HYDROGENATED NITRILE RUBBER WITH REDUCED CATALYST IMPURITY

    公开(公告)号:US20240228757A1

    公开(公告)日:2024-07-11

    申请号:US18613564

    申请日:2024-03-22

    摘要: The residual hydrogenation catalyst from the hydrogenated nitrile rubber solution is recovered by using two steps such as (1) the catalyst extraction step with an ammonium salt and water (optionally including an oxidation step) to extract catalyst from the HNBR polymer chain to the solvent and then (2) the separation/column recovery step with the column packed with functional ion exchange resins for the separation of ammonia-catalyst complex from hydrogenated nitrile rubber solution and the column recovery for the high catalyst recovery with functional groups of resins. The ammonium salt for the catalyst extraction step is selected from ammonium chloride, ammonium bromide, ammonium iodide, and ammonium acetate. The functional groups in the functional ion exchange resins for packing the column is selected from thiourea, thiouronium, thiol, amine, diamine, triamine, TMT, dithiocarbamate, and carbodithioate.

    Rubber compositions
    5.
    发明授权

    公开(公告)号:US12024619B2

    公开(公告)日:2024-07-02

    申请号:US17255429

    申请日:2019-06-21

    申请人: KURARAY CO., LTD.

    摘要: The invention provides a peroxide crosslinkable rubber composition including a hydrogenated nitrile rubber that is enhanced in scorch stability without deterioration in superior characteristics of crosslinked products of the composition. The invention also provides a crosslinked product of such a rubber composition. The rubber composition includes 100 parts by mass of a hydrogenated nitrile rubber (A), 5 to 100 parts by mass of a filler (B), 1 to 10 parts by mass of an organic peroxide (C), and 1 to 20 parts by mass of a liquid diene rubber (D) having a polystyrene-equivalent weight average molecular weight of 3,000 to 120,000 as measured by gel permeation chromatography (GPC).