Annealed and promoted catalyst
    4.
    发明授权

    公开(公告)号:US07396955B2

    公开(公告)日:2008-07-08

    申请号:US12002821

    申请日:2007-12-19

    IPC分类号: C07C61/16 B01J23/00

    摘要: A mixed metal oxide, which may be an orthorhombic phase material, is improved as a catalyst for the production of unsaturated carboxylic acids, or unsaturated nitrites, from alkanes, or mixtures of alkanes and alkenes, by: contacting with a liquid contact member selected from the group consisting of organic acids, alcohols, inorganic acids and hydrogen peroxide to form a contact mixture; recovering insoluble material from the contact mixture; calcining the recovered insoluble material in a non-oxidizing atmosphere; admixing the calcined recovered insoluble material with (i) at least one promoter element or compound thereof and (ii) at least one solvent for the at least one promoter element or compound thereof; removing the at least one solvent to form a catalyst precursor; and calcining the catalyst precursor.

    Catalyst composition for the selective conversion of alkanes to unsaturated carboxylic acids, method of making and method of using thereof
    5.
    发明申请
    Catalyst composition for the selective conversion of alkanes to unsaturated carboxylic acids, method of making and method of using thereof 有权
    用于将烷烃选择性转化为不饱和羧酸的催化剂组合物,其制备方法及其使用方法

    公开(公告)号:US20070232828A1

    公开(公告)日:2007-10-04

    申请号:US11805656

    申请日:2007-05-24

    IPC分类号: C07C61/16

    摘要: A catalyst composition having the formula: Mo1VaSbbNbcMdOx wherein M is gallium, bismuth, silver or gold, a is 0.01 to 1, b is 0.01 to 1, c is 0.01 to 1, d is 0.01 to 1 and x is determined by the valence requirements of the other components. Other metals, such as tantalum, titanium, aluminum, zirconium, chromium, manganese, iron, ruthenium, cobalt, rhodium, nickel, platinum, boron, arsenic, lithium, sodium, potassium, rubidium, calcium, beryllium, magnesium, cerium, strontium, hafnium, phosphorus, europium, gadolinium, dysprosium, holmium, erbium, thulium, terbium, ytterbium, lutetium, lanthanum, scandium, palladium, praseodymium, neodymium, yttrium, thorium, tungsten, cesium, zinc, tin, germanium, silicon, lead, barium or thallium may also be components of the catalyst. This catalyst is prepared by co-precipitation of metal compounds which are calcined to form a mixed metal oxide catalyst that can be used for the selective conversion of an alkane to an unsaturated carboxylic acid in a one-step process.

    摘要翻译: 具有下式的催化剂组合物:<?in-line-formula description =“In-line formula”end =“lead”?> Mo 1 β-in-line-formula description =“In-line Formulas”end =“in-line formula”end =“in-line formula”end = “尾”→其中M为镓,铋,银或金,a为0.01至1,b为0.01至1,c为0.01至1,d为0.01至1,x由另一个的化合价要求确定 组件。 其他金属如钽,钛,铝,锆,铬,锰,铁,钌,钴,铑,镍,铂,硼,砷,锂,钠,钾,铷,钙,铍,镁,铈,锶 铪,磷,铕,钆,镝,钬,铒,ium,铽,镱,镥,镧,钪,钯,镨,钕,钇,钍,钨,铯,锌,锡,锗,硅,铅 钡或铊也可以是催化剂的组分。 该催化剂通过共沉淀金属化合物制备,金属化合物被煅烧以形成可用于在一步法中将烷烃选择性转化为不饱和羧酸的混合金属氧化物催化剂。

    (1,4-cyclohexadien-1-yl)acetic acid
    7.
    发明授权
    (1,4-cyclohexadien-1-yl)acetic acid 失效
    (1,4-环己基-1-基)乙酸

    公开(公告)号:US3794678A

    公开(公告)日:1974-02-26

    申请号:US3794678D

    申请日:1969-07-22

    发明人: DVONCH W ALBURN H

    IPC分类号: C07D499/00 C07C61/16

    CPC分类号: C07D499/00

    摘要: THIS INVENTION CONCERNS (1,4-CYCLOHEXADIEN-1-YL) ALKANOIC ACIDS WHICH ARE USEFUL AS AMTI-INFLAMMATORY AGENTS. FURTHER, THESE COMPOUNDS ARE ALSO USEFUL INTERMEDIATES IN THE PREPARATION OF SYNTHETIC 6-(1,4-CYCLOHEXADIEN-1-YLAMIDO)PENICILLANIC ACIDS AND 7-(1,4-CYCLOHEXADIEN-1-YLAMIDO)-CEPHALOSPORANIC ACIDS WHICH HAVE POTENT ACTIVITY AGAINST PENICILLIN STAPHYLOCOCCI.