METHOD FOR PREPARING DIAMINOBIPHENYL COMPOUND

    公开(公告)号:US20220402858A1

    公开(公告)日:2022-12-22

    申请号:US17783848

    申请日:2020-12-02

    Abstract: The object of the present invention is to provide a method which provides a diaminobiphenyl compound in a high yield and in a short period of time by a benzidine rearrangement reaction of a hydrazobenzene having a bulky substituent group at the meta position. Specifically, the present invention provides a method for preparing a diaminobiphenyl compound represented by the following formula (1): wherein, X1 and X2 are, independently of each other, a group selected from the group consisting of a trifluoromethyl group and, optionally fluorinated, isopropyl, isobutyl, sec-butyl, tert-butyl and neopentyl groups, comprising a step of subjecting a diphenylhydrazine compound represented by the following formula (2) wherein X1 and X2 are as defined above, to a benzidine rearrangement reaction in the presence of an organic solvent and an inorganic acid at a temperature of from −70° C. to −11° C. to obtain the diaminobiphenyl compound represented by the formula (1).

    Silica materials and methods of making thereof

    公开(公告)号:US11512002B2

    公开(公告)日:2022-11-29

    申请号:US16388725

    申请日:2019-04-18

    Abstract: Disclosed herein are methods for the preparation of porous metal oxide materials, including metal oxide xerogels and metal oxide aerogels. Methods for preparing porous metal oxide materials can comprise (i) reacting a metal alkoxide with water in the presence of a catalyst system to form a partially hydrolyzed sol, (ii) contacting the partially hydrolyzed sol with a base catalyst and a non-aqueous solvent to form a precursor gel; and (iii) drying the precursor gel to form the porous metal oxide material. The catalyst system employed in step (i) comprises a combination of a weak acid and a strong acid.

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