METHOD AND SYSTEM FOR PREPARING UREA BY COUPLING DENITRATION WITH ELECTROCATALYTIC REDUCTION

    公开(公告)号:US20230391716A1

    公开(公告)日:2023-12-07

    申请号:US18035625

    申请日:2022-01-07

    摘要: The present disclosure relates to a method and a system for preparing urea by coupling denitration with electrocatalytic reduction. Specifically, the method of the present disclosure comprises: introducing an absorption solution containing nitrite and nitrate, which is generated by subjecting flue gas containing nitric oxide to a denitration step, into a separation step to separate the nitrite and the nitrate, thereby obtaining a solution rich in the nitrite and the nitrate; and introducing the solution rich in the nitrite and the nitrate generated in the separation step into an electrocatalysis step, and carrying out the electrocatalytic reduction in the presence of carbon dioxide or carbonate ions to generate a urea solution. The system of the present disclosure comprises: a denitration device, a separation device connected to the denitration device, and an electrocatalytic device connected to the separation device. The method and system of the present disclosure can be used for the deep removal of nitrogen oxides from industrial flue gas at a low temperature, and can achieve the recycling of nitrogen.

    PROCESS FOR PRODUCING FEED-GRADE UREA
    5.
    发明公开

    公开(公告)号:US20230303485A1

    公开(公告)日:2023-09-28

    申请号:US18035030

    申请日:2021-09-10

    申请人: Casale SA

    发明人: Leonardo Marrone

    IPC分类号: C07C273/16 C05C9/00

    CPC分类号: C07C273/16 C05C9/005

    摘要: A process for the production of feed grade urea starting from a liquid urea melt, the process comprising processing the urea melt (6) to promote the formation of biuret until a concentration of at least 3% biuret, and subjecting the so obtained biuret-containing urea melt (8) to a shaping process to obtain a granular urea product.

    HIGH PRESSURE STRIPPERS FOR USE IN UREA PLANTS

    公开(公告)号:US20220064109A1

    公开(公告)日:2022-03-03

    申请号:US17418512

    申请日:2020-04-30

    摘要: Shell-and-tube strippers for stripping a urea/carbamate mixture, related systems, methods, and uses. The stripper includes a shell, a plurality of tubes disposed within the shell, and a heating fluid distributor for homogenizing the flow of a heating fluid near a heating fluid inlet. The heating fluid distributor includes an edge wall and a laterally disposed heating fluid distribution plate. Related systems, methods, and uses are also provided.

    Controlling biuret in urea production

    公开(公告)号:US10766856B2

    公开(公告)日:2020-09-08

    申请号:US16698734

    申请日:2019-11-27

    申请人: STAMICARBON B.V.

    发明人: Eelco Mostert

    摘要: Disclosed is a novel method of controlling the formation of biuret in urea production, and particularly reducing, preventing or reversing such formation. This is accomplished by adding liquid ammonia to a urea aqueous stream. This addition is done at one or more positions downstream of a recovery section in a urea plant. The addition of liquid ammonia serves to shift the equilibrium of biuret formation from urea, to the side of the formation of urea from biuret and ammonia. The invention can be accomplished also in pre-existing urea plant, by the simple measure of providing an appropriate inlet for liquid ammonia, in fluid communication with a source of such liquid ammonia.