Process of making an epoxide polymer using highly active double metal cyanide catalysts
    1.
    发明授权
    Process of making an epoxide polymer using highly active double metal cyanide catalysts 失效
    使用高活性双金属氰化物催化剂制备环氧化物聚合物的方法

    公开(公告)号:US06211330B1

    公开(公告)日:2001-04-03

    申请号:US08902784

    申请日:1997-07-30

    申请人: Bi Le-Khac

    发明人: Bi Le-Khac

    IPC分类号: C08G5900

    CPC分类号: B01J27/26 C08G65/2663

    摘要: Improved double metal cyanide (DMC) catalysts are disclosed. The catalysts comprise a DMC compound, an organic complexing agent, from about 0.1 to about 10 wt. % of an organophosphine oxide, and optionally, a polyether. Compared with other DMC catalysts prepared in the absence of the organophosphine oxide, those of the invention have higher activity for epoxide polymerization, and they give polyols having reduced unsaturation even at high epoxide polymerization temperatures.

    摘要翻译: 公开了改进的双金属氰化物(DMC)催化剂。 催化剂包含DMC化合物,有机络合剂,约0.1-约10wt。 %的有机膦氧化物,和任选的聚醚。 与在不存在有机膦氧化物的情况下制备的其它DMC催化剂相比,本发明的DMC催化剂具有较高的环氧化物聚合活性,并且即使在高环氧化物聚合温度下也产生具有降低的不饱和度的多元醇。

    Process for producing polymers having oxetanyl group on side chain
    2.
    发明授权
    Process for producing polymers having oxetanyl group on side chain 失效
    在侧链上生产具有氧杂环丁烷基的聚合物的方法

    公开(公告)号:US06770737B2

    公开(公告)日:2004-08-03

    申请号:US10102652

    申请日:2002-03-22

    IPC分类号: C08G5900

    摘要: Polymers having an oxetanyl group on the side chain and being represented by the following formula (2) are provided. They are usable for reactions such as ring-opening reaction and addition reaction. The process comprises subjecting to anionic ring-opening polymerization a 3-[(oxiranylmethoxy)methyl]oxetane monomer represented by the following formula (1) alone or together with other monomer containing an epoxy group: wherein A represents a hydrogen atom or an alkyl group of 1-6 carbon atoms, wherein A is the same as above, and R represents a hydrogen atom, a chloromethyl group, straight chain alkyl group or branched chain alkylene group of 1-12 carbon atoms, phenyl group, straight or branched chain alkyloxymethyl group of 1-12 carbon atoms or phenoxymethyl group, and n and m each represent a molar fraction, n being 100-1 mol %, m being 0-99 mol % with n+m=100.

    摘要翻译: 提供侧链上具有氧杂环丁烷基并由下式(2)表示的聚合物。 它们可用于开环反应和加成反应等反应。 该方法包括单独或与含有环氧基的其它单体一起进行由下式(1)表示的3 - [(环氧乙烷基甲氧基)甲基]氧杂环丁烷单体的阴离子开环聚合:其中A表示氢原子或烷基 1-6个碳原子,其中A与上述相同,R表示氢原子,氯甲基,1-12个碳原子的直链烷基或支链亚烷基,苯基,直链或支链烷氧基甲基 1-12个碳原子的基团或苯氧基甲基,n和m各自表示摩尔分数,n为100-1摩尔%,m为0-99摩尔%,n + m = 100。

    Hyperbranched dendritic polyether and process for manufacture thereof
    3.
    发明授权
    Hyperbranched dendritic polyether and process for manufacture thereof 有权
    超支化树枝状聚醚及其制造方法

    公开(公告)号:US06617418B1

    公开(公告)日:2003-09-09

    申请号:US09937350

    申请日:2002-01-25

    IPC分类号: C08G5900

    摘要: A hyperbranched dendritic polyether, which optionally is further processed, such as further chain extended, chain terminated and/or functionalised. The hyperbranched dendritic polyether is obtained in a process comprising the step of thermally initiated cationic ring-opening polymerisation of at least one oxetane having at least two reactive groups of which at least one is an oxetane group. The thermally initiated ring-opening polymerisation is performed using an effective amount of at least one initiator, such as a thermal onium salt, a Lewis acid and/or a Brønsted acid. The terminal groups in said hyperbranched dendritic polyether are substantially hydroxyl groups and used for said optional further processing.

    摘要翻译: 任选进一步加工的超支化树枝状聚醚,例如进一步链延长,链终止和/或官能化。 获得超支化树枝状聚醚的方法包括至少一种具有至少两个其中至少一个是氧杂环丁烷基的反应性基团的氧杂环丁烷的热引发阳离子开环聚合步骤。 使用有效量的至少一种引发剂如热鎓盐,路易斯酸和/或布朗斯台德酸进行热引发的开环聚合。 所述超支化树枝状聚醚中的末端基团基本上是羟基并用于所述任选的进一步加工。

    Methods of fabricating cross-linked biobased materials and structures fabricated therewith
    4.
    发明授权
    Methods of fabricating cross-linked biobased materials and structures fabricated therewith 失效
    制造交联的生物基材料和用其制造的结构的方法

    公开(公告)号:US06339116B1

    公开(公告)日:2002-01-15

    申请号:US08770212

    申请日:1996-12-19

    IPC分类号: C08G5900

    摘要: Biobased cross-linked compositions, methods of fabrication and structures, in particular biobased printed wiring boards using the compositions and methods of making the structures are described. Biobased materials such as lignin, crop oils, wood resins, tannins, and polysaccharides and combinations thereof are cross-linked, preferably using heat, a cross-linking agent, and an initiator. The materials fabricated have suitable properties for printed wiring boards which are made by impregnating a fiberglass or biobased cloth with an admixture of the biobased material, cross-linking agent and initiator which is processed by conventional methods to produce a printed wiring board.

    摘要翻译: 描述了生物基交联组合物,制造方法和结构,特别是使用组合物的生物基印刷线路板和制造结构的方法。 生物基材料如木质素,作物油,木材树脂,单宁和多糖及其组合是优选使用热交联剂和引发剂交联的。 制造的材料具有适用于印刷线路板的性能,其通过用生物基材料,交联剂和引发剂的混合物浸渍玻璃纤维或生物基布而制成,其通过常规方法加工以生产印刷线路板。

    Quick-setting mixtures and kits with polyfunctional cyanates and amines, the thermosets produced therefrom and methods for the production thereof
    5.
    发明授权
    Quick-setting mixtures and kits with polyfunctional cyanates and amines, the thermosets produced therefrom and methods for the production thereof 有权
    具有多官能氰酸酯和胺的快速固化混合物和试剂盒,由其制备的热固性材料及其生产方法

    公开(公告)号:US06822067B2

    公开(公告)日:2004-11-23

    申请号:US10221484

    申请日:2002-11-08

    IPC分类号: C08G5900

    CPC分类号: C08G73/0655

    摘要: The invention describes a fast curable system for the preparation of amine modified thermosettings containing triazine groups, the system comprising at least one polyfuctional organic monomeric or prepolymerized cyanate and at least one primary or secondary amine, wherein the amount of amine is selected such that the molar ratio of cyanate radicals to amine radicals is from 95:5 to 50:50, and optionally additional additives, characterized in that the amine is present in a form having a blocked or decreased reactivity which can be reactivated without reacting it with a chemical participant of reaction. Further, it is directed to amine modified thermosetting materials containing triazine groups as well as to a method for preparing same.

    摘要翻译: 本发明描述了用于制备含有三嗪基团的胺改性热固性物质的快速可固化体系,该系统包含至少一种多官能有机单体或预聚氰酸酯和至少一种伯胺或仲胺,其中胺的量选择为使得摩尔 氰酸根自由基与胺基的比例为95:5至50:50,以及任选的其它添加剂,其特征在于胺以具有阻止或降低的反应性的形式存在,其可以重新活化而不与其反应,化学参与者 反应。 此外,其涉及含有三嗪基团的胺改性的热固性材料以及其制备方法。

    Branched polymeric surfactant reaction products, methods for their preparation, and uses therefor
    6.
    发明授权
    Branched polymeric surfactant reaction products, methods for their preparation, and uses therefor 有权
    支化聚合物表面活性剂反应产物,其制备方法及用途

    公开(公告)号:US06465605B2

    公开(公告)日:2002-10-15

    申请号:US09783855

    申请日:2001-02-15

    IPC分类号: C08G5900

    摘要: Polymeric compounds useful as low foaming surfactants and defoaming and stabilizing agents for aqueous-and nonaqueous-based compositions, and to processes for the preparation of the polymeric compounds, wherein the polymeric compounds are the reaction products of reactants comprising A) at least one linking compound of formula I R1(X)3  (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) compounds of formula 11 R2(OA)nX  (II) wherein R2 is an organic group containing from 4 to 36 carbon atoms, n is a number of from 0 to 200, X is —OH, —NHR′, or —SH and each OA group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group.

    摘要翻译: 可用作低泡表面活性剂的聚合化合物和用于水基和非水基组合物的消泡和稳定剂以及制备聚合物的方法,其中聚合物是反应物的反应产物,其包含:A)至少一种连接化合物 式I其中X基团为卤素原子或一个X基团为卤素原子,两个X基团表示环氧氧原子,其与R1基团中两个相邻的碳原子连接形成环氧基团,R1为烷基三 含3至10个碳原子的基团; 和B)式11的化合物,其中R2是含有4至36个碳原子的有机基团,n是0-200的数,X是-OH,-NHR'或-SH,各个OA基团独立地是亚乙基氧基, 1,2-亚丙氧基或1,2-亚丁氧基。

    Polymer electrolyte composition and uses thereof
    7.
    发明授权
    Polymer electrolyte composition and uses thereof 失效
    聚合物电解质组合物及其用途

    公开(公告)号:US06828407B2

    公开(公告)日:2004-12-07

    申请号:US10341500

    申请日:2003-01-14

    IPC分类号: C08G5900

    摘要: The present invention provides a polymer electrolyte composition excellent in radical resistance and/or proton conductivity. The polymer electrolyte composition comprises an aromatic polymer phosphonic acid derivative represented by the following formula (1); and at least one selected from the group consisting of a phosphoric acid derivative and a polymer electrolyte. (wherein -Z- represents —SO2— or —CO—, x and y each represent 0.01-0.99 provided that the sum of x and y is 1, —Ar— represents a divalent aromatic group of 4-18 carbon atoms which may contain a hetero atom and may contain one or more substituents, n represents the average number of substituents per unit structure of polymeric moiety containing the aromatic group and is a positive number of 8 or less, and R and R′ each independently represent a hydrogen atom or an alkyl group).

    摘要翻译: 本发明提供了具有优异的自由基电阻和/或质子传导性的聚合物电解质组合物。 聚合物电解质组合物包含由下式(1)表示的芳族聚合物膦酸衍生物; 和选自磷酸衍生物和聚合物电解质中的至少一种(其中-Z-表示-SO2-或-CO-,x和y各自表示0.01-0.99,条件是x和y的和为 1,-Ar-表示可以含有杂原子并且可以含有一个或多个取代基的4-18个碳原子的二价芳族基团,n表示每单位结构的含芳族基团的聚合物部分的取代基的平均数, 正数为8以下,R和R'各自独立地表示氢原子或烷基。

    Highly purified epoxy resin
    8.
    发明授权
    Highly purified epoxy resin 失效
    高纯度环氧树脂

    公开(公告)号:US06818727B2

    公开(公告)日:2004-11-16

    申请号:US09320719

    申请日:1999-05-27

    IPC分类号: C08G5900

    摘要: Provided is an epoxy resin having glycidylamino group, wherein the content of hydrolyzable chlorine is 1000 ppm or less. The epoxy resin is useful for adhesives, paints and electric/electronic materials(e.g. insulation materials, laminated plate, etc.).

    摘要翻译: 提供具有缩水甘油基氨基的环氧树脂,其中可水解氯的含量为1000ppm以下。 环氧树脂可用于粘合剂,油漆和电气/电子材料(例如绝缘材料,层压板等)。

    Polymeric thickeners for aqueous compositions
    9.
    发明授权
    Polymeric thickeners for aqueous compositions 失效
    含水组合物的聚合增稠剂

    公开(公告)号:US06649733B1

    公开(公告)日:2003-11-18

    申请号:US08236328

    申请日:1994-05-09

    IPC分类号: C08G5900

    摘要: Latexes are thickened by compounds of the formula: R1—(O—A)a—B1—R2—(B2—R3)d—(B3—(A′—O)b-f—(A′—B4)f—R4—(B5—R5)e)n—B6—(A″O)c—R6 wherein: R1 and R6 are monovalent hydrophobic groups independently selected from the group consisting of an aliphatic group, a substituted aliphatic group, an aromatic group, and a substituted aromatic group; R2 and R4 are independently selected from the group consisting of aliphatic, substituted aliphatic, aromatic, or substituted aromatic radicals, each radical being divalent or trivalent; R3 and R5 are independently selected from hydrogen, lower alkyl and lower aralkyl; B1, B2, B3, B4, B5, and B6 are linking groups independently selected from the group consisting of an oxygen atom (to form the ether linkage —O—), a carboxylate group (to form an ester linkage R2—C(O)—O— and/or R4—C(O)—O—), an amino group (to form the amine linkage R2—N(R)— and or R4—N(R)—, wherein R is hydrogen, lower alkyl, lower aralkyl, or lower acyl), and an amido group (to form the amide linkage R2—N(R)—C(O)— and/or R4—N(R)—C(O)—, wherein R is hydrogen, lower alkyl, lower aralkyl, or lower acyl); each of a, b, c, d, e, f, and n are integers, wherein each of a and c are independently any integer from greater than 20 to about 200; b is any integer from greater than 20 to about 450; d, e, and f are zero or 1; and n is any integer from 1 to about 5; and each of A, A′, and A″ is independently an ethylene, 1,2-propylene, 1,2-butylene unit or combinations thereof.

    摘要翻译: 乳化剂由下式化合物增稠:其中:R 1和R 6是独立地选自脂族基团,取代的脂族基团,芳族基团和取代的芳族基团的一价疏水基团; R 2和R 4独立地选自脂族,取代的脂族,芳族或取代的芳族基团,每个基团是二价或三价的; R 3和R 5独立地选自氢 ,低级烷基和低级芳烷基; B 1,B 2,B 3,B 4,B 5和B 6是独立地选自氧原子 (形成醚键-O-),羧酸酯基(形成酯键R 2 -C(O)-O-和/或R 4 -C(O)-O-), 氨基(形成胺键R 2 -N(R) - 和/或R 4 -N(R) - ,其中R是氢,低级烷基,低级芳烷基或低级酰基) (形成酰胺键R 2 -N(R)-C(O) - 和/或R 4 -N(R)-C(O) - , 其中R为氢,低级烷基,低级芳烷基或低级酰基); a,b,c,d,e,f和n各自为整数,其中a和c各自独立地为大于20至 约200; b是大于20到约450的任何整数; d,e和f为零或1; n为1〜5的整数; A,A'和A“的每一个独立地是乙烯,1,2-亚丙基,1,2-亚丁基单元或其组合。