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公开(公告)号：US12203035B2
公开(公告)日：2025-01-21
申请号：US17930148
申请日：2022-09-07
Applicant: NESTE OYJ
Inventor： Jukka Myllyoja , Pekka Aalto , Pekka Savolainen , Veli-Matti Purola , Ville Alopaeus , Johan Gronqvist
IPC: C10G3/00 , C07C1/24 , C07C5/03 , C07C5/22 , C07C5/27 , C07C7/10 , C07C7/12 , C07C7/13 , C10G45/02 , C10G45/58 , C10G45/62 , C10G45/64 , C10G65/04 , C10L1/08
Abstract: The invention relates to a process for the manufacture of diesel range hydrocarbons wherein a feed is hydrotreated in a hydrotreating step and isomerised in an isomerisation step, and a feed comprising fresh feed containing more than 5 wt % of free fatty acids and at least one diluting agent is hydrotreated at a reaction temperature of 200-400° C., in a hydrotreating reactor in the presence of catalyst, and the ratio of the diluting agent/fresh feed is 5-30:1.
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公开(公告)号：US12084622B2
公开(公告)日：2024-09-10
申请号：US17820152
申请日：2022-08-16
Inventor： Matthew J. Vincent , Keith H. Kuechler
IPC: B01D3/14 , C07C1/24 , C07C2/08 , C07C2/12 , C07C5/03 , C07C7/04 , C07C7/08 , C10G69/12 , C10L1/08
CPC classification number: C10G69/126 , B01D3/14 , B01D3/143 , C07C1/24 , C07C2/08 , C07C2/12 , C07C5/03 , C07C7/04 , C07C7/08 , C10L1/08 , C07C2529/85 , C07C2529/89 , C10G2300/1092 , C10G2300/301 , C10G2400/08 , C10L2270/04
Abstract: A method for producing a blended jet boiling range composition stream may include: oligomerizing an ethylene stream to a C4+ olefin stream in a first olefin oligomerization unit, wherein the C4+ olefin stream contains no greater than 10 wt % of methane, ethylene, and ethane combined; wherein the ethylene stream contains at least 50 wt % ethylene, at least 2000 wppm ethane, no greater than 1000 wppm of methane, and no greater than 20 wppm each of carbon monoxide and hydrogen; oligomerizing the C4+ olefin stream and a propylene/C4+ olefin stream in a second oligomerization unit to produce an isoolefinic stream; subjecting at least a portion of the isoolefinic stream to a hydroprocessing process with hydrogen as treat gas to produce an isoparaffinic stream having no greater than 10 wt % olefin content; and using least a portion of the isoparaffinic stream to create the blended jet boiling range.
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公开(公告)号：US12036539B2
公开(公告)日：2024-07-16
申请号：US17621281
申请日：2020-05-28
Inventor： Joseph M. Falkowski , Yogesh V. Joshi , Mary S. Abdulkarim , Simon C. Weston
CPC classification number: B01J31/1691 , B01J35/617 , B01J35/618 , B01J35/633 , B01J35/635 , B01J35/643 , B01J35/647 , B01J37/04 , B01J37/30 , C07C5/03 , C07F3/06 , B01J2231/645 , B01J2531/0205 , B01J2531/0211 , B01J2531/0238 , B01J2531/26 , B01J2531/72 , B01J2531/845 , B01J2531/847 , C07C2531/22
Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers. MOFs having ambient condition stability may comprise a plurality of metal clusters comprising one or more M4O clusters (M is a metal), and a plurality of 4-pyrazolecarboxylate ligands coordinated to the plurality of metal clusters to define an at least partially crystalline network structure having a plurality of internal pores. The MOFs may have a Pa3 symmetry, which upon activation may convert into Fm3m symmetry. Methods for synthesizing the MOFs may comprise combining a metal source, such as a preformed metal cluster, with 4-pyrazolecarboxylic acid, and reacting the preformed metal cluster with the 4-pyrazolecarboxylic acid to form a MOF having an at least partially crystalline network structure with a plurality of internal pores defined therein and comprising a plurality of metal clusters coordinated to a multidentate organic ligand comprising 4-pyrazolecarboxylate.
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公开(公告)号：US11976036B2
公开(公告)日：2024-05-07
申请号：US18338401
申请日：2023-06-21
Applicant: Chevron Phillips Chemical Company LP
Inventor： Steven M. Bischof , Jeffery C Gee , James Hillier , Kamaljeet Kaur , Ronald C. Smith , Darin B. Tiedtke , Mark L. Hlavinka
CPC classification number: C07C6/04 , B01D3/143 , B01J19/245 , B01J21/08 , B01J23/30 , C07C5/03 , B01J2219/0004 , C07C2521/08 , C07C2523/30
Abstract: Processes for producing n-heptane from a mixture of 1-hexene and 1-octene in the presence of a suitable isomerization-metathesis catalyst followed by a hydrogenation step are disclosed. Integrated manufacturing systems for producing n-heptane with minimal waste also are disclosed.
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公开(公告)号：US20240034702A1
公开(公告)日：2024-02-01
申请号：US18338401
申请日：2023-06-21
Applicant: Chevron Phillips Chemical Company LP
Inventor： Steven M. BISCHOF , Jeffery C. GEE , James HILLIER , Kamaljeet KAUR , Ronald C. SMITH , Darin B. TIEDTKE , Mark L. HLAVINKA
CPC classification number: C07C6/04 , B01D3/143 , B01J21/08 , B01J23/30 , C07C5/03 , B01J19/245 , C07C2521/08 , C07C2523/30 , B01J2219/0004
Abstract: Processes for producing n-heptane from a mixture of 1-hexene and 1-octene in the presence of a suitable isomerization-metathesis catalyst followed by a hydrogenation step are disclosed. Integrated manufacturing systems for producing n-heptane with minimal waste also are disclosed.
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6.发明公开
公开(公告)号：US20240018422A1
公开(公告)日：2024-01-18
申请号：US18371800
申请日：2023-09-22
Applicant: SK Innovation Co., Ltd. , SK Geo Centric Co., Ltd.
Inventor： Sang Il Lee , Ji Hoon Lee , Young Eun Cheon
IPC: C10G45/38 , C07C7/163 , C07C5/03 , B01J19/24 , B01J23/882 , B01J23/28 , B01J23/883 , C10G45/08 , C10G45/36 , C10G45/40 , B01J37/18 , B01J37/20
CPC classification number: C10G45/38 , C07C7/163 , C07C5/03 , B01J19/245 , B01J23/882 , B01J23/28 , B01J23/883 , C10G45/08 , C10G45/36 , C10G45/40 , B01J37/18 , B01J37/20 , C07C2523/28 , B01J2219/0004 , C07C2523/882 , C07C2523/883
Abstract: Disclosed are a process and system that are capable of performing selective hydrogenation on aromatic fractions by configuring a catalyst bed through staged loading of a plurality of hydrogenation catalysts with different catalytic properties, or configuring a catalyst system in which a plurality of hydrogenation catalysts are arranged using a plurality of reactors in such a way as to be equivalent with the staged loading, and as a result, are capable of suppressing aromatic loss while improving the selective removal of unsaturated hydrocarbons in the aromatic fraction and durability compared to the case of using a single catalyst.
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公开(公告)号：US11718572B2
公开(公告)日：2023-08-08
申请号：US17621949
申请日：2020-06-08
Applicant: Dow Global Technologies LLC
Inventor： Lin Luo , Hangyao Wang , Yu Liu , Barry B. Fish
CPC classification number: C07C7/167 , B01D3/14 , B01J23/62 , C07C5/03 , C07C7/005 , C07C7/04 , C07C2523/62
Abstract: A method for operating an integrated system for producing olefins may include contacting a hydrogenation feed with a first hydrogenation catalyst to produce a hydrogenated effluent, the hydrogenation feed including at least a portion of a first process effluent from a first olefin production process and at least a portion of a second process effluent from a second olefin production process. The hydrogenation feed may include at least hydrogen, ethylene, carbon monoxide, acetylene, methyl acetylene, and propadiene, and the first hydrogenation catalyst may be a hydrogenation catalyst having a temperature operating range of at least 40° C. The hydrogenated effluent may include methyl acetylene, propadiene, or both. The method may further include contacting at least a portion of the hydrogenated effluent with a second hydrogenation catalyst, which may cause hydrogenation of at least a portion of the methyl acetylene and propadiene to produce an MAPD hydrogenated effluent.
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公开(公告)号：US11702377B2
公开(公告)日：2023-07-18
申请号：US17122030
申请日：2020-12-15
Applicant: IFP Energies Nouvelles
Inventor： Olivier Thinon , Anne Claire Pierron , Vania Santos-Moreau
Abstract: The present invention relates to an NCC process and an apparatus for producing light olefins and aromatics, wherein the fraction comprising ethane and/or propane (12) from the cracking effluent is sent at least partly into a steam cracking furnace (19), fed with steam (20), to produce a steam cracking effluent (21) comprising ethylene and/or propylene.
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9.发明公开
公开(公告)号：US20230182122A1
公开(公告)日：2023-06-15
申请号：US17872385
申请日：2022-07-25
Applicant: Qufu Normal University
Inventor： Anguo Ying , Shengnan Li , Xiaotong Lu , Qi Liu , Yujing Liu , Zhongqiu Liu
CPC classification number: B01J31/28 , B01J23/745 , B01J31/2295 , B01J31/4069 , C07C5/03 , C11C3/04 , C07C2523/745 , C07C2531/22 , C07C2531/28
Abstract: The disclosure provides use of an efficient, recyclable, green and friendly catalyst to realize a method of hydrogenation of an unsaturated alkene, and a method for preparing biodiesel through the transesterification of soybean oil with ethanol. The method of hydrogenation of the unsaturated alkene comprises performing a hydrogenation reaction of an unsaturated alkene at ambient temperature and atmospheric pressure by using a CO2 and magnetic dual-responsive mesoporous poly(ionic liquid) as a catalyst I, and using n-hexane and water as a solvent, to obtain a corresponding saturated alkane. The method for preparing biodiesel through transesterification of soybean oil with ethanol comprises performing a transesterification reaction of soybean oil with ethanol at a temperature of 25-90° C. and atmospheric pressure by using a CO2 and magnetic dual-responsive mesoporous poly(ionic liquid) as a catalyst II, to obtain the biodiesel.
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公开(公告)号：US20220370992A1
公开(公告)日：2022-11-24
申请号：US17621281
申请日：2020-05-28
Applicant: ExxonMobil Research and Engineering Company
Inventor： Joseph M. Falkowski , Yogesh V. Joshi , Mary S. Abdulkarim , Simon C. Weston
Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers. MOFs having ambient condition stability may comprise a plurality of metal clusters comprising one or more M4O clusters (M is a metal), and a plurality of 4-pyrazolecarboxylate ligands coordinated to the plurality of metal clusters to define an at least partially crystalline network structure having a plurality of internal pores. The MOFs may have a Pa3 symmetry, which upon activation may convert into Fm3m symmetry. Methods for synthesizing the MOFs may comprise combining a metal source, such as a preformed metal cluster, with 4-pyrazolecarboxylic acid, and reacting the preformed metal cluster with the 4-pyrazolecarboxylic acid to form a MOF having an at least partially crystalline network structure with a plurality of internal pores defined therein and comprising a plurality of metal clusters coordinated to a multidentate organic ligand comprising 4-pyrazolecarboxylate.
