Preceramic 3D-printing monomer and polymer formulations

    公开(公告)号:US11891341B2

    公开(公告)日:2024-02-06

    申请号:US16888724

    申请日:2020-05-30

    摘要: This disclosure provides resin formulations which may be used for 3D printing and thermally treating to produce a ceramic material. The disclosure provides direct, free-form 3D printing of a preceramic polymer, followed by converting the preceramic polymer to a 3D-printed ceramic composite with potentially complex 3D shapes. A wide variety of chemical compositions is disclosed, and several experimental examples are included to demonstrate reduction to practice. For example, preceramic resin formulations may contain a carbosilane in which there is at least one functional group selected from vinyl, allyl, ethynyl, unsubstituted or substituted alkyl, ester group, amine, hydroxyl, vinyl ether, vinyl ester, glycidyl, glycidyl ether, vinyl glycidyl ether, vinyl amide, vinyl triazine, vinyl isocyanurate, acrylate, methacrylate, alkacrylate, alkyl alkacrylate, phenyl, halide, thiol, cyano, cyanate, or thiocyanate. The resin formulations may contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material.

    CURABLE COMPOSITION
    4.
    发明公开
    CURABLE COMPOSITION 审中-公开

    公开(公告)号:US20230227612A1

    公开(公告)日:2023-07-20

    申请号:US18098553

    申请日:2023-01-18

    发明人: Yoshiaki HONDA

    摘要: A curable composition including a perfluoro(poly)ether group-containing silane compound having two or more Si atoms each bonding to at least one of a hydroxyl and hydrolyzable group, and a perfluoro(poly)ether group represented by: —(OC6F12)a—(OC5F10)b—(OC4F8)c—(OC3X106)d—(OC2F4)e—(OCF2)f—, wherein a, b, c and d are each independently an integer of 0 to 30, e and f are each independently an integer of 1 to 200, the sum of a, b, c, d, e and f is at least 5, the occurrence order of respective repeating units with the subscript a, b, c, d, e or f is not limited, a ratio of e to f is less than 1.0, and each X10 is independently a hydrogen, fluorine or chlorine atom; an organosilicon compound having at least two —O—Rg3(s) each bonding to a Si atom, wherein each Rg3 is independently a hydrogen atom or a monovalent organic group; and a catalyst.

    Low-density gel product and production method therefor

    公开(公告)号:US11518855B2

    公开(公告)日:2022-12-06

    申请号:US16634800

    申请日:2018-08-23

    申请人: KYOTO UNIVERSITY

    IPC分类号: C08G77/42 C08G77/50 C08J9/28

    摘要: A low-density gel product of the present disclosure has a skeleton containing a polysiloxane chain and an organic polymer chain. In the skeleton, the polysiloxane chain and the organic polymer chain are bonded to each other by covalent bonds at a plurality of positions on both of the chains with silicon atoms of the polysiloxane chain as bonding points. The organic polymer chain may be an aliphatic hydrocarbon chain. The polysiloxane chain may be a polyorganosiloxane chain. The low-density gel product of the present disclosure is a novel low-density gel product with improved mechanical properties including bending flexibility.