Bimodal polymerization process utilizing chromium/silica catalysts
    9.
    发明授权
    Bimodal polymerization process utilizing chromium/silica catalysts 有权
    使用铬/二氧化硅催化剂的双峰聚合方法

    公开(公告)号:US09353196B2

    公开(公告)日:2016-05-31

    申请号:US14085198

    申请日:2013-11-20

    摘要: The present invention relates to novel methods for producing a bimodal or broad distribution of molecular weight polyolefin polymers using Cr/silica catalysts. In some aspects the methods utilize different pressures of hydrogen to tailor the properties of the polymer. In particular aspects, a method of preparing a polyolefin having a bimodal molecular weight distribution, comprising: (a) preparing a reaction mixture comprising a monomer, a catalyst, and an organic solvent; (b) heating the reaction mixture under a first set of reaction conditions to effect a first polymerization comprising the polymerization of a first fraction of the monomer; and (c) heating the reaction mixture under a second set of reaction conditions to effect a second polymerization comprising the polymerization of a second fraction of the monomer.

    摘要翻译: 本发明涉及使用Cr /二氧化硅催化剂制备分子量聚烯烃聚合物的双峰或宽分布的新方法。 在一些方面,该方法利用不同的氢气压力来调整聚合物的性质。 在具体方面,制备具有双峰分子量分布的聚烯烃的方法包括:(a)制备包含单体,催化剂和有机溶剂的反应混合物; (b)在第一组反应条件下加热反应混合物以进行包含单体的第一部分的聚合的第一聚合; 和(c)在第二组反应条件下加热反应混合物以进行包含第二部分单体聚合的第二次聚合。