CELLULOSE NANOCRYSTAL POWDER AND PREPARATION METHOD AND USE THEREOF

    公开(公告)号:US20230076982A1

    公开(公告)日:2023-03-09

    申请号:US18047314

    申请日:2022-10-18

    IPC分类号: C08F251/02 C08L51/02

    摘要: A preparation method includes 1) dispersing cellulose nanocrystal in water and adjusting pH to 7; 2) adding carboxylate to the aqueous dispersion of the step 1), and stirring until uniform; and 3) adding a monomer and a ceric ammonium nitrate initiator to the system of the step 2), reacting for 0.5-3 h to obtain a precipitate, and subjecting the precipitate to suction filtration, washing, and drying to obtain the cellulose nanocrystal powder. By adding a small amount of carboxylate into a cellulose nanocrystal graft polymer modification system initiated by ceric ammonium nitrate, hydrolysis of cerium ions can be inhibited through complexation of the carboxylate to the cerium ions which play an initiating role in ceric ammonium nitrate, so that ceric ammonium nitrate can initiate the polymerization reaction under acid-free conditions, thereby achieving polymerization of polyvinyl acetate monomer on the surface of cellulose nanocrystals.

    Expandable Starch Beads and Method for Preparing the Same
    10.
    发明申请
    Expandable Starch Beads and Method for Preparing the Same 有权
    可膨胀淀粉珠及其制备方法

    公开(公告)号:US20130116352A1

    公开(公告)日:2013-05-09

    申请号:US13809973

    申请日:2011-07-14

    IPC分类号: C08L51/02

    摘要: Provided is expandable starch beads including a starch-monomer copolymer and a foaming agent impregnated in the starch-monomer copolymer, in which the starch-monomer copolymer is prepared by bonding at least one monomer selected from the group consisting of styrene, α-methylstyrene, lactide, lactic acid, acrylic acid, methacrylic acid, acrylic ester, methacrylic ester, acrylonitrile, acrylamide, and caprolactone to starch, and the foaming agent includes at least one selected from the group consisting of C2 to C7 aliphatic hydrocarbon, C2 to C7 halogenated hydrocarbon, and carbon dioxide. Since the expandable starch beads have the similar properties to expandable polystyrene beads, and thereby can be foam-molded by equipment for foaming the expandable polystyrene beads, it is possible to produce foams with various sizes and various shapes.

    摘要翻译: 提供了包含淀粉 - 单体共聚物和浸渍在淀粉 - 单体共聚物中的发泡剂的可发酵淀粉珠粒,其中淀粉 - 单体共聚物通过将至少一种选自苯乙烯,α-甲基苯乙烯, 丙交酯,乳酸,丙烯酸,甲基丙烯酸,丙烯酸酯,甲基丙烯酸酯,丙烯腈,丙烯酰胺和己内酯与淀粉,发泡剂包括选自C2〜C7脂肪族烃,C2〜C7卤代 碳氢化合物和二氧化碳。 由于可膨胀淀粉珠具有与可发性聚苯乙烯珠相似的性质,因此可以通过用于发泡可发性聚苯乙烯珠的设备进行发泡成型,可以生产各种尺寸和各种形状的泡沫。