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    Thermally initiated polymerization of olefins using ruthenium or osmium vinylidene complexes
    1.
    再颁专利
    Thermally initiated polymerization of olefins using ruthenium or osmium vinylidene complexes 失效
    使用钌或锇亚乙烯基配合物进行热引发烯烃的聚合

    公开(公告)号：USRE38676E1

    公开(公告)日：2004-12-21

    申请号：US10224679

    申请日：2002-08-21

    Applicant: Robert H. Grubbs ,  Thomas E. Wilhelm

    Inventor： Robert H. Grubbs ,  Thomas E. Wilhelm

    IPC: C08F200

    CPC classification number: C08G61/08 ,  Y10S526/922

    Abstract: The present invention generally relates to the use of certain ruthenium and osmium complexes that are substantially inactive at a first temperature (preferably about room temperature) but becomes progressively more active at a higher second temperature. This difference in reactivities allows the reaction mixture to be formed and manipulated at the first temperature until polymerization is desired. When appropriate, the reaction mixture is heated to a suitable temperature (preferably greater than 50° C.) to activate the catalyst and to initiate polymerization. Because both the initiation and the rate of polymerization may be controlled with temperature, the inventive methods are especially suitable for ring opening metathesis polymerization (“ROMP”) reactions and for molding polymer articles that require extended pot-lives.

    Polymer-containing organo-metal catalysts
    2.
    发明授权
    Polymer-containing organo-metal catalysts 失效
    含聚合物的有机金属催化剂

    公开(公告)号：US06831138B2

    公开(公告)日：2004-12-14

    申请号：US10040530

    申请日：2002-01-07

    Applicant: Yi-Feng Wang

    Inventor： Yi-Feng Wang

    IPC: C08F200

    CPC classification number: C08G63/85 ,  B01J31/0212 ,  B01J31/06 ,  B01J31/122

    Abstract: The invention relates to polymer-containing catalysts (e.g., polymer-containing organo-metal catalysts) that may be useful in various applications (e.g., polymerization of macrocyclic oligoesters). Advantages of these catalysts include the improved ability to prepare, store, and handle the catalyst in open air; higher molar volume and molecular weight; and the ability to produce a blend of reactants and a catalyst (e.g., a macrocyclic oligoester and a polymerization catalyst) for subsequent one-step reaction (e.g., polymerization of macrocyclic oligoesters).

    Abstract translation: 本发明涉及可用于各种应用（例如大环低聚酯的聚合）的含聚合物的催化剂（例如，含聚合物的有机金属催化剂）。 这些催化剂的优点包括提高在露天空气中制备，储存和处理催化剂的能力; 较高的摩尔体积和分子量; 以及产生用于后续一步反应（例如大环低聚酯的聚合）的反应物和催化剂（例如，大环低聚酯和聚合催化剂）的共混物的能力。

    Process for the preparation of latices using block copolymers as surfactants
    3.
    发明授权
    Process for the preparation of latices using block copolymers as surfactants 有权
    使用嵌段共聚物作为表面活性剂制备胶乳的方法

    公开(公告)号：US06825290B2

    公开(公告)日：2004-11-30

    申请号：US10137944

    申请日：2002-05-02

    Applicant: Hervé Adam ,  Wan-Li Liu

    Inventor： Hervé Adam ,  Wan-Li Liu

    IPC: C08F200

    CPC classification number: C08F2/24 ,  C08F2/38 ,  C08F8/00 ,  C08F2800/20 ,  C08F2810/40 ,  Y10S526/922 ,  C08F293/005

    Abstract: A subject-matter of the present invention is a process for the preparation of a latex by radical aqueous emulsion polymerization in the presence of at least one ethylenically unsaturated monomer, of at least one radical polymerization initiator and of at least one surface-active block copolymer comprising at least one hydrophilic block and at least one hydrophobic block which is prepared by a “living” or “controlled” preparation process, the said copolymer exhibiting a number-average molecular mass of between 2 000 and 20 000, preferably between 4 000 and 16 000, a glass transition temperature of the hydrophobic block of less than 30° C., preferably of less than 25° C., and greater than −100° C., and a surface tension of less than 60 millinewtons per metre (mN/m), preferably of less than 50 mN/m, measured at a concentration in demineralized water of less than or equal to 10−4 mol/l at 20° C. and under one atmosphere, and the transfer agent having been rendered inert with respect to the said radical polymerization. The latices obtained can be used in particular in paints, adhesives and building materials.

    Abstract translation: 本发明的主题是在至少一种烯键式不饱和单体，至少一种自由基聚合引发剂和至少一种表面活性嵌段共聚物的存在下，通过自由基水乳液聚合制备胶乳的方法 包括至少一个亲水性嵌段和至少一个通过“活性”或“受控”制备方法制备的疏水嵌段，所述共聚物的数均分子量在2000至20000之间，优选在4000和 16000，疏水嵌段的玻璃化转变温度小于30℃，优选小于25℃，大于-100℃，表面张力小于60毫牛顿/米（mN / m），优选小于50mN / m，在20℃和一个大气压下在软化水中的浓度小于或等于10 -4 mol / l测量，转移剂已经 相对而言是惰性的 到所述自由基聚合。 所得的胶乳特别可用于油漆，粘合剂和建筑材料中。

    Continuous slurry polymerization volatile removal
    4.
    发明授权
    Continuous slurry polymerization volatile removal 有权
    连续淤浆聚合挥发性去除

    公开(公告)号：US06800698B2

    公开(公告)日：2004-10-05

    申请号：US10260011

    申请日：2003-03-11

    Applicant: James Austin Kendrick ,  Thomas W. Towles ,  Scott Thomas Roger

    Inventor： James Austin Kendrick ,  Thomas W. Towles ,  Scott Thomas Roger

    IPC: C08F200

    CPC classification number: B01D3/06 ,  B01J8/003 ,  B01J8/005 ,  B01J8/0055 ,  B01J8/007 ,  B01J8/20 ,  B01J8/382 ,  B01J19/0053 ,  B01J19/1837 ,  B01J2208/0007 ,  B01J2208/00539 ,  B01J2208/00761 ,  B01J2208/00769 ,  B01J2208/00867 ,  B01J2219/00006 ,  B01J2219/00033 ,  B01J2219/00103 ,  B01J2219/00114 ,  B01J2219/00162 ,  B01J2219/00164 ,  B01J2219/00191 ,  B01J2219/002 ,  B01J2219/00213 ,  B01J2219/00231 ,  B01J2219/00236 ,  B01J2219/0024 ,  C08F2/00 ,  C08F6/003 ,  C08F10/00 ,  C08F210/16 ,  C08F2/14 ,  C08F210/14

    Abstract: A process/apparatus is disclosed for continuously separating a liquid medium comprising diluent and unreacted monomers from a polymerization effluent comprising diluent, unreacted monomers and polymer solids, comprising a continuous discharge of the polymerization effluent from a slurry reactor through a discharge valve and transfer conduit into a first intermediate pressure flash tank with a conical bottom defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the slurry/polymer solids and an exit seal chamber of such diameter (d) and length (l) as to maintain a desired volume of concentrated polymer solids/slurry in the exit seal chamber such as to form a pressure seal while continuously discharging a plug flow of concentrated polymer solids/slurry bottom product of the first flash tank from the exit seal chamber through a seal chamber exit reducer with inclined sides defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the polymer solids which remain after removal of about 50 to 100% of the inert diluent therefrom to a second flash tank at a lower pressure.

    Abstract translation: 公开了一种用于从包含稀释剂，未反应单体和聚合物固体的聚合流出物连续分离包含稀释剂和未反应单体的液体介质的方法/装置，其包括通过排放阀将淤浆反应器的聚合流出物连续排出并将传输导管 具有锥形底部的第一中间压力闪蒸罐，该锥形底部由基本上直的侧面倾斜的水平面倾斜，该水平面等于或大于浆料/聚合物固体的滑动角度以及直径（d）的出口密封室， 长度（l）以在出口密封室中保持所需体积的浓缩聚合物固体/浆料，以形成压力密封，同时连续地将第一闪蒸罐的浓缩聚合物固体/浆料底部产物的塞流从出口 密封室通过密封室出口减速器，斜面大致直线形成 以等于或大于在较低压力下将约50至100％的惰性稀释剂从其中除去至第二闪蒸罐后残留的聚合物固体的滑动角度等于或大于水平的角度。

    Copolymer, process for producing the same, and resist composition
    8.
    发明授权
    Copolymer, process for producing the same, and resist composition 有权
    共聚物，其制造方法和抗蚀剂组合物

    公开(公告)号：US06706826B1

    公开(公告)日：2004-03-16

    申请号：US09646117

    申请日：2000-09-27

    Applicant: Tadayuki Fujiwara ,  Masayuki Tooyama ,  Yukiya Wakisaka ,  Koji Nishida ,  Akira Yanagase

    Inventor： Tadayuki Fujiwara ,  Masayuki Tooyama ,  Yukiya Wakisaka ,  Koji Nishida ,  Akira Yanagase

    IPC: C08F200

    CPC classification number: G03F7/039 ,  G03F7/0045

    Abstract: The present invention relates to a copolymer for use in paints, resists, and the like; a method for manufacturing the same; and a resist composition using the same. The copolymer according to the present invention is obtained by means of polymerizing at least one monomer containing an alicyclic structure and one monomer containing a lactone structure, and the distribution of the copolymer composition of said monomer containing a lactone structure in said copolymer is in the range of −10 to +10 mol % of the average copolymer composition of said monomer containing a lactone structure in said entire copolymer. In addition, the copolymer according to the present invention is obtained by means of polymerizing a monomer containing an alicyclic structure, a monomer containing a lactone structure, and another vinyl monomer comprising a higher polarity than said monomer containing an alicyclic structure, but a lower polarity than said monomer containing a lactone structure. The copolymer according to the present invention exhibits superior adhesion properties to surfaces possessing a high polarity, such as metal surfaces and the like, in addition to excellent hydrophobic and thermal resistance properties, and also displays a favorable solubility in solvents used for paints, resists, and the like.

    Abstract translation: 本发明涉及一种用于涂料，抗蚀剂等的共聚物; 其制造方法; 和使用其的抗蚀剂组合物。 本发明的共聚物是通过聚合至少一种含有脂环结构的单体和含有内酯结构的单体而得到的，所述共聚物中含有内酯结构单体的共聚物组成的分布范围为 在所述全部共聚物中含有内酯结构的所述单体的平均共聚物组成为-10〜+ 10mol％。 此外，根据本发明的共聚物是通过使包含脂环结构的单体，含有内酯结构的单体和另外的含有比所述含有脂环结构的单体极性高的极性的乙烯基单体聚合而得到的， 比所述含有内酯结构的单体。 根据本发明的共聚物除了具有优异的疏水和耐热性能之外，还具有对具有高极性的表面，例如金属表面等的优异的粘合性，并且在用于涂料，抗蚀剂， 等等。

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