Method of making hydrocarbon soluble metal compositions

    公开(公告)号:US11453600B2

    公开(公告)日:2022-09-27

    申请号:US16440168

    申请日:2019-06-13

    IPC分类号: C01G41/00 C01G31/00 C01G39/00

    摘要: The present invention relates to a method of making of hydrocarbon soluble metal composition comprising of one or more metals of group VIB of the periodic table, wherein the metal having 4+ oxidation state predominantly forms highly active metal sulfide catalyst for hydro-conversion of heavy oil feedstocks in liquid phase. More particularly, present invention relates to a hydrocarbon soluble metal composition comprising of reaction products of a metal source, a lipophilic phenolic acid, a surfactant and an organophosphorus compound. The present invention also provides a one-pot process for preparation of the hydrocarbon soluble metal composition comprising reacting a metal source, a lipophilic phenolic acid, a surfactant, an organophosphorus compound and water to obtain a reaction product and drying the reaction product to obtain the hydrocarbon soluble metal composition.

    Preparation method of phosphotungstic acid

    公开(公告)号:US11214495B2

    公开(公告)日:2022-01-04

    申请号:US16327334

    申请日:2017-08-03

    摘要: A preparation method of phosphotungstic acid includes mixing a mixed solution containing tungsten, phosphorus and an inorganic acid with an organic-alcohol-containing oil phase for extraction, stripping the obtained supported organic phase and distilled water according to an oil phase:aqueous phase volume ratio of 3:1 to 10:1 to obtain a stripping solution; and carrying out thermal evaporation crystallization or spray drying on the stripping solution to obtain a phosphotungstic acid crystal, wherein the organic alcohol is a C7-C20 alcohol. The inventors have found out that the addition of an inorganic acid to a solution of phosphorus or tungsten and the use of an organic alcohol as an extractant can achieve simultaneous and efficient extraction of phosphotungstic acid. It has also been found that the organic-alcohol-containing oil phase has excellent selectivity for phosphotungstic acid molecules in the mixed solution.