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公开(公告)号：US20240173711A1
公开(公告)日：2024-05-30
申请号：US18483573
申请日：2023-10-10
申请人： UOP LLC
发明人： John Q. Chen , Wei Pan , Stephen C. Houdek
CPC分类号： B01J38/16 , B01J21/04 , B01J23/42 , B01J23/96 , B01J38/02 , C07C5/3337 , C07C2523/04 , C07C2523/08 , C07C2523/42
摘要： A system for contacting a reactant stream with a catalyst that includes a reactor containing a quantity of catalyst and an inlet and a product outlet configured for discharging product and a catalyst regenerator unit having an inlet configured for receiving a spent catalyst stream from the reactor and an outlet configured for passage of a regenerated catalyst to the reactor where a water level in the reactor is about 10 vppm to about 3 mole percent.
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公开(公告)号：US11926800B2
公开(公告)日：2024-03-12
申请号：US17574439
申请日：2022-01-12
申请人： UOP LLC
CPC分类号： C10G35/09 , B01J23/96 , B01J38/02 , C10G2300/1085 , C10G2400/20
摘要： A fluidized catalytic reactor system cycles from 0.05-5% of catalyst at a time through a rejuvenation unit to be heated in the presence of oxygen to maintain catalyst activity. The use of the rejuvenation unit that may be 2% of the size of the main catalyst regeneration unit allows for reduction in equipment size and in catalyst inventory. The catalyst that is sent to the rejuvenation unit may be spent catalyst but may be partially or fully regenerated catalyst. The rejuvenation unit may be heated by combusting fuel or by hot flue gas.
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公开(公告)号：US11767232B2
公开(公告)日：2023-09-26
申请号：US17367642
申请日：2021-07-06
发明人： Yong Nie , Shangzhi Yu , Xiaojiang Liang , Qinglong Xie , Zhenyu Wu , Jianfeng Bai
IPC分类号： C02F1/04 , B01D53/48 , B01D53/81 , B01D53/96 , B01J23/96 , B01J38/12 , C02F1/16 , F23G7/07 , C02F101/10 , C02F101/30 , C02F103/36
CPC分类号： C02F1/048 , B01D53/48 , B01D53/81 , B01D53/96 , B01J23/96 , B01J38/12 , C02F1/043 , C02F1/16 , F23G7/07 , B01D2251/602 , B01D2255/1021 , B01D2257/30 , C02F2101/101 , C02F2101/30 , C02F2103/365 , C02F2209/03 , C02F2209/08
摘要： The present invention provides a process for continuous treatment of high-concentration organic wastewater and a device for continuous treatment of high-concentration organic wastewater. The process of the present application is that: high-concentration organic wastewater is continuously separated through the synergistic interaction of a multilayer evaporator and a heat pump, and the generated wastewater steam containing light components is continuously subjected to desulfurization and catalytic combustion after being mixed with air in a gaseous form, the treated wastewater can meet discharge standards, and heavy components of the generated wastewater can be recycled. After the desulfurizing agent in a first desulfurizer and the catalyst in a first catalytic combustor are deactivated, the generated wastewater steam containing the light components can be switched to a second desulfurizer and a second catalytic combustor for reaction, and air can be introduced into the deactivated catalyst and desulfurizing agent for in-situ regeneration at a high temperature.
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公开(公告)号：US20230072588A1
公开(公告)日：2023-03-09
申请号：US17891093
申请日：2022-08-18
发明人： Paul G. Blommel , Colin Anson , Matt van Straten , Edgar Steenwinkel , Chris Holland , Rauf Gearing , Chris Ferguson , Rob Wild , Ian Campbell
摘要： The present disclosure provides methods for producing a regenerated hydrogenation catalyst from a fouled hydrogenation catalyst having a total surface area and at least one associated impurity. The method can include maintaining contact between the fouled hydrogenation catalyst and a flushing medium that comprises water, oxygen, and an inert or diluent gas at a regeneration temperature and a regeneration pressure sufficient to remove at least a portion of the at least one impurity from the hydrogenation catalyst to produce the regenerated hydrogenation catalyst, where the regenerated hydrogenation catalyst is characterized as retaining at least 70% of the activity of the hydrogenation catalyst.
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5.发明申请公开(公告)号：US20220340505A1
公开(公告)日：2022-10-27
申请号：US17860357
申请日：2022-07-08
发明人： Matthew T. Pretz , Mark W. Stewart , Lin Luo , Hangyao Wang
IPC分类号： C07C5/333 , B01J8/00 , B01J8/18 , B01J8/24 , B01J21/12 , B01J23/62 , B01J23/96 , B01J38/02 , B01J38/12
摘要： A method for processing a chemical stream includes contacting a feed stream with a catalyst in a reactor portion of a reactor system that includes a reactor portion and a catalyst processing portion. The catalyst includes platinum, gallium, or both and contacting the feed stream with the catalyst causes a reaction which forms an effluent stream. The method includes separating the effluent stream from the catalyst, passing the catalyst to the catalyst processing portion, and processing the catalyst in the catalyst processing portion. Processing the catalyst includes passing the catalyst to a combustor, combusting a supplemental fuel in the combustor to heat the catalyst, treating the heated catalyst with an oxygen-containing gas to produce a reactivated catalyst, and passing the reactivated catalyst from the catalyst processing portion to the reactor portion. The supplemental fuel may include a molar ratio of hydrogen to other combustible fuels of at least 1:1.
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公开(公告)号：US20220135887A1
公开(公告)日：2022-05-05
申请号：US17574439
申请日：2022-01-12
申请人： UOP LLC
摘要： A fluidized catalytic reactor system cycles from 0.05-5% of catalyst at a time through a rejuvenation unit to be heated in the presence of oxygen to maintain catalyst activity. The use of the rejuvenation unit that may be 2% of the size of the main catalyst regeneration unit allows for reduction in equipment size and in catalyst inventory. The catalyst that is sent to the rejuvenation unit may be spent catalyst but may be partially or fully regenerated catalyst. The rejuvenation unit may be heated by combusting fuel or by hot flue gas.
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公开(公告)号：US10646855B2
公开(公告)日：2020-05-12
申请号：US16177833
申请日：2018-11-01
申请人： UOP LLC
发明人： Manuela Serban , Matthew C. Cole , Ellen Arnold , Guanghui Zhu
IPC分类号： B01J23/62 , B01J21/04 , B01J35/08 , B01J35/00 , B01J35/10 , C07C5/333 , B01J23/96 , B01J38/02
摘要： A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with a median diameter between 1.6 mm and 2.5 mm and an apparent bulk density between 0.6 and 0.3 g/cc. Also a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.
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公开(公告)号：US10472304B2
公开(公告)日：2019-11-12
申请号：US15737848
申请日：2016-06-29
申请人： SMH Co., Ltd
IPC分类号： C07C5/333 , B01J37/04 , B01J23/652 , C07C6/10 , B01J37/18 , B01J38/12 , B01J23/00 , B01J23/28 , B01J23/30 , B01J23/36 , B01J23/656 , B01J23/92 , B01J23/96
摘要： The present invention relates to a hydrocarbon conversion catalyst comprising i) a catalyst, in oxidic form, metals M1, M2, M3 and M4, wherein: M1 is selected from Si, Al, Zr, and mixtures thereof; M2 is selected from Pt, Cr, and mixtures thereof; M3 is selected from W, Mo, Re and mixtures thereof; M4 is selected from Sn, K, Y, Yb and mixtures thereof; and ii) a hydrogen scavenger selected from at least one alkali and/or alkaline earth metal derivative, preferably in metallic, hydride, salt, complex or alloy form; as well as a hydrocarbon conversion process utilizing this catalyst.
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公开(公告)号：US20190225563A1
公开(公告)日：2019-07-25
申请号：US16255364
申请日：2019-01-23
发明人： Matthew T. Pretz
IPC分类号： C07C5/333 , B01J23/26 , B01J38/02 , B01J38/12 , B01J38/14 , B01J23/62 , B01J23/94 , B01J35/00 , B01J21/04 , B01J21/12 , B01J23/887 , B01J23/92 , B01J23/96 , B01J35/10 , B01J8/00 , B01J8/26 , B01J8/18 , B01J8/12 , B01J8/08
CPC分类号： C07C5/3332 , B01J8/0025 , B01J8/0055 , B01J8/087 , B01J8/12 , B01J8/1836 , B01J8/1863 , B01J8/26 , B01J21/04 , B01J21/12 , B01J23/26 , B01J23/62 , B01J23/8871 , B01J23/92 , B01J23/94 , B01J23/96 , B01J35/0006 , B01J35/1009 , B01J35/1014 , B01J38/02 , B01J38/12 , B01J38/14 , B01J2208/00176 , B01J2208/00362 , B01J2208/00769 , B01J2219/00024 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2523/08 , C07C2523/42 , C07C2523/62 , Y02P20/125 , Y02P20/52 , Y02P20/584 , C07C11/06 , C07C11/08
摘要： An integrated process for producing C3-C4 olefins or di-olefins including: contacting a hydrocarbon feed and a catalyst feed in a fluidized dehydrogenation reactor under conditions such that a product mixture is formed and the catalyst is at least partially deactivated; transferring the product mixture and the catalyst from the reactor to a cyclonic separation system under conditions such that the product mixture is converted to form a new product mixture and is separated from the catalyst; transferring at least a portion of the catalyst to a regenerator vessel and heating it in order to combust the coke deposited thereon; subjecting the catalyst to a conditioning step to form an oxygen-containing, at least partially reactivated catalyst; and transferring the partially reactivated catalyst back to the fluidized dehydrogenation reactor.
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公开(公告)号：US20180169630A1
公开(公告)日：2018-06-21
申请号：US15847976
申请日：2017-12-20
申请人： UOP LLC
摘要： A process is presented for the management of sulfur on a catalyst. The catalyst is a dehydrogenation catalyst, and sulfur accumulates during the dehydrogenation process. Sulfur compounds are stripped from the spent catalyst and the catalyst is cooled before the regeneration process. The process includes controlling the amount of sulfur that needs to be removed from the catalyst before regeneration.
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