and an acid, to obtain a mixture; —(ii) subjecting the mixture obtained from (i) to a shaping process; —(iii) calcining the molding obtained from (ii) in a gas atmosphere having a temperature in the range of from 700 to 1400° C.; wherein the molar ratio of the acid used in (i) to Ni, calculated as elemental Ni, of the Ni source used in (i), acid:Ni, is equal to or higher than 0.001:1. Further, the present invention relates to a molding comprising a mixed oxide comprising O, Mg, and Ni, wherein the mixed oxide comprises a specific crystalline phase NixMgyO, wherein the sum of x and y is 1, and wherein y is greater than 0.52. The molding is used for reforming methane to a synthesis gas comprising hydrogen and carbon monoxide.

公开(公告)号：US11478784B2

公开(公告)日：2022-10-25

申请号：US16781843

申请日：2020-02-04

Applicant: Saudi Arabian Oil Company ,  King Abdullah University of Science and Technology

Inventor： Jorge Gascon ,  Salvador Sayas ,  Natalia Morlanes ,  Sai Katikaneni ,  Aadesh Harale ,  Bandar Solami

IPC: B01J23/10 ,  B01J23/78 ,  B01J35/02 ,  C01B3/04 ,  B01J37/03 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08

Abstract: A method for ammonia decomposition to produce hydrogen, the method comprising the steps of introducing an ammonia stream to a reactor, wherein the ammonia stream comprises ammonia, wherein the reactor comprises a cobalt-based catalyst, the cobalt-based catalyst comprising 15 wt % and 70 wt % of cobalt, 5 wt % and 45 wt % of cerium, and 0.4 wt % and 0.5 wt % barium, wherein a remainder of weight of the cobalt-based catalyst is oxygen; contacting the ammonia in the ammonia stream with the cobalt-based catalyst, wherein the cobalt-based catalyst is operable to catalyze an ammonia decomposition reaction; catalyzing the ammonia decomposition reaction to cause the ammonia decomposition in the presence of the cobalt-based catalyst to produce hydrogen; and withdrawing a product stream from the reactor, the product stream comprising hydrogen.